A Fluorescent In (III) Metal-Organic Framework for Explosives Detection

doi:10.1007/s40242-023-3058-5

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (6): 1005-1009.doi: 10.1007/s40242-023-3058-5

A Fluorescent In (III) Metal-Organic Framework for Explosives Detection

LI Wen¹, LIU Xinyao^1,2, LI Guanghua¹, and LIU Yunling¹

1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China;
2. Sinochem Holdings Corporation Ltd., Beijing 100031, P.R. China

收稿日期:2023-03-03 出版日期:2023-12-01 发布日期:2023-11-18
通讯作者: LIU Yunling E-mail:yunling@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.22171100, 22288101) and the “111” Project of China (No.B17020).

A Fluorescent In (III) Metal-Organic Framework for Explosives Detection

LI Wen¹, LIU Xinyao^1,2, LI Guanghua¹, and LIU Yunling¹

1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China;
2. Sinochem Holdings Corporation Ltd., Beijing 100031, P.R. China

Received:2023-03-03 Online:2023-12-01 Published:2023-11-18
Contact: LIU Yunling E-mail:yunling@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.22171100, 22288101) and the “111” Project of China (No.B17020).

摘要/Abstract

摘要： Anovel metal-organic framework {[In₃(TATAT)₂]·3CH₃NH₃· 7NMF·8H₂O}[JLU-MOF101, H₆TATAT=5,5’,5’’-(1,3,5-triazine- 2,4,6-triyl)tris-(azanediyl)triisophthalate, NMF=N-methyl- formamide] with cor topology has been synthesized under solvothermal conditions. The framework of JLU-MOF101 is constructed by {In(COO)₄}^- nodes and a hexacarboxylic organic ligand. JLU-MOF101 exhibits excellent fluorescence properties in N,N-dimethylformamide (DMF) solution, and its emission spectrum can be greatly overlapped with the ultraviolet absorption spectra of trinitrophenol (TNP) and 2,4-dinitrophenol (2,4-DNP). As a result, JLU-MOF101 exhibits excellent performance of fluorescence quenching for TNP and 2,4-DNP. In addition, we demonstrate the selective detection capability of JLU-MOF101 through a large number of anti-interference tests.

关键词: Selective detection, Indium metal-organic framework, Fluorescent detection, Nitroaromatic explosive

Abstract: Anovel metal-organic framework {[In₃(TATAT)₂]·3CH₃NH₃· 7NMF·8H₂O}[JLU-MOF101, H₆TATAT=5,5’,5’’-(1,3,5-triazine- 2,4,6-triyl)tris-(azanediyl)triisophthalate, NMF=N-methyl- formamide] with cor topology has been synthesized under solvothermal conditions. The framework of JLU-MOF101 is constructed by {In(COO)₄}^- nodes and a hexacarboxylic organic ligand. JLU-MOF101 exhibits excellent fluorescence properties in N,N-dimethylformamide (DMF) solution, and its emission spectrum can be greatly overlapped with the ultraviolet absorption spectra of trinitrophenol (TNP) and 2,4-dinitrophenol (2,4-DNP). As a result, JLU-MOF101 exhibits excellent performance of fluorescence quenching for TNP and 2,4-DNP. In addition, we demonstrate the selective detection capability of JLU-MOF101 through a large number of anti-interference tests.

Key words: Selective detection, Indium metal-organic framework, Fluorescent detection, Nitroaromatic explosive

LI Wen, LIU Xinyao, LI Guanghua, and LIU Yunling. A Fluorescent In (III) Metal-Organic Framework for Explosives Detection[J]. 高等学校化学研究, 2023, 39(6): 1005-1009.

LI Wen, LIU Xinyao, LI Guanghua, and LIU Yunling. A Fluorescent In (III) Metal-Organic Framework for Explosives Detection[J]. Chemical Research in Chinese Universities, 2023, 39(6): 1005-1009.

