Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP

高等学校化学研究 ›› 1998, Vol. 14 ›› Issue (2): 194-198.

Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP

WU Cheng-pei¹, PAN Cai-yuan¹, Toshiyuki-Uryu²

1. Department of Polymer Science & Engineering, University of Science & Technology of China, Hefei 230026;
2. Institute of Industrial Science, University of Tokyo, Tokyo 106, Japan

收稿日期:1997-01-06 出版日期:1998-04-24 发布日期:2011-08-17

Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP

WU Cheng-pei¹, PAN Cai-yuan¹, Toshiyuki-Uryu²

1. Department of Polymer Science & Engineering, University of Science & Technology of China, Hefei 230026;
2. Institute of Industrial Science, University of Tokyo, Tokyo 106, Japan

Received:1997-01-06 Online:1998-04-24 Published:2011-08-17

摘要/Abstract

摘要： Two kinds of 1,4-anhydroribose derivatives, 1,4-anhydro 2,3-O-benzylidene-α-D-ribopyranose （ABRP） and 1,4-anhydro 2,3-O-isopropylidene α D ribopyranose （AIRP） were prepared from D-ribose. The ring-opening copolymerizations of ABRP and AIRP in various feed ratios were carried out with SbCl₅ and BF₃OEt₂ as catalyst at low temperatures. The copolymer structure was characterized by means of ¹H,¹³C NMR spectroscopy and specific rotation. When SbCl₅ was used as catalyst, the copolymer obtained had completely 1,4-β-pyranosidic structure, i.e., cellulose type structure. However, when BF₃OEt₂ was used as catalyst, the copolymer had a mixed structure of furanosidic and pyranosidic units.

关键词: 1, 4-anhydroribose derivative, ringopening copolymerization, cellulosetype polysaccharide

Abstract: Two kinds of 1,4-anhydroribose derivatives, 1,4-anhydro 2,3-O-benzylidene-α-D-ribopyranose （ABRP） and 1,4-anhydro 2,3-O-isopropylidene α D ribopyranose （AIRP） were prepared from D-ribose. The ring-opening copolymerizations of ABRP and AIRP in various feed ratios were carried out with SbCl₅ and BF₃OEt₂ as catalyst at low temperatures. The copolymer structure was characterized by means of ¹H,¹³C NMR spectroscopy and specific rotation. When SbCl₅ was used as catalyst, the copolymer obtained had completely 1,4-β-pyranosidic structure, i.e., cellulose type structure. However, when BF₃OEt₂ was used as catalyst, the copolymer had a mixed structure of furanosidic and pyranosidic units.

Key words: 1,4-anhydroribose derivative, ringopening copolymerization, cellulosetype polysaccharide

WU Cheng-pei, PAN Cai-yuan, Toshiyuki-Uryu . Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP[J]. 高等学校化学研究, 1998, 14(2): 194-198.

WU Cheng-pei, PAN Cai-yuan, Toshiyuki-Uryu . Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP[J]. Chemical Research in Chinese Universities, 1998, 14(2): 194-198.

