Bimetallic Au-Pd NPs Embedded in MOF Ultrathin Nanosheets with Tuned Surface Electronic Properties for High-performance Benzyl Alcohol Oxidation

doi:10.1007/s40242-022-2210-y

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (6): 1344-1348.doi: 10.1007/s40242-022-2210-y

Bimetallic Au-Pd NPs Embedded in MOF Ultrathin Nanosheets with Tuned Surface Electronic Properties for High-performance Benzyl Alcohol Oxidation

GUO Taolian^1,2, BAO Shutong², GUO Jie², CHEN Wu¹, WEN Lili^2,3

1. National Local Joint Engineering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University, Wuhan 430200, P. R. China;
2. College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China;
3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

收稿日期:2022-06-26 出版日期:2022-12-01 发布日期:2022-12-06
通讯作者: CHEN Wu, WEN Lili E-mail:wuchen@wtu.edu.cn;wenlili@mail.ccnu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.22171097 and 21771072) and the Fundamental Research Funds for the Central Universities, China(No.CCNU22QN008).

Bimetallic Au-Pd NPs Embedded in MOF Ultrathin Nanosheets with Tuned Surface Electronic Properties for High-performance Benzyl Alcohol Oxidation

GUO Taolian^1,2, BAO Shutong², GUO Jie², CHEN Wu¹, WEN Lili^2,3

1. National Local Joint Engineering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University, Wuhan 430200, P. R. China;
2. College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China;
3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received:2022-06-26 Online:2022-12-01 Published:2022-12-06
Contact: CHEN Wu, WEN Lili E-mail:wuchen@wtu.edu.cn;wenlili@mail.ccnu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.22171097 and 21771072) and the Fundamental Research Funds for the Central Universities, China(No.CCNU22QN008).

摘要/Abstract

摘要： Bimetallic Au-Pd nanoparticles(NPs) with synergistic effect between Au and Pd atom have shown excellent catalytic activity toward benzyl alcohol oxidation. The catalytic activities of metal NPs supported within metal-organic frameworks (MOFs) are affected by the electronic interactions between metal NPs and MOFs. Taking the advantages of ultrathin nanosheets, we confine the highly dispersed Au-Pd NPs within ultrathin nanosheets of MOF-Ni(NMOF-Ni) to fabricate Au_xPd_y@NMOF-Ni as catalysts. Under base-free and atmospheric pressure conditions, the as-prepared Au_xPd_y@NMOF-Ni catalysts exhibit superior activity and selectivity for benzyl alcohol oxidation. This work highlights the synergistic effects among different components in composite catalysts effectively improving the activity and offers a new way for designing efficient catalysts toward benzyl alcohol oxidation.

关键词: Bimetallic Au-Pd nanoparticle, Ultrathin MOF nanosheet, Nanocomposite, Synergistic effect, Benzyl alcohol

Abstract: Bimetallic Au-Pd nanoparticles(NPs) with synergistic effect between Au and Pd atom have shown excellent catalytic activity toward benzyl alcohol oxidation. The catalytic activities of metal NPs supported within metal-organic frameworks (MOFs) are affected by the electronic interactions between metal NPs and MOFs. Taking the advantages of ultrathin nanosheets, we confine the highly dispersed Au-Pd NPs within ultrathin nanosheets of MOF-Ni(NMOF-Ni) to fabricate Au_xPd_y@NMOF-Ni as catalysts. Under base-free and atmospheric pressure conditions, the as-prepared Au_xPd_y@NMOF-Ni catalysts exhibit superior activity and selectivity for benzyl alcohol oxidation. This work highlights the synergistic effects among different components in composite catalysts effectively improving the activity and offers a new way for designing efficient catalysts toward benzyl alcohol oxidation.

Key words: Bimetallic Au-Pd nanoparticle, Ultrathin MOF nanosheet, Nanocomposite, Synergistic effect, Benzyl alcohol

GUO Taolian, BAO Shutong, GUO Jie, CHEN Wu, WEN Lili. Bimetallic Au-Pd NPs Embedded in MOF Ultrathin Nanosheets with Tuned Surface Electronic Properties for High-performance Benzyl Alcohol Oxidation[J]. 高等学校化学研究, 2022, 38(6): 1344-1348.

