Gold and Silver Nanoparticles Supported on Metal-organic Frameworks: a Highly Active Catalyst for Three-component Coupling Reaction

doi:10.1007/s40242-016-5435-9

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (3): 443-450.doi: 10.1007/s40242-016-5435-9

Gold and Silver Nanoparticles Supported on Metal-organic Frameworks: a Highly Active Catalyst for Three-component Coupling Reaction

LIU Lili¹, TAI Xishi¹, YU Guanglin², GUO Huanmei¹, MENG Qingguo¹

1. School of Chemistry &Chemical Engineering and Environmental Engineering, Weifang University, Weifang 261061, P. R. China;
2. School of Environment, Tsinghua University, Beijing 100084, P. R. China

收稿日期:2015-11-08 修回日期:2015-12-18 出版日期:2016-06-01 发布日期:2015-12-26
通讯作者: LIU Lili, TAI Xishi E-mail:liulili122@126.com;taixishi@lzu.edu.cn
基金资助:
Supported by the Promotive Research Fund for Young and Middle-aged Scientists of Shandong Province, China (Nos.BS2014CL021, BS2015CL012), the Natural Science Foundation of Shandong Province, China(Nos.ZR2014BL003, ZR2015BM005), the Project of Shandong Province Higher Educational Science and Technology Program, China(Nos.J14LC01, J15LA09) and the Technology Research and Development Program of Weifang, China(No.201301035)

Gold and Silver Nanoparticles Supported on Metal-organic Frameworks: a Highly Active Catalyst for Three-component Coupling Reaction

LIU Lili¹, TAI Xishi¹, YU Guanglin², GUO Huanmei¹, MENG Qingguo¹

1. School of Chemistry &Chemical Engineering and Environmental Engineering, Weifang University, Weifang 261061, P. R. China;
2. School of Environment, Tsinghua University, Beijing 100084, P. R. China

Received:2015-11-08 Revised:2015-12-18 Online:2016-06-01 Published:2015-12-26
Contact: LIU Lili, TAI Xishi E-mail:liulili122@126.com;taixishi@lzu.edu.cn
Supported by:
Supported by the Promotive Research Fund for Young and Middle-aged Scientists of Shandong Province, China (Nos.BS2014CL021, BS2015CL012), the Natural Science Foundation of Shandong Province, China(Nos.ZR2014BL003, ZR2015BM005), the Project of Shandong Province Higher Educational Science and Technology Program, China(Nos.J14LC01, J15LA09) and the Technology Research and Development Program of Weifang, China(No.201301035)

摘要/Abstract

摘要：

Engineering metal-organic frameworks(MOF) for heterogeneous catalysts have been of extreme interest since they have large pore size within the crystalline framework and well defined pore architecture. Ni-containing MOF Ni₂(3,5-Pydc)₂(H₂O)₈·2H₂O(1·H₂O) was prepared by solvothermal method from 3,5-pyridinedicarboxylic acid, D-camphoric acid and Ni(NO₃)₂·6H₂O in dimethylformamide(DMF)/water(volume ratio 2:1). And two gold and silver functionalized 1·H₂O catalysts were prepared by impregnation method. Catalysts 2.53%Au/MOF and 4.23%Ag/MOF were in-depth characterized by single crystal X-ray diffraction, powder X-ray diffraction(PXRD), thermogravimetric analysis(TGA), transmission electron microscopy(TEM), and inductively coupled plasma-atomic emission spectroscopy(ICP-AES). Their catalytic performance was examined in one-pot synthesis of structurally divergent propargylamines via three component coupling of aldehyde, alkyne, and amine(A³) in 1,4-dioxane. The results show that the catalysts all displayed high reactivities, and a selectivity of 100% for propargylamines. Catalysts 2.53%Au/MOF and 4.23%Ag/MOF have proved to be applicable to a wide range of substrates. Catalysts 2.53%Au/MOF and 4.23%Ag/MOF can be easily recycled and used repetitively at least 3 times with a slight drop in activity. These features render the catalysts particularly attractive in the practice of propargylamines synthesis in an environmentally friendly manner.

关键词: Metal-organic framework, Three component coupling reaction, Gold, Silver, Immobilization

Abstract:

Key words: Metal-organic framework, Three component coupling reaction, Gold, Silver, Immobilization

LIU Lili, TAI Xishi, YU Guanglin, GUO Huanmei, MENG Qingguo. Gold and Silver Nanoparticles Supported on Metal-organic Frameworks: a Highly Active Catalyst for Three-component Coupling Reaction[J]. 高等学校化学研究, 2016, 32(3): 443-450.

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Gold and Silver Nanoparticles Supported on Metal-organic Frameworks: a Highly Active Catalyst for Three-component Coupling Reaction

Gold and Silver Nanoparticles Supported on Metal-organic Frameworks: a Highly Active Catalyst for Three-component Coupling Reaction

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