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高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (S1): 127-127.

• Articles • 上一篇    下一篇

Carboxymethylation of Cellulose by Microwave irradiation

YE Jun1, XIONG Jian2, SU Ying-zhi1, XIAO Ping1   

  1. 1. State Key Laboratory of Pulp & Paper Engineering, South China Univ, of Tech, Guangzhou 510640;
    2. Research Institute of Light Industry & Chemical Engineering, South China Univ. of Tech., Guangzhou 510640
  • 出版日期:2001-12-31 发布日期:2016-03-14
  • 通讯作者: XIONG Jian,E-mail:lcjxiong@scut.edu.cn E-mail:lcjxiong@scut.edu.cn
  • 基金资助:

    We gratefully acknowledge the financial support from the NSFC(project 20014003)

Carboxymethylation of Cellulose by Microwave irradiation

YE Jun1, XIONG Jian2, SU Ying-zhi1, XIAO Ping1   

  1. 1. State Key Laboratory of Pulp & Paper Engineering, South China Univ, of Tech, Guangzhou 510640;
    2. Research Institute of Light Industry & Chemical Engineering, South China Univ. of Tech., Guangzhou 510640
  • Online:2001-12-31 Published:2016-03-14
  • Contact: XIONG Jian,E-mail:lcjxiong@scut.edu.cn E-mail:lcjxiong@scut.edu.cn
  • Supported by:

    We gratefully acknowledge the financial support from the NSFC(project 20014003)

摘要:

Cellulose may be readily converted into ethers involving primary and secondary alcohol groups in each monomer unit and the glycosidic bonds.However,these reactions are rather more complicated than with simple substances,because the stereochemistry of the cellulose molecule is such that the vast majority of its hydroxyl groups form intra-chain hydrogen bonds or inter-chain hydrogen bonds with contiguous molecules.

Abstract:

Cellulose may be readily converted into ethers involving primary and secondary alcohol groups in each monomer unit and the glycosidic bonds.However,these reactions are rather more complicated than with simple substances,because the stereochemistry of the cellulose molecule is such that the vast majority of its hydroxyl groups form intra-chain hydrogen bonds or inter-chain hydrogen bonds with contiguous molecules.