参考文献

[1] Guo Z., Liu B., Zhang Q., Deng W., Wang Y., Yang Y., Chem. Soc. Rev., 2014, 43, 3480;
[2] Ramirez-Barria C. S., Isaacs M., Parlett C., Wilson K., Guerrero-Ruiz A., Rodríguez-Ramos I., Catal. Today, 2020, 357, 8;
[3] Dai X., Rasamani K. D., Wu S., Sun Y., Today Energy, 2018, 10, 15;
[4] Bai L., Zhang S., Chen Q., Gao C., ACS Appl. Mater. Inter., 2017, 9, 9710;
[5] Oliveira R. L., Kiyohara P. K., Rossi L. M., Green Chem., 2010, 12, 144;
[6] Naya S., Teranishi M., Aoki R., Tada H., J. Phys. Chem. C, 2016, 120, 12440;
[7] Rostamnia S., Kholdi S., Adv. Powder Technol., 2018, 29, 1167;
[8] Liu Y., Liu Z., Huang D., Cheng M., Zeng G., Lai C., Zhang C., Zhou C., Wang W., Jiang D., Wang H., Shao B., Coordin. Chem. Rev., 2019, 388, 63;
[9] Crombie C. M., Lewis R. J., Taylor R. L., Morgan D. J., Davies T. E., Folli A., Murphy D. M., Edwards J. K., Qi J., Jiang H., Kiely C. J., Liu X., Skjøth-Rasmussen M. S., Hutchings G. J., ACS Catal., 2021, 11, 2701;
[10] Luan Y., Qi Y., Gao H., Zheng N., Wang G., J. Mater. Chem. A, 2014, 2, 20588;
[11] Olmos C. M., Chinchilla L. E., Villa A., Delgado J. J., Pan H., Hungría A. B., Blanco G., Calvino J. J., Prati L., Chen X., Appl. Catal. A:Gen., 2016, 525, 145;
[12] Guadix-Montero S., Alshammari H., Dalebout R., Nowicka E., Morgan D. J., Shaw G., He Q., Sankar M., Appl. Catal. A:Gen., 2017, 546, 58;
[13] Zhu X., Guo Q., Sun Y., Chen S., Wang J. Q., Wu M., Fu W., Tang Y., Duan X., Chen D., Wan Y., Nat. Commun., 2019, 10, 1428;
[14] Wang H., Wang C., Yan H., Yi H., Lu J., J. Catal., 2015, 324, 59;
[15] Zhang Z., Wang Y., Li X., Dai W. L., Chinese J. Catal., 2014, 35, 1846;
[16] Choi K. M., Na K., Somorjai G. A., Yaghi O. M., J. Am. Chem. Soc., 2015, 137, 7810;
[17] Zhang W., Shi W., Ji W., Wu H., Gu Z., Wang P., Li X., Qin P., Zhang J., Fan Y., Wu T., Fu Y., Zhang W., Huo F., ACS Catal., 2020, 10, 5805;
[18] Li L., Chen X., Wu Y., Wang D., Peng Q., Zhou G., Li Y., Angew. Chem. Int. Ed., 2013, 52, 11049;
[19] Wang F., Ueda W., Xu J., Angew. Chem. Int. Ed., 2012, 51, 3883;
[20] Vayssilov G. N., Lykhach Y., Migani A., Staudt T., Petrova G. P., Tsud N., Skála T., Bruix A., Illas F., Prince K. C., Matolıxn V., Neyman K. M., Libuda J.,Nat. Mater., 2011, 10, 310;
[21] Li X., Goh T. W., Li L., Xiao C., Guo Z., Zeng X. C., Huang W., ACS Catal., 2016, 6, 3461;
[22] Yoshimaru S., Sadakiyo M., Staykov A., Kato K., Yamauchi M., Chem. Commun., 2017, 53, 6720;
[23] Tong Y., Xue G., Wang H., Liu M., Wang J., Hao C., Zhang X., Wang D., Shi X., Liu W., Li G., Tang Z., Nanoscale, 2018, 10, 16425;
[24] Choi K. M., Na K., Somorjai G. A., Yaghi O. M., J. Am. Chem. Soc., 2015, 137, 7810;
[25] Zhao M., Yuan K., Wang Y., Li G., Guo J., Gu L., Hu W., Zhao H., Tang Z., Nature, 2016, 539, 76;
[26] Zhang W., Ji W., Li L., Qin P., Khalil I. E., Gu Z., Wang P., Li H., Fan Y., Ren Z., Shen Y., Zhang W., Fu Y., Huo F., ACS Appl. Mater. Inter., 2020, 12, 52660;
[27] Xu M., Li D., Sun K., Jiao L., Xie C., Ding C., Jiang H. L., Angew. Chem. Int. Ed., 2021, 60, 16372;
[28] Chen D., Yang W., Jiao L., Li L., Yu S. H., Jiang H. L., Adv. Mater., 2020, 32, 2000041;
