Visible Light-driven Self-healable Mechanochromic Polyurethanes

doi:10.1007/s40242-023-3118-x

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (5): 757-762.doi: 10.1007/s40242-023-3118-x

Visible Light-driven Self-healable Mechanochromic Polyurethanes

HAN Jinpeng¹, YUAN Yuan¹, CHEN Yulan^1,2

1. Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300354, P. R. China;
2. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2023-05-10 出版日期:2023-10-01 发布日期:2023-09-26
通讯作者: YUAN Yuan, CHEN Yulan E-mail:yyuan@tju.edu.cn;yulanchen@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.21734006, 21975178 and 22275068), the Open Project of the State Key Laboratory of Supramolecular Structure and Materials, and the National Key Research and Development Program of China (No.2022YFF1202902).

Visible Light-driven Self-healable Mechanochromic Polyurethanes

HAN Jinpeng¹, YUAN Yuan¹, CHEN Yulan^1,2

1. Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin 300354, P. R. China;
2. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2023-05-10 Online:2023-10-01 Published:2023-09-26
Contact: YUAN Yuan, CHEN Yulan E-mail:yyuan@tju.edu.cn;yulanchen@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21734006, 21975178 and 22275068), the Open Project of the State Key Laboratory of Supramolecular Structure and Materials, and the National Key Research and Development Program of China (No.2022YFF1202902).

摘要/Abstract

摘要： Polyurethanes incorporating spiropyran (SP) and diselenide (DiSe) in the main chain, which are confined in different hard segments are developed. Visible light-driven diselenide metathesis and mechanically induced ring opening of SP offer self-healing and mechanochromic properties of the polymers, respectively. Delicate selection of the polymer backbone is found essential to promote the dual functions. In particular for polyurethane with SP coupled into 4,4'-methylenebis(cyclohexyl isocyanate) and DiSe linked with isophorone diisocyanate, excellent mechanical, mechanochromic and self-healing properties are estimated. Moreover, combining self-healing and self-reporting moieties in one chain allows the discrimination of different healing mechanisms, including bond formation and chain entanglement, in a visualized way.

关键词: Self-healing, Self-reporting, Polyurethane, Mechano-chromic, Diselenide

Abstract: Polyurethanes incorporating spiropyran (SP) and diselenide (DiSe) in the main chain, which are confined in different hard segments are developed. Visible light-driven diselenide metathesis and mechanically induced ring opening of SP offer self-healing and mechanochromic properties of the polymers, respectively. Delicate selection of the polymer backbone is found essential to promote the dual functions. In particular for polyurethane with SP coupled into 4,4'-methylenebis(cyclohexyl isocyanate) and DiSe linked with isophorone diisocyanate, excellent mechanical, mechanochromic and self-healing properties are estimated. Moreover, combining self-healing and self-reporting moieties in one chain allows the discrimination of different healing mechanisms, including bond formation and chain entanglement, in a visualized way.

Key words: Self-healing, Self-reporting, Polyurethane, Mechano-chromic, Diselenide

HAN Jinpeng, YUAN Yuan, CHEN Yulan. Visible Light-driven Self-healable Mechanochromic Polyurethanes[J]. 高等学校化学研究, 2023, 39(5): 757-762.

HAN Jinpeng, YUAN Yuan, CHEN Yulan. Visible Light-driven Self-healable Mechanochromic Polyurethanes[J]. Chemical Research in Chinese Universities, 2023, 39(5): 757-762.

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Visible Light-driven Self-healable Mechanochromic Polyurethanes

Visible Light-driven Self-healable Mechanochromic Polyurethanes

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