The Synthesis of Star Style Metalloporphyrin

高等学校化学研究 ›› 1997, Vol. 13 ›› Issue (4): 299-303.

The Synthesis of Star Style Metalloporphyrin

TONG Shan-ling¹, ZHA NG Jing-yan², ZHEN Kai-ji², FANG Chi-guang²

1. Changchun Light Industry School, Changchun 130021;
2. Dep ar tment of Chemistry, Jilin University, Changchun, 130023;
3. The Heal th&A nt i-ep idemic Station of Jilin, Changchun, 130021

收稿日期:1996-10-10 出版日期:1997-12-24 发布日期:2011-08-17
基金资助:
Support by the Fund of Chinese Doctoral Site.

The Synthesis of Star Style Metalloporphyrin

TONG Shan-ling¹, ZHA NG Jing-yan², ZHEN Kai-ji², FANG Chi-guang²

1. Changchun Light Industry School, Changchun 130021;
2. Dep ar tment of Chemistry, Jilin University, Changchun, 130023;
3. The Heal th&A nt i-ep idemic Station of Jilin, Changchun, 130021

Received:1996-10-10 Online:1997-12-24 Published:2011-08-17
Supported by:
Support by the Fund of Chinese Doctoral Site.

摘要/Abstract

摘要： The present paper covers a novel star style metalloporphyrin [tetra(4-(4'-methoxycarbonylbenzoxyl)phenyl)porphyrin cobalt, TMBPPCo] with four paw groups [4-(4'-methoxycarbonylbenzoxyl)phenyl(—C₆H₄CO₂C₆H₄CO₂CH ₃)]. Its structure was characterized by means of UV-Vis, IR, ¹H NMR and MS spectrometries.

关键词: Metalloporphyrin, Paw group, Characterization

Abstract: The present paper covers a novel star style metalloporphyrin [tetra(4-(4'-methoxycarbonylbenzoxyl)phenyl)porphyrin cobalt, TMBPPCo] with four paw groups [4-(4'-methoxycarbonylbenzoxyl)phenyl(—C₆H₄CO₂C₆H₄CO₂CH ₃)]. Its structure was characterized by means of UV-Vis, IR, ¹H NMR and MS spectrometries.

Key words: Metalloporphyrin, Paw group, Characterization

TONG Shan-ling, ZHA NG Jing-yan, ZHEN Kai-ji, FANG Chi-guang . The Synthesis of Star Style Metalloporphyrin[J]. 高等学校化学研究, 1997, 13(4): 299-303.

TONG Shan-ling, ZHA NG Jing-yan, ZHEN Kai-ji, FANG Chi-guang . The Synthesis of Star Style Metalloporphyrin[J]. Chemical Research in Chinese Universities, 1997, 13(4): 299-303.

[1]	LIU Zailun, SUN Like, ZHANG Qitao, TENG Zhenyuan, SUN Hongli, SU Chenliang. TiO₂-supported Single-atom Catalysts: Synthesis, Structure, and Application[J]. 高等学校化学研究, 2022, 38(5): 1123-1138.
[2]	WANG Lu, WANG Dong. Two-dimensional Covalent Organic Frameworks: Tessellation by Synthetic Art[J]. 高等学校化学研究, 2022, 38(2): 265-274.
[3]	HE Qian, ZHANG Ying, XIAO Huajian, HE Xiaohui, ZHOU Xiantai, JI Hongbing. Facile Synthesis of Metalloporphyrins-Ba²⁺ Composites as Recyclable and Efficient Catalysts for Olefins Epoxidation Reactions[J]. 高等学校化学研究, 2019, 35(2): 251-255.
[4]	YANG Dalei, HU Wei. Study on Refined Triticale Straw Reinforced PP Composites[J]. 高等学校化学研究, 2015, 31(5): 873-877.
[5]	CHANG Qing, LI Li, YANG Dalei, ZHANG Mingyao, TON-THAT Minh-Tan, HU Wei, LÜ Shuai. Synthesis and Characterization of Poly(ω-pentadecalactone) for Its Industrial-scale Production[J]. 高等学校化学研究, 2015, 31(4): 640-644.
[6]	YANG Yu, XU Wenyan, HU Yanjing, WANG Lei, HUANG Keke. Multi-component Hydrogen-bonding Organic Salts Formed from 1-Methylpiperazine with Aromatic Carboxylic Acids: Synthons Cooperation and Crystal Structures[J]. 高等学校化学研究, 2015, 31(1): 9-15.
[7]	LU Sheng-li, GENG Rui. Efficient Hybrid Photovoltaic Devices Based on in-situ Electrochemical Copolymerization of 3-Methylthiophene and Bithiophene into Pores of Nanocrystalline TiO₂[J]. 高等学校化学研究, 2013, 29(6): 1208-1213.
[8]	LI Rong, ZHANG Fei, CAO Shu-gui, XIE Gui-qiu, GAO Ren-jun. Expression and Characterization of a Thermostable Acyl-peptide Releasing Enzyme ST0779 from Sulfolobus tokodaii[J]. 高等学校化学研究, 2012, 28(5): 851-855 .
[9]	REN He-jun, LU Yang, ZHOU Rui, DAI Chun-yan, WANG Yan, ZHANG Lan-ying . Molecular Cloning and Characterization of a New Cold-active Extradiol Dioxygenase from a Metagenomic Library Derived from Polychlorinated Biphenyl-contaminated Soil[J]. 高等学校化学研究, 2012, 28(4): 666-671.
[10]	CUI Kun, DING Guang-zhu, CHEN Shi-fu and LIU Jie-ping*. Synthesis, Characterization and Electrochemical Behavior of p-NiO/n-TiO₂/Polyaniline Composites[J]. 高等学校化学研究, 2011, 27(5): 870-874.
[11]	ZHANG Yi-bo, YUAN Li-jia, CHEN Zhao-jie, FU Lu, LU Jia-hui, MENG Qing-fan, .... Purification and Characterization of β-Glucosidase from a Newly Isolated Strain Tolypocladium cylindrosporum Syzx4[J]. 高等学校化学研究, 2011, 27(4): 557-561.
[12]	DAI Jian-ying, ZHANG Li-fu and XIU Zhi-long. AI-2 Key Enzyme S-Ribosylhomocysteinase from Strain Klebsiella pneumoniae CICC 10011 Producing 2,3-Butanediol[J]. 高等学校化学研究, 2011, 27(2): 273-276.
[13]	WANG Lei, LUO Yan-ling, WEN Yong-hong*, LI Guang-hua and FENG Shou-hua. New Zincophosphite with Infinite One-dimensional [Zn(HPO3)(H2PO3)]– Chains: Synthesis, Characterizations and Spectral Properties[J]. 高等学校化学研究, 2011, 27(1): 19-22.
[14]	LU Yang, LIU Xiang-guo, YU Ying, QU He-zhi, YANG Shuo, NING Bo, .... Isolation and Characterization of Two Novel Gene Encoded Alkaline Esterases from an Alkaline Soil Metagenomic Library[J]. 高等学校化学研究, 2010, 26(4): 583-590.
[15]	SUN Hui, XU Ying-kai and XU Guo-zhi. Quantitative ³¹P NMR Analysis of Lignocellulosic Materials in Ionic Liquids[J]. 高等学校化学研究, 2010, 26(3): 488-490.

The Synthesis of Star Style Metalloporphyrin

The Synthesis of Star Style Metalloporphyrin

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价