Introduction of H2SO4 and H3PO4 into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

doi:10.1007/s40242-020-9276-1

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (5): 976-980.doi: 10.1007/s40242-020-9276-1

Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

WANG Yuxia¹, YAN Tingting^1,2, BEN Teng¹

1. Department of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Shandong Key Laboratory of Biophysics, Institute of Biophysics, Dezhou University, Dezhou 253023, P. R. China

收稿日期:2019-10-11 修回日期:2019-12-17 出版日期:2020-10-01 发布日期:2020-10-01
通讯作者: BEN Teng E-mail:tben@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.91956108, 21871103), the "111" Project, China (No.BP0719036) and the Foundation of the Science and Technology Department of Jilin Province, China(No.20180414009GH).

Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

WANG Yuxia¹, YAN Tingting^1,2, BEN Teng¹

1. Department of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Shandong Key Laboratory of Biophysics, Institute of Biophysics, Dezhou University, Dezhou 253023, P. R. China

Received:2019-10-11 Revised:2019-12-17 Online:2020-10-01 Published:2020-10-01
Contact: BEN Teng E-mail:tben@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.91956108, 21871103), the "111" Project, China (No.BP0719036) and the Foundation of the Science and Technology Department of Jilin Province, China(No.20180414009GH).

摘要/Abstract

摘要： To improve the proton conduction of crystalline porous organic salts(CPOS-1), H₂SO₄ and H₃PO₄ were introduced into the channel to obtain H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1. Compared to CPOS-1, the proton conductivities of H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100% RH, respectively. It can be attributed to the increasing concentration of the protons, which dissociates from the acids.

关键词: Proton conductivity, Crystalline porous organic salt, H₂SO₄, H₃PO₄

Abstract: To improve the proton conduction of crystalline porous organic salts(CPOS-1), H₂SO₄ and H₃PO₄ were introduced into the channel to obtain H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1. Compared to CPOS-1, the proton conductivities of H₂SO₄@CPOS-1 and H₃PO₄@CPOS-1 increased two orders of magnitude and one order of magnitude at 303 K and 100% RH, respectively. It can be attributed to the increasing concentration of the protons, which dissociates from the acids.

Key words: Proton conductivity, Crystalline porous organic salt, H₂SO₄, H₃PO₄

WANG Yuxia, YAN Tingting, BEN Teng. Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity[J]. 高等学校化学研究, 2020, 36(5): 976-980.

WANG Yuxia, YAN Tingting, BEN Teng. Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity[J]. Chemical Research in Chinese Universities, 2020, 36(5): 976-980.

