Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media

doi:10.1007/s40242-021-1199-y

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (4): 961-967.doi: 10.1007/s40242-021-1199-y

Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media

ZHENG Ruonan, ZHAI Zihui, QIU Chenxi, GAO Rui, LV Yang, SONG Yujiang

State Key Laboratory of Fine Chemicals &Dalian Key Laboratory of Core Materials and Units for Hydrogen Energy and Fuel Cells, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China

收稿日期:2021-04-30 修回日期:2021-05-30 出版日期:2022-08-01 发布日期:2022-07-01
通讯作者: SONG Yujiang E-mail:yjsong@dlut.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.22090050, 22090053, 21974126, 21874121, 51803194), the Zhejiang Provincial Natural Science Foundation, China(No.LY19B030001), the Open-end Funds from the Engineering Research Center of Nano-Geomaterials of Ministry of Education, China(No.NGM2019KF013) and the Fundamental Research Funds for National Universities, China University of Geosciences(Wuhan).

Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media

ZHENG Ruonan, ZHAI Zihui, QIU Chenxi, GAO Rui, LV Yang, SONG Yujiang

State Key Laboratory of Fine Chemicals &Dalian Key Laboratory of Core Materials and Units for Hydrogen Energy and Fuel Cells, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China

Received:2021-04-30 Revised:2021-05-30 Online:2022-08-01 Published:2022-07-01
Contact: SONG Yujiang E-mail:yjsong@dlut.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.22090050, 22090053, 21974126, 21874121, 51803194), the Zhejiang Provincial Natural Science Foundation, China(No.LY19B030001), the Open-end Funds from the Engineering Research Center of Nano-Geomaterials of Ministry of Education, China(No.NGM2019KF013) and the Fundamental Research Funds for National Universities, China University of Geosciences(Wuhan).

摘要/Abstract

摘要： Zeolite imidazole frameworks 8(ZIF-8) and modified ones after pyrolysis are highly promising toward oxygen reduction reaction(ORR). Especially, the compositional modification of ZIF-8 is crucial to the enhancement of ORR performance, yet limited to the substitution of skeletal Zn(II) with other cations or simple physical adsorption of cations. Herein, we report the decoration of ZIF-8 with ORR active hemin(FeP) and Co(III) protoporphyrin(CoP) via the coordination between the peripheral carboxylic group of FeP and CoP with skeletal Zn(II). This allows well control over the quantity of loaded FeP and CoP, critical to the synthesis of advanced electrocatalysts. Subsequent pyrolysis of FeP and CoP co-decorated ZIF-8 leads to highly active ORR electrocatalysts with a half-wave potential(E_1/2) of 0. 913 V(vs. RHE) in 0.1 mol/L KOH aq. and an E_1/2 of 0.803 V(vs. RHE) in 0.1 mol/L HClO₄ aq. Moreover, our electrocatalyst shows much more improved and comparable durability in alkaline and acidic media, respectively, during 3000 cycles of cyclic voltammetry(CV) scanning relative to commercial Pt/C.

关键词: Non-noble metal electrocatalyst, ZIF-8, Porphyrin, Oxygen reduction reaction(ORR)

Abstract: Zeolite imidazole frameworks 8(ZIF-8) and modified ones after pyrolysis are highly promising toward oxygen reduction reaction(ORR). Especially, the compositional modification of ZIF-8 is crucial to the enhancement of ORR performance, yet limited to the substitution of skeletal Zn(II) with other cations or simple physical adsorption of cations. Herein, we report the decoration of ZIF-8 with ORR active hemin(FeP) and Co(III) protoporphyrin(CoP) via the coordination between the peripheral carboxylic group of FeP and CoP with skeletal Zn(II). This allows well control over the quantity of loaded FeP and CoP, critical to the synthesis of advanced electrocatalysts. Subsequent pyrolysis of FeP and CoP co-decorated ZIF-8 leads to highly active ORR electrocatalysts with a half-wave potential(E_1/2) of 0. 913 V(vs. RHE) in 0.1 mol/L KOH aq. and an E_1/2 of 0.803 V(vs. RHE) in 0.1 mol/L HClO₄ aq. Moreover, our electrocatalyst shows much more improved and comparable durability in alkaline and acidic media, respectively, during 3000 cycles of cyclic voltammetry(CV) scanning relative to commercial Pt/C.

Key words: Non-noble metal electrocatalyst, ZIF-8, Porphyrin, Oxygen reduction reaction(ORR)

ZHENG Ruonan, ZHAI Zihui, QIU Chenxi, GAO Rui, LV Yang, SONG Yujiang. Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media[J]. 高等学校化学研究, 2022, 38(4): 961-967.