[29] Yuan S., Feng L., Wang K., Pang J., Bosch M., Lollar C., Sun Y., Qin J., Yang X., Zhang P., Wang Q., Zou L., Zhang Y., Zhang L., Fang Y., Li J., Zhou H., Adv. Mater., 2018, 30, 1704303;
[30] Danowski W., van Leeuwen T., Abdolahzadeh S., Roke D., Browne W. R., Wezenberg S. J., Feringa B. L., Nat. Nanotechnol., 2019, 14, 488;
[31] Van Vleet M. J., Weng T., Li X., Schmidt J. R., Chem. Rev., 2018, 118, 3681;
[32] Howarth A. J., Liu Y., Li P., Li Z., Wang T. C., Hupp J. T., Farha O. K., Nat. Rev. Mater., 2016, 1, 15018;
[33] Zhao X., Wang Y., Li D., Bu X., Feng P., Adv. Mater., 2018, 30, 1705189;
[34] Feng L., Wang K., Powell J., Zhou H., Matter, 2019, 1, 801;
[35] Zhang W., Lu G., Cui C., Liu Y., Li S., Yan W., Xing C., Chi Y. R., Yang Y., Huo F., Adv. Mater., 2014, 26, 4056;
[36] Zhang W., Zheng B., Shi W., Chen X., Xu Z., Li S., Chi Y. R., Yang Y., Lu J., Huang W., Huo F.,Adv. Mater., 2018, 30, 1800643;
[37] Peng Y., Li Y., Ban Y., Jin H., Jiao W., Liu X., Yang W., Science, 2014, 346, 1356;
[38] Zhao M., Huang Y., Peng Y., Huang Z., Ma Q., Zhang H., Chem. Soc. Rev., 2018, 47, 6267;
[39] Li Y., Fu Z., Xu G., Coordin. Chem. Rev., 2019, 388, 79;
[40] Zhuang L., Ge L., Liu H., Jiang Z., Jia Y., Li Z., Yang D., Hocking R. K., Li M., Zhang L., Wang X., Yao X., Zhu Z., Angew. Chem. Int. Ed., 2019, 58, 13565;
[41] Liu M., Xie K., Nothling M. D., Gurr P. A., Tan S. S. L., Fu Q., Webley P. A., Qiao G. G., ACS Nano, 2018, 12, 11591;
[42] Huang C., Guo Z., Zheng X., Chen X., Xue Z., Zhang S., Li X., Guan B., Li X., Hu G., Wang T., J. Am. Chem. Soc., 2020, 142, 9408;
[43] Liu Y., Liu L., Chen X., Liu Y., Han Y., Cui Y., J. Am. Chem. Soc., 2021, 143, 3509;
[44] Yan R., Zhao Y., Yang H., Kang X., Wang C., Wen L., Lu Z., Adv. Funct. Mater., 2018, 28, 1802021;
[45] Guo T., Mo K, Zhang N., Xiao L., Liu W., Wen L., Dalton Trans., 2021, 50, 1774;
[46] Guo T., Huang Y., Zhang N., Chen T., Wang C., Xing X., Lu Z., Wen L., Inorg. Chem., 2022, 61, 2538;
[47] Chen B., Li F., Huang Z., Yuan G., Appl. Catal. A:Gen., 2015, 500, 23;
[48] Khorsand S., Raeissi K., Ashrafizadeh F., Arenas M. A., Chem. Eng. J., 2015, 273, 638;
[49] Zhong Y. C., Mao Y. L., Shi S. L., Wan M. M., Ma C., Wang S. H., Chen C., Zhao D., Zhang N., ACS Appl. Mater. Interfaces, 2019, 11, 32251;
[50] Dimitratos N., Villa A., Wang D., Porta F., Su D., Prati L.,J. Catal., 2006, 244, 113;
[51] Chen Y., Wang H., Liu C., Zeng Z., Zhang H., Zhou C., Jia X., Yang Y., J. Catal., 2012, 289, 105;
[52] Xu J., Shang J., Chen Y., Wang Y., Li Y., Appl. Catal. A:Gen., 2017, 542, 380;
[53] Wei Q., Liu T., Wang Y., Dai L., RSC Adv., 2019, 9, 962;
[54] Kong L., Wang C., Gong F., Zhu W., Zhong Y., Ye X., Li F., Catal. Lett., 2016, 146, 1321;
[55] Liu H., Liu Y., Li Y., Tang Z., Jiang H., J. Phys. Chem. C, 2010, 114, 13362;
[56] Liu H., Li Y., Jiang H., Vargas C., Luque R., Chem. Commun., 2012, 48, 8431

Bimetallic Au-Pd NPs Embedded in MOF Ultrathin Nanosheets with Tuned Surface Electronic Properties for High-performance Benzyl Alcohol Oxidation

Bimetallic Au-Pd NPs Embedded in MOF Ultrathin Nanosheets with Tuned Surface Electronic Properties for High-performance Benzyl Alcohol Oxidation

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