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高等学校化学研究 ›› 2010, Vol. 26 ›› Issue (6): 1011-1015.

• Articles • 上一篇    下一篇

Spectroscopic Studies on Co(II), Ni(II), Zn(II) Complexes with 4,4'-Bipyridine

SHI Xiu-min1,2, WANG Hai-yan3, LI Yan-bing2, YANG Jing-xiu1, CHEN Lei1, HUI Ge1, XU Wei-qing1 and ZHAO Bing1*   

  1. 1. State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P. R. China;
    2. College of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
    3. The Second Hospital, Jilin University, Changchun 130041, P. R. China
  • 收稿日期:2009-11-30 修回日期:2010-01-22 出版日期:2010-11-25 发布日期:2010-12-01
  • 通讯作者: ZHAO Bing E-mail:zhaobing@jlu.edu.cn
  • 作者简介:ZHAO Bing. E-mail: zhaobing@jlu.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China(Nos.20773044, 20873050, 20921003 and 20973074) and the “111” Project of Minstry of Education of China(No.B06009).

Spectroscopic Studies on Co(II), Ni(II), Zn(II) Complexes with 4,4'-Bipyridine

SHI Xiu-min1,2, WANG Hai-yan3, LI Yan-bing2, YANG Jing-xiu1, CHEN Lei1, HUI Ge1, XU Wei-qing1 and ZHAO Bing1*   

  1. 1. State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P. R. China;
    2. College of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
    3. The Second Hospital, Jilin University, Changchun 130041, P. R. China
  • Received:2009-11-30 Revised:2010-01-22 Online:2010-11-25 Published:2010-12-01
  • Contact: ZHAO Bing E-mail:zhaobing@jlu.edu.cn
  • About author:ZHAO Bing. E-mail: zhaobing@jlu.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China(Nos.20773044, 20873050, 20921003 and 20973074) and the “111” Project of Minstry of Education of China(No.B06009).

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摘要： Fourier-transform infrared(FTIR), Raman and ultraviolet-visible spectra of 4,4'-bipyridine and its me- tal-organic coordination compounds synthesized from 4,4'-bipyridine and nitrate of Co(II), Ni(II) and Zn(II) were measured and analyzed, respectively. The main FTIR and Raman bands were assigned in detail. The relationship  between these characteristic bands and the structure of ligands and coordination compounds were discussed.

关键词: 4,4'-Bipyridine, Infrared spectrum, Raman spectrum, Ultraviolet-Visible spectrum

Abstract: Fourier-transform infrared(FTIR), Raman and ultraviolet-visible spectra of 4,4'-bipyridine and its me- tal-organic coordination compounds synthesized from 4,4'-bipyridine and nitrate of Co(II), Ni(II) and Zn(II) were measured and analyzed, respectively. The main FTIR and Raman bands were assigned in detail. The relationship  between these characteristic bands and the structure of ligands and coordination compounds were discussed.

Key words: 4,4'-Bipyridine, Infrared spectrum, Raman spectrum, Ultraviolet-Visible spectrum