参考文献

[1] Jiang H., Gu J., Zheng X., Liu M., Qiu X., Wang L., Li W., Chen Z., Ji X., Li J., Energy Environ. Sci., 2019, 12, 322
[2] Shao M., Chang Q., Dodelet J.-P., Chenitz R., Chem. Rev., 2016, 116, 3594
[3] Zhu C., Li H., Fu S., Du D., Lin Y., Chem. Soc. Rev., 2016, 45, 517
[4] Zhang J., Zhang C., Li W., Guo Q., Gao H., You Y., Li Y., Cui Z., Jiang K.-C., Long H., Zhang D., Xin S., ACS Appl. Mater. Interfaces, 2018,10, 5543
[5] Wang J., Huang Z., Liu W., Chang C., Tang H., Li Z., Chen W., Jia C., Yao T., Wei S., Wu Y., Li Y., J. Am. Chem. Soc., 2017, 139, 17281
[6] Guo Z., Zhang Z., Li Z., Dou M., Wang F., Nano Energy, 2019, 57, 108
[7] Ye G., He Q., Liu S., Zhao K., Su Y., Zhu W., Huang R., He Z., J. Mater. Chem. A, 2019,7, 16508
[8] Li J., Song Y., Zhang G., Liu H., Wang Y., Sun S., Guo X., Adv. Funct. Mater., 2017, 27, 1604356
[9] Wen J., Li Y., Gao J., Chem. Res. Chinese Universities, 2020, 36(4), 662
[10] Fu X., Zamani P., Choi J.-Y., Hassan F. M., Jiang G., Higgins D. C., Zhang Y., Hoque M. A., Chen Z., Adv. Mater., 2017, 29, 1604456
[11] Liang S., Chen R., Yu P., Ni M., Zhang Q., Zhang X., Yang W., Chem. Commun., 2017,53, 11453
[12] Chen Y., Ji S., Wang Y., Dong J., Chen W., Li Z., Shen R., Zheng L., Zhuang Z., Wang D., Li Y., Angew. Chem. Int. Ed., 2017,56, 6937
[13] Zhang H., Chung H. T., Cullen D. A., Wagner S., Kramm U. I., More K. L., Zelenay P., Wu G., Energy Environ. Sci., 2019, 12, 2548
[14] Kwak D.-H., Han S.-B., Lee Y.-W., Park H.-S., Choi I.-A., Ma K.-B., Kim M.-C., Kim S.-J., Kim D.-H., Sohn J.-I., Park K.-W., Appl. Catal. B Environ., 2017,203, 889
[15] Zitolo A., Goellner V., Armel V., Sougrati M.-T., Mineva T., Stievano L., Fonda E., Jaouen F., Nat. Mater., 2015, 14, 937
[16] Wang X., Zhang H., Lin H., Gupta S., Wang C., Tao Z., Fu H., Wang T., Zheng J., Wu G., Li X., Nano Energy, 2016,25, 110
[17] Li J., Zhang H., Samarakoon W., Shan W., Cullen D. A., Karakalos S., Chen M., Gu D., More K. L., Wang G., Feng Z., Wang Z., Wu G., Angew. Chem. Int. Ed., 2019,58, 18971
[18] Zhu Z., Yin H., Wang Y., Chuang C.-H., Xing L., Dong M., Lu Y.-R., Casillas-Garcia G., Zheng Y., Chen S., Dou Y., Liu P., Cheng Q., Zhao H., Adv. Mater., 2020, 32, 2004670
[19] Kato M., Murotani T., Yagi I., Chem. Lett., 2016, 45, 1213
[20] He Q., Yang X., Ren X., Koel B. E., Ramaswamy N., Mukerjee S., Kostecki R., J. Power Sources, 2011, 196, 7404
[21] Zhang J., Yang H., Liu B., Adv. Eng. Mater., 2021, 11, 2002473
[22] Zhai Z., Liu Q., Zheng R., Qiu C., Qin J., Li J., Xie Y., Wang A., Huang J., Song Y., Int. J. Hydrogen Energy, 2021, 46, 11041
[23] Lu Z., Wang B., Hu Y., Liu W., Zhao Y., Yang R., Li Z., Luo J., Chi B., Jiang Z., Li M., Mu S., Liao S., Zhang J., Sun X., Angew. Chem. Int. Ed., 2019, 58, 2622
