Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

doi:10.1007/s40242-013-2234-4

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (2): 384-388.doi: 10.1007/s40242-013-2234-4

Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

XU Da, ZHANG Yu-xuan, REN Dian-fu, CHEN Xing-bo, ZHANG Hai-bo, JIANG Zhen-hua

College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2012-06-16 修回日期:2012-07-15 出版日期:2013-04-01 发布日期:2013-03-20
通讯作者: ZHANG Hai-bo E-mail:zhanghaib@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.51103060).

Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

XU Da, ZHANG Yu-xuan, REN Dian-fu, CHEN Xing-bo, ZHANG Hai-bo, JIANG Zhen-hua

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2012-06-16 Revised:2012-07-15 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the National Natural Science Foundation of China(No.51103060).

摘要/Abstract

摘要：

A series of azobenzene functionalized poly(aryl ether) copolymers(azo-PAEs) containing azo moieties on pendants was prepared by direct copolymerization. The amount of azobenzene chromophores could be controlled by the feed ratio of azo-monomer. Their chemical structures and properties were characterized by means of infrared(IR) spectrometry, UV-Vis, hydrogen nuclear magnetic resonance(¹H NMR), difference scanning calorimetry(DSC), and thermogravimetric analysis(TGA). The results suggest that azo-PAEs had high glass transition temperatures(T_gs) and good thermal stability. By exposing their spin-coated films to an interference pattern laser beam, azo-PAEs could be used for the fabrication of thermal stable surface relief gratings(SRGs).

关键词: Azo polymer, Poly(aryl ether), Surface relief grating, Photoactive

Abstract:

Key words: Azo polymer, Poly(aryl ether), Surface relief grating, Photoactive

XU Da, ZHANG Yu-xuan, REN Dian-fu, CHEN Xing-bo, ZHANG Hai-bo, JIANG Zhen-hua. Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings[J]. 高等学校化学研究, 2013, 29(2): 384-388.

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Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

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