高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (5): 874-878.doi: 10.1007/s40242-014-3507-2
• Articles • 上一篇
Synthesis and Characterization of Dinuclear Aluminum Complexes Bearing N,N-Dialkylaniline-amido Ligands and Its Catalytic Properties for Lactone Polymerization
HAN Yancheng1, ZHU Guangyun1, ZHANG Mengmeng1, WANG Shuai1, YAO Wei1,2, GAO Aihong1,2, LU Ping3
- 1. School of Resources and Environment, Jinan 250022, P. R. China;
2. Shandong Provincial Engineering Research Center for Ecological Carbon Sink and Capture Utilization, Jinan 250022, P. R. China;
3. School of Chemistry, University of Jinan, Jinan 250022, P. R. China
Synthesis and Characterization of Dinuclear Aluminum Complexes Bearing N,N-Dialkylaniline-amido Ligands and Its Catalytic Properties for Lactone Polymerization
HAN Yancheng1, ZHU Guangyun1, ZHANG Mengmeng1, WANG Shuai1, YAO Wei1,2, GAO Aihong1,2, LU Ping3
- 1. School of Resources and Environment, Jinan 250022, P. R. China;
2. Shandong Provincial Engineering Research Center for Ecological Carbon Sink and Capture Utilization, Jinan 250022, P. R. China;
3. School of Chemistry, University of Jinan, Jinan 250022, P. R. China
摘要：
Two ligands[ortho-C6H4NR2(CH2NH)]2CH2CH2(3: R=Me; 4: R=Et) were prepared by the reduction of preligands[ortho-C6H4NR2(CH=N)]2CH2CH2(1: R=Me; 2: R=Et). These ligands reacted with AlMe3 to afford the corresponding dinuclear aluminum complexes {AlMe2[ortho-C6H4NR2(CH2N)]}2CH2CH2(5: R=Me; 6: R=Et). All the compounds were characterized by 1H and 13C nuclear magnetic resonance(NMR) spectroscopies and elemental analyses. The catalytic properties of the aluminum complexes towards the ring-opening polymerization of lactones were investigated in the presence of benzyl alcohol. All the polymerization reactions were proceeded in a controlled manner.