[24] Yang G., Zhu J., Yuan P., Hu Y., Qu G., Lu B.-A., Xue X., Yin H., Cheng W., Cheng J., Xu W., Li J., Hu J., Mu S., Zhang J.-N., Nat. Commun., 2021, 12, 1734
[25] Kato M., Fujibayashi N., Abe D., Matsubara N., Yasuda S., Yagi I., ACS Catal., 2021, 11, 2356
[26] Sahraie N. R., Kramm U. I., Steinberg J., Zhang Y., Thomas A., Reier T., Paraknowitsch J.-P., Strasser P., Nat. Commun., 2015, 6, 8618
[27] Wang J., Liu W., Luo G., Li Z., Zhao C., Zhang H., Zhu M., Xu Q., Wang X., Zhao C., Qu Y., Yang Z., Yao T., Li Y., Lin Y., Wu Y., Li Y., Energy Environ. Sci., 2018, 11, 3375
[28] Wu G., More K. L., Johnston C. M., Zelenay P., Science, 2011, 332, 443
[29] Zhang D., Chen W., Li Z., Chen Y., Zheng L., Gong Y., Li Q., Shen R., Han Y., Cheong W.-C., Gu L., Li Y., Chem. Commun., 2018, 54, 4274
[30] Wang X., Zhuang L., Jia Y., Zhang L., Yang Q., Xu W., Yang D., Yan X., Zhang L., Zhu Z., Brown C. L., Yuan P., Yao X., Chem. Res. Chinese Universities, 2020, 36(3), 479
[31] Qian Y., An T., Birgersson K. E., Liu Z., Zhao D., Small, 2018, 14, 1704169
[32] Han J., Meng X., Lu L., Bian J., Li Z., Sun C., Adv. Funct. Mater., 2019, 29, 1808872
[33] Garrido-Barros P., Gimbert-Suriñach C., Matheu R., Sala X., Llobet A., Chem. Soc. Rev., 2017,46, 6088
[34] Wang D., Groves J. T., Proc. Natl. Acad. Sci., 2013, 110, 15579
[35] Olaya A. J., Omatsu T., Hidalgo-Acosta J. C., Riva J. S., Bassetto V. C., Gasilova N., Girault H. H., J. Am. Chem. Soc., 2019, 141, 6765
[36] Meyer K., Ranocchiari M., van Bokhoven J. A., Energy Environ. Sci., 2015, 8, 1923
[37] Liao P.-Q., Shen J.-Q., Zhang J.-P., Coordin. Chem. Rev., 2018, 373, 22
[38] Venna S. R., Jasinski J. B., Carreon M. A., J. Am. Chem. Soc., 2010, 132, 18030
[39] Lv Y., Liu H., Li J., Chen J., Song Y., J. Electroanal. Chem., 2020, 870, 114172
[40] Li J., Liu H., Lü Y., Guo X., Song Y., Chin. J. Catal., 2016, 37, 1109
[41] Hu Y., Kazemian H., Rohani S., Huang Y., Song Y., Chem. Commun., 2011, 47, 12694
[42] Park K. S., Ni Z., Côté A. P., Choi J. Y., Huang R., Uribe-Romo F. J., Chae H. K., O'Keeffe M., Yaghi O. M., Proc. Natl. Acad. Sci., 2006, 103, 10186
[43] Mukhopadhyay S., Basu O., Das S. K., ChemCatChem, 2020, 12, 5430
[44] Liang Z., Guo H., Zhou G., Guo K., Wang B., Lei H., Zhang W., Zheng H., Apfel U.-P., Cao R., Angew. Chem. Int. Ed., 2021, 60, 8472
[45] Wang R., Li Y., J. Power Sources, 2019, 421, 139
[46] Busch M., Halck N. B., Kramm U. I., Siahrostami S., Krtil P., Rossmeisl J., Nano Energy, 2016, 29, 126
[47] Jia Q., Ramaswamy N., Tylus U., Strickland K., Li J., Serov A., Artyushkova K., Atanassov P., Anibal J., Gumeci C., Barton S. C., Sougrati M.-T., Jaouen F., Halevi B., Mukerjee S., Nano Energy, 2016, 29, 65
[48] Jiang R., Li L., Sheng T., Hu G., Chen Y., Wang L., J. Am. Chem. Soc., 2018, 140, 11594

Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media

Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	ZHANG Xingcong, ZHONG Yunzhu, CHEN Hongyu, CHENG Yujie, SUN Qingdi, ZHANG Hao, HE Qian, ZHANG Ying, GUO Guanghui, HE Xiaohui, JI Hongbing. Synthesis of Nitrogen-doped Carbon Supported Cerium Single Atom Catalyst by Ball Milling for Selective Oxidation of Ethylbenzene[J]. 高等学校化学研究, 2022, 38(5): 1258-1262.
[2]	SHU Chengyong, GAN Zhuofan, ZHOU Jia, WANG Zhen, TANG Wei. Highly Efficient Oxygen Reduction Reaction Fe-N-C Cathode in Long-durable Direct Glycol Fuel Cells[J]. 高等学校化学研究, 2022, 38(5): 1268-1274.
[3]	ZHENG Meng, WANG Jin. Regulating the Oxygen Affinity of Single Atom Catalysts by Dual-atom Design for Enhanced Oxygen Reduction Reaction Activity[J]. 高等学校化学研究, 2022, 38(5): 1275-1281.
[4]	CHEN Yu, CHEN Yongting, LIAO Yuxiang, CHEN Shengli. A Chemical Dealloying Approach for Pt Surface-enriched Pt₃Co Alloy Nanoparticles as Oxygen Reduction Reaction Electrocatalysts[J]. 高等学校化学研究, 2022, 38(4): 991-998.
[5]	HE Qian, ZHANG Ying, XIAO Huajian, HE Xiaohui, ZHOU Xiantai, JI Hongbing. Facile Synthesis of Metalloporphyrins-Ba²⁺ Composites as Recyclable and Efficient Catalysts for Olefins Epoxidation Reactions[J]. 高等学校化学研究, 2019, 35(2): 251-255.
[6]	HUANG He, LIANG Chen, SHA Haoyan, YU Ying, LOU Yue, CHEN Cailing, LI Chunguang, CHEN Xiaobo, SHI Zhan, FENG Shouhua. Microwave Assisted Hydrothermal Way Towards Highly Crystalized N-Doped Carbon Quantum Dots and Their Oxygen Reduction Performance[J]. 高等学校化学研究, 2019, 35(2): 171-178.
[7]	GUO Ximing, GUO Bin. Preparation of Fe₃O₄-porphyrin Nano-composited Particles and Their Optical and Magnetic Properties[J]. 高等学校化学研究, 2017, 33(4): 530-533.
[8]	ZHANG Ya, QIAN Linlin, YIN Wei, HE Bin, LIU Fangmei, HOU Changjun, HUO Danqun, FA Huanbao. A Dual Read-out Molecularly Imprinted Composite Membrane Sensor Based on Zinc Porphyrin for the Detection of Dimethyl Methylphosphonate[J]. 高等学校化学研究, 2016, 32(5): 725-730.
[9]	MI Yongsheng, LIANG Pengxia, YANG Zhou, WANG Dong, CAO Hui, HE Wanliand YANG Huai. Effects of Donor and Acceptor on Optoelectronic Performance for Porphyrin Derivatives: Nonlinear Optical Properties and Dye-sensitized Solar Cells[J]. 高等学校化学研究, 2015, 31(6): 992-996.
[10]	XIA Hongqiang, WANG Jian, JIA Ran, WANG Qin, ZHANG Hongxing. Theoretical Studies on the Absorption Spectra and Intramolecular Charge Transfer of Push-pull Zinc Porphyrin Dyes for Dye-sensitized Solar Cells[J]. 高等学校化学研究, 2015, 31(2): 276-280.
[11]	WU Yu, HUO Danqun, HOU Changjun, FA Huanbao, YANG Mei, LUO Xiaogang. Colorimetric Artificial Nose for Identification of Breath Volatile Organic Compounds of Patients with Lung Cancer[J]. 高等学校化学研究, 2014, 30(4): 572-577.
[12]	LIU Yun, HUANG Yan, BOAMAH Peter Osei, ZHANG Qi, LIU Yuanyuan, HUA Mingqing. Synthesis and in vitro Evaluation of Manganese(II)-porphyrin Modified with Chitosan Oligosaccharides as Potential MRI Contrast Agents[J]. 高等学校化学研究, 2014, 30(4): 549-555.
[13]	FEI Qiang, WANG Chunyu, WANG Baojun, XU Hui, LI Guanghua, HUAN Yanfu, SHAN Hongyan, FENG Guodong. Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement[J]. 高等学校化学研究, 2014, 30(3): 379-382.
[14]	HE Leien, WU Yingying, ZHANG Hanyun, LIU Manyun, SHI Deqing. Synthesis and Herbicidal Activities of Novel Uracil Derivatives Containing Pyrimidinyl Moiety[J]. 高等学校化学研究, 2014, 30(3): 400-404.
[15]	ZHAO Yi-dan, FU Jing-jing, LI Hai-bin, DONG Hao, LIAO Yi. Photoinduced Charge Transfer Processes of Zinc Porphyrin Derivatives for Dye-sensitized Solar Cells[J]. 高等学校化学研究, 2013, 29(5): 974-981.