Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene

doi:10.1007/s40242-022-2202-y

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (5): 1258-1262.doi: 10.1007/s40242-022-2202-y

Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene

ZHANG Xingcong¹, ZHONG Yunzhu¹, CHEN Hongyu¹, CHENG Yujie¹, SUN Qingdi¹, ZHANG Hao¹, HE Qian¹, ZHANG Ying¹, GUO Guanghui¹, HE Xiaohui^1,2, JI Hongbing^1,2,3

1. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, P. R. China;
2. Huizhou Research Institute of Sun Yat-sen University, Huizhou 516216, P. R. China;
3. Advanced Energy Science and Technology Guangdong Laboratory, Huizhou 516000, P. R. China

收稿日期:2022-06-15 出版日期:2022-10-01 发布日期:2022-10-08
通讯作者: HE Xiaohui, JI Hongbing E-mail:hexiaohui@mail.sysu.edu.cn;jihb@mail.sysu.edu.cn
基金资助:
This work was supported by the National Key Research and Development Program Nanotechnology Specific Project, China(No.2020YFA0210900), the Science and Technology Key Project of Guangdong Province, China(No. 2020B010188002), the Guangdong Natural Science Funds for Distinguished Young Scholar, China(No.2022B1515020035), the Guangdong Provincial Key R&D Programme, China(No.2019B110206002), the National Natural Science Foundation of China(Nos.22078371, 21938001, 21961160741), the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program, China(No.2017BT01C102), the Natural Science Foundation of Guangdong Province, China(No.2020A1515011141), and the Science and Technology Project of Guangzhou City, China(No.202102020461).

Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene

ZHANG Xingcong¹, ZHONG Yunzhu¹, CHEN Hongyu¹, CHENG Yujie¹, SUN Qingdi¹, ZHANG Hao¹, HE Qian¹, ZHANG Ying¹, GUO Guanghui¹, HE Xiaohui^1,2, JI Hongbing^1,2,3

1. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, P. R. China;
2. Huizhou Research Institute of Sun Yat-sen University, Huizhou 516216, P. R. China;
3. Advanced Energy Science and Technology Guangdong Laboratory, Huizhou 516000, P. R. China

Received:2022-06-15 Online:2022-10-01 Published:2022-10-08
Contact: HE Xiaohui, JI Hongbing E-mail:hexiaohui@mail.sysu.edu.cn;jihb@mail.sysu.edu.cn
Supported by:
This work was supported by the National Key Research and Development Program Nanotechnology Specific Project, China(No.2020YFA0210900), the Science and Technology Key Project of Guangdong Province, China(No. 2020B010188002), the Guangdong Natural Science Funds for Distinguished Young Scholar, China(No.2022B1515020035), the Guangdong Provincial Key R&D Programme, China(No.2019B110206002), the National Natural Science Foundation of China(Nos.22078371, 21938001, 21961160741), the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program, China(No.2017BT01C102), the Natural Science Foundation of Guangdong Province, China(No.2020A1515011141), and the Science and Technology Project of Guangzhou City, China(No.202102020461).

摘要/Abstract

摘要： Through screening Ce precursors and pyrolysis temperatures[Ce(acac)₃ as Ce precursors and pyrolysis at 900 °C], zeolitic imidazolate framework-8(ZIF-8) derived nitrogen-doped carbon supported cerium single atom catalyst(Ce₁/NC) is successfully prepared by ball milling method. The Ce₁/NC catalyst exhibits exceptional catalytic performance in the selective oxidation of saturated C―H bonds in aromatic compounds, e.g., 91% conversion and 99% selelctivity can be achieved in the oxidation of ethylbenzene to acetophenone under mild reaction conditions.

关键词: Single atom catalyst, Ball milling, ZIF-8, Ethylbenzene oxidation

Abstract: Through screening Ce precursors and pyrolysis temperatures[Ce(acac)₃ as Ce precursors and pyrolysis at 900 °C], zeolitic imidazolate framework-8(ZIF-8) derived nitrogen-doped carbon supported cerium single atom catalyst(Ce₁/NC) is successfully prepared by ball milling method. The Ce₁/NC catalyst exhibits exceptional catalytic performance in the selective oxidation of saturated C―H bonds in aromatic compounds, e.g., 91% conversion and 99% selelctivity can be achieved in the oxidation of ethylbenzene to acetophenone under mild reaction conditions.

Key words: Single atom catalyst, Ball milling, ZIF-8, Ethylbenzene oxidation

ZHANG Xingcong, ZHONG Yunzhu, CHEN Hongyu, CHENG Yujie, SUN Qingdi, ZHANG Hao, HE Qian, ZHANG Ying, GUO Guanghui, HE Xiaohui, JI Hongbing. Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene[J]. 高等学校化学研究, 2022, 38(5): 1258-1262.

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Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene

Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene

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