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高等学校化学研究 ›› 1988, Vol. 4 ›› Issue (2): 45-53.

• Articles • 上一篇    下一篇

Syntheses and Structures of Rare Earth Nitrate Complexes with 2.6-Diacetylpyridinebis(Semicarbazone)

Pan Xiangyang1, Yan Shiping1, Wang Genglin1, Wang Honggen2, Wang Ruji2, Yao Xinkan2   

  1. 1. Department of Chemistry, Nankai University, Tianjin;

    2. Test center, Nankai University, Tianjin
  • 收稿日期:1987-03-10 出版日期:1988-04-24 发布日期:2011-09-09

Syntheses and Structures of Rare Earth Nitrate Complexes with 2.6-Diacetylpyridinebis(Semicarbazone)

Pan Xiangyang1, Yan Shiping1, Wang Genglin1, Wang Honggen2, Wang Ruji2, Yao Xinkan2   

  1. 1. Department of Chemistry, Nankai University, Tianjin;

    2. Test center, Nankai University, Tianjin
  • Received:1987-03-10 Online:1988-04-24 Published:2011-09-09

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摘要： Six rare earth nitrate complexes of 2, 6-diacetylpyridinebis (semicarbazone) (DAPSC) were synthesized and characterized by elemental analysis, IR spectra and electrical conductance. Molecular and crystal structures of complex [Sm(DAPSC)(NO3)2(EtOH)]NO3 were determined by X-ray diffraction method. C13H21N10O12 Sm crystallized in the monoclinic apace group C2/c with the following unit-cell constants, a=16.674(2)Å, b = 10. 715(2)Å, c = 25.242(4)Å . β = 100.077(11)°; z=8, the final R factor is 0.025. The coordination number of Sm3+ is ten.

Abstract: Six rare earth nitrate complexes of 2, 6-diacetylpyridinebis (semicarbazone) (DAPSC) were synthesized and characterized by elemental analysis, IR spectra and electrical conductance. Molecular and crystal structures of complex [Sm(DAPSC)(NO3)2(EtOH)]NO3 were determined by X-ray diffraction method. C13H21N10O12 Sm crystallized in the monoclinic apace group C2/c with the following unit-cell constants, a=16.674(2)Å, b = 10. 715(2)Å, c = 25.242(4)Å . β = 100.077(11)°; z=8, the final R factor is 0.025. The coordination number of Sm3+ is ten.