One-step Synthesis of 5-Ethyl-2-methylpyridine from NH4HCO3 and C2H5OH Under Hydrothermal Condition

doi:10.1007/s40242-015-4297-x

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (2): 249-252.doi: 10.1007/s40242-015-4297-x

One-step Synthesis of 5-Ethyl-2-methylpyridine from NH₄HCO₃ and C₂H₅OH Under Hydrothermal Condition

TIAN Zhenzhen¹, ZHANG Dong², GUO Biao¹, TIAN Ge¹, LIU Xinxin¹, YUE Huijuan¹, FENG Shouhua¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Key Laboratory of Physics and Technology for Advance Batteries, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China

收稿日期:2014-08-04 修回日期:2014-12-01 出版日期:2015-04-01 发布日期:2014-12-29
通讯作者: YUE Huijuan E-mail:huijuan@jlu.edu.cn
基金资助:
Supported by the Natural Science Foundation of Jilin Province, China(No.201215028), the S&T Development Program of Jilin Province, China(Nos.20130522128JH, 20140520078JH, 20150204030GX) and the National Natural Science Foundation of China(Nos.21201073, 21401070).

One-step Synthesis of 5-Ethyl-2-methylpyridine from NH₄HCO₃ and C₂H₅OH Under Hydrothermal Condition

TIAN Zhenzhen¹, ZHANG Dong², GUO Biao¹, TIAN Ge¹, LIU Xinxin¹, YUE Huijuan¹, FENG Shouhua¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Key Laboratory of Physics and Technology for Advance Batteries, Ministry of Education, College of Physics, Jilin University, Changchun 130012, P. R. China

Received:2014-08-04 Revised:2014-12-01 Online:2015-04-01 Published:2014-12-29
Contact: YUE Huijuan E-mail:huijuan@jlu.edu.cn
Supported by:
Supported by the Natural Science Foundation of Jilin Province, China(No.201215028), the S&T Development Program of Jilin Province, China(Nos.20130522128JH, 20140520078JH, 20150204030GX) and the National Natural Science Foundation of China(Nos.21201073, 21401070).

摘要/Abstract

摘要：

A simple one-pot approach to synthesizing 5-ethyl-2-methylpyridine(EMP) was established using NH₄HCO₃ and C₂H₅OH as starting materials and commercial Cu₂O as catalyst and oxidant under hydrothermal condition. Different reaction conditions were researched and the optimal ones were achieved by studying the parameters, that could affect the yield of product and by considering the energy and resource saving. The present study provided an eco-friendly way to obtaining EMP with lower volatility using fewer toxic starting materials.

关键词: 5-Ethyl-2-methylpyridine, Hydrothermal condition, NH₄HCO₃, C₂H₅OH, Cu₂O

Abstract:

Key words: 5-Ethyl-2-methylpyridine, Hydrothermal condition, NH₄HCO₃, C₂H₅OH, Cu₂O

TIAN Zhenzhen, ZHANG Dong, GUO Biao, TIAN Ge, LIU Xinxin, YUE Huijuan, FENG Shouhua. One-step Synthesis of 5-Ethyl-2-methylpyridine from NH₄HCO₃ and C₂H₅OH Under Hydrothermal Condition[J]. 高等学校化学研究, 2015, 31(2): 249-252.

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One-step Synthesis of 5-Ethyl-2-methylpyridine from NH₄HCO₃ and C₂H₅OH Under Hydrothermal Condition

One-step Synthesis of 5-Ethyl-2-methylpyridine from NH₄HCO₃ and C₂H₅OH Under Hydrothermal Condition

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