高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (5): 801-808.doi: 10.1007/s40242-015-5140-0
Dipyrrin-based Complexes for Solution-processed Organic Solar Cells
ZOU Liyun1, GUAN Shuang2, LI Leijiao3, ZHAO Li1
- 1. School of Life Sciences, Jilin University, Changchun 130012, P. R. China;
2. College of Chemistry and Life Sciences, Changchun University of Techology, Changchun 130012, P. R. China;
3. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
Dipyrrin-based Complexes for Solution-processed Organic Solar Cells
ZOU Liyun1, GUAN Shuang2, LI Leijiao3, ZHAO Li1
- 1. School of Life Sciences, Jilin University, Changchun 130012, P. R. China;
2. College of Chemistry and Life Sciences, Changchun University of Techology, Changchun 130012, P. R. China;
3. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
摘要：
Three dipyrrin-containing metal complexes and a boron dipyrromethene(BODIPY)-containing complex were designed and synthesized. The photophysical properties, electrochemical behaviours and photovoltaic performance were extensively investigated. Density functional theory calculations were also performed on those complexes. These complexes, together with electron-acceptor [6,6]-phenyl-C71-butyric acid methyl ester, were utilized for the fabrication of solution-processed bulk heterojunction solar cells as the electron-donor materials. The more efficient electron acceptor BODIPY segment renders a lower energy gap and a relatively better photovoltaic conversion efficiency of 0.58%. These results prove that BODIPY segment has a great potential for constructing efficient organic solar cell materials.