Cu2SnSe3/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries

doi:10.1007/s40242-020-9061-1

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (1): 91-96.doi: 10.1007/s40242-020-9061-1

Cu₂SnSe₃/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries

YANG Zuojun, WU Xueyan, MA Chao, HOU Chengcheng, XU Shumao, WEI Xiao, WANG Kaixue, CHEN Jiesheng

Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

收稿日期:2019-11-24 修回日期:2019-12-26 出版日期:2020-02-01 发布日期:2020-01-20
通讯作者: WU Xueyan, WEI Xiao E-mail:xueyanwu@sjtu.edu.cn;weixiao@sjtu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21871177, 21671134, 21720102002 and 21761132004).

Cu₂SnSe₃/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries

YANG Zuojun, WU Xueyan, MA Chao, HOU Chengcheng, XU Shumao, WEI Xiao, WANG Kaixue, CHEN Jiesheng

Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received:2019-11-24 Revised:2019-12-26 Online:2020-02-01 Published:2020-01-20
Contact: WU Xueyan, WEI Xiao E-mail:xueyanwu@sjtu.edu.cn;weixiao@sjtu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21871177, 21671134, 21720102002 and 21761132004).

摘要/Abstract

摘要： Metal selenides as anode materials for sodium-ion batteries have attracted considerable attention owing to their high theoretical specific capacities and variable composition and structures. However, the achievement of long cycle life and superior rate performance is challenging for these selenide materials due to the volume variation upon cycling. Herein, a composite composed of a new binary-metal selenide[Cu₂SnSe₃(CSS)] and carbon nanotubes(CNTs) was constructed via a hydrothermal process followed by calcination at 600℃. Benefited from the unique structure of binary-metal selenide and the conductive network of CNTs, the Cu₂SnSe₃/carbon nanotubes(CSS/CNT) composite exhibits excellent electrochemical performance when used as an anode material for sodium-ion batteries. A reversible specific capacity of 399 mA·h/g can be maintained at a current density of 100 mA/g even after 100 cycles. This work provides a promising strategy for rational design of binary-metal selenides upon delicate crystal phase control as electrode materials.

关键词: Cu₂SnSe₃, Binary-metal selenide, Carbon nanotube, Anode material, Sodium-ion battery

Abstract: Metal selenides as anode materials for sodium-ion batteries have attracted considerable attention owing to their high theoretical specific capacities and variable composition and structures. However, the achievement of long cycle life and superior rate performance is challenging for these selenide materials due to the volume variation upon cycling. Herein, a composite composed of a new binary-metal selenide[Cu₂SnSe₃(CSS)] and carbon nanotubes(CNTs) was constructed via a hydrothermal process followed by calcination at 600℃. Benefited from the unique structure of binary-metal selenide and the conductive network of CNTs, the Cu₂SnSe₃/carbon nanotubes(CSS/CNT) composite exhibits excellent electrochemical performance when used as an anode material for sodium-ion batteries. A reversible specific capacity of 399 mA·h/g can be maintained at a current density of 100 mA/g even after 100 cycles. This work provides a promising strategy for rational design of binary-metal selenides upon delicate crystal phase control as electrode materials.

Key words: Cu₂SnSe₃, Binary-metal selenide, Carbon nanotube, Anode material, Sodium-ion battery

YANG Zuojun, WU Xueyan, MA Chao, HOU Chengcheng, XU Shumao, WEI Xiao, WANG Kaixue, CHEN Jiesheng. Cu₂SnSe₃/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries[J]. 高等学校化学研究, 2020, 36(1): 91-96.

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Cu₂SnSe₃/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries

Cu₂SnSe₃/CNTs Composite as a Promising Anode Material for Sodium-ion Batteries

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