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高等学校化学研究 ›› 1990, Vol. 6 ›› Issue (4): 317-319.

• Articles • 上一篇    下一篇

Sol-Gel Distribution of Polycondensation Reaction

Li Zesheng, Ba Xlnwu, Sun Jiazhong, Tang Xinyi   

  1. Institute of Theoretical Chemistry and Department of Chemistry, Mm University, Changchun
  • 收稿日期:1990-05-18 出版日期:1990-12-24 发布日期:2011-09-09

Sol-Gel Distribution of Polycondensation Reaction

Li Zesheng, Ba Xlnwu, Sun Jiazhong, Tang Xinyi   

  1. Institute of Theoretical Chemistry and Department of Chemistry, Mm University, Changchun
  • Received:1990-05-18 Online:1990-12-24 Published:2011-09-09

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摘要： Atheoretical approach to polycondensation reaction of Aa-Bb type Involving intramolecular cycllzatlon has been proposed by Tang Au-chin et al.. In this paper, the theoretical sol-gel distribution is tested by polycondensation of adipic acid with trimethylol propane in a sto-ichiometric ratio of 0.8, and the effect of intramolecular cyclization is discussed in detail.

关键词: Polycondensation reaction, Sol-gel distribution, Effect of intramolecular cyclization

Abstract: Atheoretical approach to polycondensation reaction of Aa-Bb type Involving intramolecular cycllzatlon has been proposed by Tang Au-chin et al.. In this paper, the theoretical sol-gel distribution is tested by polycondensation of adipic acid with trimethylol propane in a sto-ichiometric ratio of 0.8, and the effect of intramolecular cyclization is discussed in detail.

Key words: Polycondensation reaction, Sol-gel distribution, Effect of intramolecular cyclization