参考文献

[1] Ju K. S., Parales R. E., Microbiol. Mol. Biol. Rev., 2010, 74(2), 250
[2] Ramos J. L., Gonzalez-Perez M. M., Caballero A., van Dillewijn P., Curr. Opin. Biotechnol., 2005, 16(3), 275
[3] Tiwari J., Tarale P., Sivanesan S., Bafana A., Environ. Sci. Pollut. Res. Int., 2019, 26(28), 28650
[4] Esteve-Nunez A., Caballero A., Ramos J. L., Microbiol. Mol. Biol. Rev., 2001, 65(3), 335
[5] Chhatwal M., Mittal R., Gupta R. D., Awasthi S. K., J. Mater. Chem. C, 2018, 6(45), 12142
[6] Caygill J. S., Davis F., Higson S. P., Talanta, 2012, 88, 14
[7] Long J. R., Yaghi O. M., Chem. Soc. Rev., 2009, 38(5), 1213
[8] Zhou H. C., Long J. R., Yaghi O. M., Chem. Rev., 2012, 112(2), 673
[9] Kolle J. M., Fayaz M., Sayari A., Chem Rev., 2021, 121(13), 7280
[10] Lin J. B., Nguyen T. T. T., Vaidhyanathan R., Burner J., Taylor J. M., Durekova H., Akhtar F., Mah R. K., Ghaffari-Nik O., Marx S., Fylstra N., Iremonger S. S., Dawson K. W., Sarkar P., Hovington P., Rajendran A., Woo T. K., Shimizu G. K. H., Science, 2021, 374, 1464
[11] Li J. T., Bhatt P. M., Li J. Y., Eddaoudi M., Liu Y. L., Adv. Mater., 2020, 32(44), e2002563
[12] Zhou S., Shekhah O., Ramirez A., Lyu P., Abou-Hamad E., Jia J., Li J., Bhatt P. M., Huang Z., Jiang H., Jin T., Maurin G., Gascon J., Eddaoudi M., Nature, 2022, 606(7915), 706
[13] Zhou X., Jin, H., Xia B. Y., Davey K., Zheng Y., Qiao S. Z., Adv. Mater., 2021, 33(51), e2104341
[14] Yan R., Ma T., Cheng M., Tao X., Yang Z., Ran F., Li S., Yin B., Cheng C., Yang W., Adv. Mater., 2021, 33(27), e2008784
[15] Wang H., Chen B. H., Liu D. J., Adv. Mater., 2021, 33(25), e2008023
[16] Han D., Liu X., Wu S., Chem. Soc. Rev., 2022, 51(16), 7138
[17] Osterrieth J. W. M., Fairen-Jimenez D., Biotechnol. J., 2021, 16(2), e2000005
[18] Linnane E., Haddad S., Melle F., Mei Z., Fairen-Jimenez D., Chem. Soc. Rev., 2022, 51(14), 6065
[19] Qian Y., Zhang F., Pang H., Adv. Funct. Mater., 2021, 31(37), e2104231
[20] Shen Y., Pan T., Wang L., Ren Z., Zhang W., Huo F., Adv. Mater., 2021, 33(46), e2007442
[21] Hou S. L., Dong J., Zhao B., Adv. Mater. 2020, 32(3), e1806163
[22] Wei Y. S., Zhang M., Zou R., Xu Q., Chem. Rev., 2020, 120(21), 12089
[23] Fu D.-Y., Liu X., Zheng X., Zhou M., Wang W., Su G., Liu T., Wang L., Xie Z., Coord. Chem. Rev., 2022, 456, 214393
[24] Lian H., Cheng X., Hao H., Han J., Lau M. T., Li Z., Zhou Z., Dong Q., Wong W. Y., Chem. Soc. Rev., 2022, 51(6), 1926
[25] Feng Y., Yao J., Coord. Chem. Rev., 2022, 470, 214699
[26] Zhang S., Wang J., Zhang Y., Ma J., Huang L., Yu S., Chen L., Song G., Qiu M., Wang X., Environ. Pollut., 2021, 291, 118076
[27] Moumen E., Bazzi L., Hankari S., Coord. Chem. Rev., 2022, 455, 214376
[28] Kaur M., Kumar S., Yusuf M., Lee J., Brown R. J. C., Kim K.-H., Malik A. K., Coord. Chem. Rev., 2021, 449, 214214
[29] He Y.-P., Tan Y.-X., Zhang J., Coord. Chem. Rev., 2020, 420, 213354
[30] Razavi S. A. A., Morsali A., Chem. Rev., 2020, 415, 213299
[31] Younis S. A., Bhardwaj N., Bhardwaj S. K., Kim K.-H., Deep Coord. Chem. Rev., 2021, 429, 213620
[32] Li H. Y., Zhao S. N., Zang S. Q., Li J., Chem. Soc. Rev., 2020, 49(17), 6364
[33] Luo T. Y., Das P., White D. L., Liu C., Star A., Rosi N. L., J. Am. Chem. Soc., 2020, 142(6), 2897
[34] Li J., Yuan S., Qin J. S., Huang L., Bose R., Pang J., Zhang P., Xiao Z., Tan K., Malko A. V., ACS Appl. Mater. Interfaces, 2020, 12(23), 26727
[35] Liu X., Liu W., Kou Y., Yang X., Ju Z., Liu W., Inorg. Chem. Front., 2022, 9(16), 4065
