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高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (1): 26-29.doi: 10.1007/s40242-013-2171-2

• Articles • 上一篇    下一篇

Novel Method for Indirect Determination of Iodine in Marine Products by Atomic Fluorescence Spectrometry

LU Jian-ping1, TAN Fang-wei1, TANG Qiong1, JIANG Tian-cheng2   

  1. 1. College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P. R. China;
    2. Guangxi Center of Analysis and Test Research, Nanning 530022, P. R. China
  • 收稿日期:2012-04-28 修回日期:2012-06-20 出版日期:2013-02-01 发布日期:2013-01-23
  • 基金资助:

    Supported by the Science and Technology Basic Condition Platform Construction Project of Guangxi Zhuang Autonomous Region, China (No.07-105-002-04).

Novel Method for Indirect Determination of Iodine in Marine Products by Atomic Fluorescence Spectrometry

LU Jian-ping1, TAN Fang-wei1, TANG Qiong1, JIANG Tian-cheng2   

  1. 1. College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, P. R. China;
    2. Guangxi Center of Analysis and Test Research, Nanning 530022, P. R. China
  • Received:2012-04-28 Revised:2012-06-20 Online:2013-02-01 Published:2013-01-23
  • Supported by:

    Supported by the Science and Technology Basic Condition Platform Construction Project of Guangxi Zhuang Autonomous Region, China (No.07-105-002-04).

PDF (PC)

被引次数

8

摘要：

A method for the determination of iodine based upon compound H2HgI4, formed between I- and Hg2+ in nitric acid and extracted in methyl isobutyl ketone(MIBK), was developed via atomic fluorescence spectrometry(AFS). After the compound is reduced with potassium borohydrid(KBH4), the resultant mercury vapor was injected into the instrument and iodine was, therefore, indirectly determined. Experimental parameters such as the conditions of extraction reagents, aqueous phase acidity, elemental mercury diffusion temperature in a vial and other factors were investigated and optimized. Under the optimum experimental conditions, this method shows a detection limit of 0.038 μg/L iodine and a linear relationship between 0.04―20 μg/L. The method was applied to determining the iodine content in marine duck eggs, kelps, laver and Ganoderma lucidum spirulina, showing a relative standard deviation(RSD) of 2.15% and the recoveries in the range of 98.1%―102.5%.

关键词: Methyl isobutyl ketone, Gas injection, Atomic fluorescence spectrometer(AFS), Indirect determination, Iodine

Abstract:

A method for the determination of iodine based upon compound H2HgI4, formed between I- and Hg2+ in nitric acid and extracted in methyl isobutyl ketone(MIBK), was developed via atomic fluorescence spectrometry(AFS). After the compound is reduced with potassium borohydrid(KBH4), the resultant mercury vapor was injected into the instrument and iodine was, therefore, indirectly determined. Experimental parameters such as the conditions of extraction reagents, aqueous phase acidity, elemental mercury diffusion temperature in a vial and other factors were investigated and optimized. Under the optimum experimental conditions, this method shows a detection limit of 0.038 μg/L iodine and a linear relationship between 0.04―20 μg/L. The method was applied to determining the iodine content in marine duck eggs, kelps, laver and Ganoderma lucidum spirulina, showing a relative standard deviation(RSD) of 2.15% and the recoveries in the range of 98.1%―102.5%.

Key words: Methyl isobutyl ketone, Gas injection, Atomic fluorescence spectrometer(AFS), Indirect determination, Iodine