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高等学校化学研究 ›› 2009, Vol. 25 ›› Issue (4): 455-457.

• Articles • 上一篇    下一篇

Cobalt Sulfate as a Recyclable Catalyst for Chemoselective Synthesis of Diacetates from Aldehydes

WANG Min1*, TIAN Gui-fu1, SONG Zhi-guo2 and JIANG Heng3   

  1. 1. College of Chemistry and Chemical Engineering,
    2. Center for Science & Technology Experiment, Bohai University,Jinzhou 121000, P. R. China;
    3. College of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, P. R. China
  • 收稿日期:2008-07-04 修回日期:2008-08-25 出版日期:2009-07-25 发布日期:2009-10-16
  • 通讯作者: WANG Min. E-mail: minwangszg@yahoo.com.cn

Cobalt Sulfate as a Recyclable Catalyst for Chemoselective Synthesis of Diacetates from Aldehydes

WANG Min1*, TIAN Gui-fu1, SONG Zhi-guo2 and JIANG Heng3   

  1. 1. College of Chemistry and Chemical Engineering,
    2. Center for Science & Technology Experiment, Bohai University,Jinzhou 121000, P. R. China;
    3. College of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, P. R. China
  • Received:2008-07-04 Revised:2008-08-25 Online:2009-07-25 Published:2009-10-16
  • Contact: WANG Min. E-mail: minwangszg@yahoo.com.cn

Abstract:

A mild and efficient method for diacetylation reaction was developed, by which diacetate could be achie- ved through the reaction of aldehyde with acetic anhydride, in the presence of cobalt sulfate, with an admirable yield, at room temperature, without solvent. The catalyst could be recycled six times without a distinct loss of activity.

Key words: Diacetate; Aldehyde; Acetic anhydride; Cobalt sulfate