[1]	MIAO Tianchang, DI Xin, HAO Feini, ZHENG Gengfeng, HAN Qing. Polymeric Carbon Nitride-based Single Atom Photocatalysts for CO₂ Reduction to C₁ Products[J]. 高等学校化学研究, 2022, 38(5): 1197-1206.
[2]	LI Hongxiang, WANG Sichun, LIU Xinyu, WU Fan, ZHANG Qiang, YUAN Jian, MA Wei, HAN Yanchun. Crystals Array via Oriented Nucleation and Growth Induced by Smectic E Mesophase of C7-T-BTBT[J]. 高等学校化学研究, 2022, 38(4): 1041-1049.
[3]	Ghadah F. ALJOHANI, Fatma A. A. EL-HAG, Mohamed S. BEKHEIT, Ewies F. EWIES, May A. EL-MANAWATY. An Efficient One-pot Synthesis of Certain Stereoselective Spiro[pyrazole-4,5'-isoxazoline]-5-one Derivatives: In vitro Evaluation of Antitumor Activities,Molecular Docking and In silico ADME Predictions[J]. 高等学校化学研究, 2022, 38(4): 1073-1082.
[4]	CAO Xiaohao, HE Yanjing, ZHANG Zhengqing, SUN Yuxiu, HAN Qi, GUO Yandong, ZHONG Chongli. Predicting of Covalent Organic Frameworks for Membrane-based Isobutene/1,3-Butadiene Separation: Combining Molecular Simulation and Machine Learning[J]. 高等学校化学研究, 2022, 38(2): 421-427.
[5]	JIANG Jian. Observation of a 3-in-1 Russian-doll-like Complex in Solution[J]. 高等学校化学研究, 2022, 38(2): 497-499.
[6]	XU Wenjing, LI Li, ZHANG Tianjun, YU Jihong. Tailoring Porosity and Titanium Species of TS-1 Zeolites via Organic Base-assisted Sequential Post-treatment[J]. 高等学校化学研究, 2022, 38(1): 50-57.
[7]	LI Jun, RONG Huazhen, CHEN Cong, LI Ziyi, ZUO Jiayu, WANG Wenjian, LIU Xinjian, GUAN Yixing, YANG Xiong, LIU Yingshu, ZOU Xiaoqin, ZHU Guangshan. Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N₂/NO₂ Separation[J]. 高等学校化学研究, 2022, 38(1): 250-256.
[8]	ZHU Ruonan, WANG Jun, LI Jie. Li₄Mn₅O₁₂Cathode for Both 3 V and 4 V Lithium-ion Batteries[J]. 高等学校化学研究, 2021, 37(5): 1031-1043.
[9]	LIU Fei, LI Ren, YE Jing, REN Yujie, TANG Zhipeng, LI Rongchen, ZHANG Cuihua, LI Qunlin. Study of Aldo-keto Reductase 1C3 Inhibitor with Novel Framework for Treating Leukaemia Based on Virtual Screening and In vitro Biological Activity Testing[J]. 高等学校化学研究, 2021, 37(3): 778-786.
[10]	ZHANG Ling, FU Yihong, DING Yue, MENG Jiao, WANG Zhenchao, WANG Peiyi. Antibacterial Activity of Novel 18β-Glycyrrhetinic Hydrazide or Amide Derivatives[J]. 高等学校化学研究, 2021, 37(3): 662-667.
[11]	FENG Fan, LI Jing, ZHANG Zhihui, FU Jiaxu, ZHANG Yumin, GU Qiang. Design, Ultrasonic-assisted Synthesis and Evaluation In vitro Antimicrobial Activity of Bis-isoxazole Derivatives Bearing Chloro-pyridinyl Group[J]. 高等学校化学研究, 2021, 37(3): 668-673.
[12]	WANG Yibin, TIAN Liang, ZHU Tianhao, MEI Jing, CHEN Zezhong, YU Deng-Guang. Electrospun Aspirin/Eudragit/Lipid Hybrid Nanofibers for Colon-targeted Delivery Using an Energy-saving Process[J]. 高等学校化学研究, 2021, 37(3): 443-449.
[13]	LI Meng, WU Mingwei, PAN Biwei, XU Dandan, LVSONG Zhuopu, LI Dongqing, ZHANG Fangrong, HUANG Jun. Aerobic Oxidation of 2,3,6-Trimethylphenol with Reusable Homogenized Copper Catalysts[J]. 高等学校化学研究, 2021, 37(3): 751-756.
[14]	LI Zhihui, GUO Xiaotong, ZHANG Yaning, LIU Guangzhou, ZHANG Shuyong. Abnormal Blood Glucose Concentration on Degradation Behavior of AZ31 Magnesium Alloy[J]. 高等学校化学研究, 2020, 36(6): 1217-1226.
[15]	LI Fengyun, GONG Jianing, LIU Jingbo, LI Yuxin, LI Zhengming. Design and Synthesis of Novel 3,4-Dihydro-2H-1,2,4-benzothiadiazine 1,1-Dioxides-based Strobilurins as Potent Fungicide Candidates[J]. 高等学校化学研究, 2020, 36(6): 1190-1195.

Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP

Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价