[36] Dong J., Zhao D., Lu Y., Sun W. Y., J. Mater. Chem. A, 2019, 7(40), 22744
[37] Bhattacharjee S., Bera S., Das R., Chakraborty D., Basu A., Banerjee P., Ghosh S., Bhaumik A., ACS Appl. Mater. Interfaces, 2022, 14(18), 20907
[38] Lei M., Ge F., Ren S., Gao X., Zheng H., Sep. Purif. Technol., 2022, 286, 12433
[39] Goswami R., Das S., Seal N., Pathak B., Neogi S., ACS Appl. Mater. Interfaces, 2021, 13(29), 34012
[40] Seal N., Singh M., Das S., Goswami R., Pathak B., Neogi S., Mater. Chem. Front., 2021, 5(2), 979
[41] Wang B., Liu J. H., Yu J., Lv J., Dong C., Li J. R., J. Hazard. Mater., 2020, 382, 121018
[42] Xing S., Bing Q., Qi H., Liu J., Bai T., Li G., Shi Z., Feng S., Xu R. R., ACS Appl. Mater. Interfaces, 2017, 9(28), 23828
[43] Zeng X. S., Xu H. L., Xu Y. C., Li X. Q., Nie Z. Y., Gao S. Z., Xiao D. R., Inorg. Chem. Front., 2018, 5(7), 1622
[44] Li A., Chu Q., Zhou H., Yang Z., Liu B., Zhang J., Inorg. Chem. Front., 2021, 8(9), 2341
[45] Sun X. D., Li X., Yao S., Krishna R., Gu J. M., Li G., Liu Y. L., J. Mater. Chem. A, 2020, 8(33), 17106
[46] He H. M., Song Y., Sun F. X., Bian Z., Gao L., Zhu G. S., J. Mater. Chem. A, 2015, 3(32), 16598
[47] Xin X. L., Ai J., Li F. G., Zhao J. Q., Zhang L. L., Appl. Organomet. Chem., 2020, 34(9), e5803
[48] Hu M. L., Joharian M., Razavi S. A. A., Morsali A., Wu D. Z., Azhdari Tehrani A., Wang J., Junk P. C., Guo Z. F., J. Hazard. Mater., 2021, 406, 124501
[49] Chakraborty D., Bej S., Sahoo S., Chongdar S., Ghosh A., Banerjee P., Bhaumik A., ACS Sustainable Chem. Eng., 2021, 9(42), 14224
[50] Chatz-Giachia A., Psalti A. E., Pournara A. D., Manos M. J., Pappa C., Triantafyllidis K., Lazarides T. J. Mater. Chem. C, 2022, 10(34), 12307
[51] Liu Y., Xie X.-Y., Cheng C., Shao Z. S., Wang H. S., J. Mater. Chem. C, 2019, 7(35), 10743
[52] Wang B., Lv X. L., Feng D., Xie L. H., Zhang J., Li M., Xie Y., Li J. R., Zhou H. C., J. Am. Chem. Soc., 2016, 138(19), 6204
[53] Qiao J. Y., Liu X. Y., Zhang L. R., Eubank J. F., Liu X., Liu Y. L., J. Am. Chem. Soc., 2022, 144(37), 17054
[54] Chen L., Liu D., Peng J., Du Q., He H., Coord. Chem. Rev., 2020, 404, 213113
[55] Jia C., He T., Wang G. M., Coord. Chem. Rev., 2023, 476, 214930
[56] Kamal S., Khalid M., Khan M. S., Shahid M., Coord. Chem. Rev., 2023, 474, 214859
[57] Frisch M. J., Trucks G. W., Schlegel H. B., Scuseria G. E., Robb M. A., Cheeseman J. R., Scalmani G., Barone V., Mennucci B., Petersson G. A., Nakatsuji H., Caricato M., Li X., Hratchian H. P., Izmaylov A. F., Bloino J., Zheng G., Sonnenberg J. L., Hada M., Ehara M., Toyota K., Fukuda R., Hasegawa J., Ishida M., Nakajima T., Honda Y., Kitao O., Nakai H., Vreven T., Montgomery J. A. Jr., Peralta P. E., Ogliaro F., Bearpark M., Heyd J. J., Brothers E., Kudin K. N., Staroverov V. N., Kobayashi R., Normand J., Raghavachari K., Rendell A., Burant J. C., Iyengar S. S., Tomasi J., Cossi, M., Rega N., Millam N. J., Klene M., Knox J. E., Cross J. B., Bakken V., Adamo C., Jaramillo J., Gomperts R., Stratmann R. E., Yazyev O., Austin A. J., Cammi R., Pomelli C., Ochterski J. W., Martin R. L., Morokuma K., Zakrzewski V. G., Voth G. A., Salvador P., Dannenberg J. J., Dapprich S., Daniels A. D., Farkas Ö., Ortiz J. V., Cioslowski J., Fox D. J., Gaussian 09, revision C.01, Gaussian Inc., Wallingford, CT, 2009

A Fluorescent In (III) Metal-Organic Framework for Explosives Detection

A Fluorescent In (III) Metal-Organic Framework for Explosives Detection

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

编辑推荐

Metrics

本文评价