Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber

doi:10.1007/s40242-013-2236-2

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (2): 256-262.doi: 10.1007/s40242-013-2236-2

Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber

XIAO Jia, LI Guo-wei, ZHANG Wen-qin

Department of Chemistry, School of Sciences, Tianjin University, Tianjin 300072, P. R. China

收稿日期:2012-06-18 修回日期:2012-08-15 出版日期:2013-04-01 发布日期:2013-03-20
通讯作者: ZHANG Wen-qin E-mail:zhangwenqin@tju.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20834002).

Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber

XIAO Jia, LI Guo-wei, ZHANG Wen-qin

Department of Chemistry, School of Sciences, Tianjin University, Tianjin 300072, P. R. China

Received:2012-06-18 Revised:2012-08-15 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the National Natural Science Foundation of China(No.20834002).

摘要/Abstract

摘要：

A proline functionalized fiber catalyst was employed for aldol reactions in water. In the presence of the fiber catalyst, the aldol reactions proceeded smoothly at 40℃ and the products were obtained in excellent yields which were higher than those obtained for the reactions catalyzed by L-proline or trans-4-hydroxy-L-proline. This newly developed fiber catalyst is applicable to the reactions of a wide range of aromatic aldehydes and exhibits excellent reusability(up to 6 times) without any additional treatment.

关键词: Polyacrylonitrile fiber(PANF), Proline, Aldol reaction, Supported catalyst

Abstract:

Key words: Polyacrylonitrile fiber(PANF), Proline, Aldol reaction, Supported catalyst

XIAO Jia, LI Guo-wei, ZHANG Wen-qin. Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber[J]. 高等学校化学研究, 2013, 29(2): 256-262.

XIAO Jia, LI Guo-wei, ZHANG Wen-qin. Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber[J]. Chemical Research in Chinese Universities, 2013, 29(2): 256-262.

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Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber

Aldol Reactions Catalyzed by Proline Functionalized Polyacrylonitrile Fiber

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