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高等学校化学研究 ›› 1998, Vol. 14 ›› Issue (2): 116-119.

• Articles • 上一篇    下一篇

Heteropolyacids Catalysis in Synthesizing Butylacrylate

ZHU Zhi-ping, ZHOU De-feng, LIU Jing-fu   

  1. Department of Chemisty, Northeast Normal University, Changchun 130024
  • 收稿日期:1997-09-19 出版日期:1998-04-24 发布日期:2011-08-17
  • 基金资助:

    Supported by the National Natural Science Foundation of China.

Heteropolyacids Catalysis in Synthesizing Butylacrylate

ZHU Zhi-ping, ZHOU De-feng, LIU Jing-fu   

  1. Department of Chemisty, Northeast Normal University, Changchun 130024
  • Received:1997-09-19 Online:1998-04-24 Published:2011-08-17
  • Supported by:

    Supported by the National Natural Science Foundation of China.

PDF (PC)

摘要： The catalytic activities of some heteropolyacids(HPAs) in synthesizing butyl-acrylate are reported. It has been demonstrated that 12-tungstophosphoric acid is the most effective catalyst among more than 20 HPA(salts). Various factors concerned in this reaction have been investigated. The optimum conditions have been found, that is, the molar ratio of alcohol to acid is 1.2∶1.0 , the catalyst concentration 1%(mass fraction), the reaction time 2 h, the temperature 98—124 ℃ and a certain amount of polymerization inhibitor exists.

关键词: n-Butyl-acrylate, Acrylic acid, n-Butyl alcohol, Heteropolyacid

Abstract: The catalytic activities of some heteropolyacids(HPAs) in synthesizing butyl-acrylate are reported. It has been demonstrated that 12-tungstophosphoric acid is the most effective catalyst among more than 20 HPA(salts). Various factors concerned in this reaction have been investigated. The optimum conditions have been found, that is, the molar ratio of alcohol to acid is 1.2∶1.0 , the catalyst concentration 1%(mass fraction), the reaction time 2 h, the temperature 98—124 ℃ and a certain amount of polymerization inhibitor exists.

Key words: n-Butyl-acrylate, Acrylic acid, n-Butyl alcohol, Heteropolyacid