参考文献 33

[1]	Hou Z. J., Yu H. M., Yi B. L., Zhang H. M., Hou M., Lei H., Cheng M. J., Bao X. H., Chem. Res. Chinese Universities, 2003, 19(1), 89
[2]	Zhang K., Xie X. J., Li H. Y., Gao J. X., Nie L., Pan Y., Xie J., Tian D., Liu W. L., Fan Q. L., Su H. Q., Huang L., Huang W., Adv. Mater., 2017, 29, 1701804
[3]	Nagarkar S. S., Unni S. M., Sharma A., Kurungot S., Ghosh S. K., Angew. Chem. Int. Ed., 2014, 53, 2638
[4]	Yang F., Xu G., Dou Y. B., Wang B., Zhang H., Wu H., Zhou W., Li J. R., Chen B. L., Nat. Energy., 2017, 2, 877
[5]	Kang D. W., Lim K. S., Lee K. J., Lee J. H., Lee W. R., Song J. H., Yeom K. H., Kim J. Y., Hong C. S., Angew. Chem. Int. Ed., 2016, 55, 16123
[6]	Ye Y. X., Zhang L. Q., Peng Q. F., Wang G. E., Shen Y. C., Li Z. Y., Wang L. H., Ma X. L., Chen Q. H., Zhang Z. J., Xiang S. C., J. Am. Chem. Soc., 2015, 137, 913
[7]	Xu H., Tao S. S., Jiang D. L., Nat. Mater., 2016, 15, 722
[8]	Xing G. L., Yan T. T., Das S., Ben T., Qiu S. L., Angew. Chem. Int. Ed., 2018, 57, 5345
[9]	Shimizu G. K. H., Taylor J. M., Kim S., Science, 2013, 341, 354
[10]	Zhang F. M., Dong L. Z., Qin J. S., Guan W., Liu J., Li S. L., Lu M., Lan Y. Q., Su Z. M., Zhou H. C., J. Am. Chem. Soc., 2017, 139, 6183
[11]	Nagarkar S. S., Horike S., Itakura T., Ouay B. L., Demessence A., Tsujimoto M., Kitagawa S., Angew. Chem. Int. Ed., 2017, 56, 4976
[12]	Yamada T., Otsubo K., Makiura R., Kitagawa H., Chem. Soc. Rev., 2013, 42, 6655
[13]	Li X. M., Dong L. Z., Li S. L., Xu G., Liu J., Zhang F. M., Lu L. S., Lan Y. Q., ACS Energy Lett., 2017, 2, 2313
[14]	Bureekaew S., Horike S., Higuchi M., Mizuno M., Kawamura T., Tanaka D., Yanai N., Kitagawa S., Nat. Mater., 2009, 8, 831
[15]	Umeyama D., Horike S., Inuka M., Hijikata Y., Kitagawa S., Angew. Chem. Int. Ed., 2011, 50, 11706
[16]	Ponomareva V. G., Kovalenko K. A., Chupakhin A. P., Dybtsev D. N., Shutova E. S., Fedin V. P., J. Am. Chem. Soc., 2012, 134, 15640
[17]	Chandra S., Kundu T., Kandambeth S., Babarao R., Marathe Y., Kunjir S. M., Banerjee R., J. Am. Chem. Soc., 2014, 136, 6570
[18]	Klumpen C., Gödrich S., Papastavrou G., Senker J., Chem. Commun., 2017, 53, 7592
[19]	Phang W. J., Jo H., Lee W. R., Song J. H., Yoo K., Kim B., Hong C. S., Angew. Chem. Int. Ed., 2015, 54, 5142
[20]	Miao L., Duan H., Wang Z. W., Lv Y. K., Xiong W., Zhu D. Z., Gan L. H., Li L. C., Liu M. X., Chem. Eng. J., 2018, 347, 233
[21]	Miao L., Zhu D. Z., Liu M. X., Duan H., Wang Z. W., Lv Y. K., Xiong W., Zhu Q. J., Li L. C., Chai X. L., Gan L. H., Chem. Eng. J., 2018, 347, 233
[22]	Sarma B., Nangia A., CrystEngComm, 2007, 9, 628
[23]	Mileo P. G. M., Adil K., Davis L., Cadiau A., Belmabkhout Y., Aggarwal H., Maurin G., Eddaoudi M., Devautour-Vinot S., J. Am. Chem. Soc., 2018, 140, 13156
[24]	Karmakar A., Illathvalappil R., Anothumakkool B., Sen A., Samanta P., Desai A. V., Kurungot S., Ghosh S. K., Angew. Chem. Int. Ed., 2016, 55, 10667
[25]	Bazaga-García M., Colodrero R. M. P., Papadaki M., Garczarek P., Zoń J., Olivera-Pastor P., Losilla E. R., León-Reina L., Aranda M. A. G., Choquesillo-Lazarte D., Demadis K. D., Cabeza A., J. Am. Chem. Soc., 2014, 136, 5731
[26]	Nguyen N. T. T., Furukawa H., Gándara F., Trickett C. A., Jeong H. M., Cordova K. E., Yaghi O. M., J. Am. Chem. Soc., 2015, 137, 15394
[27]	Sasmal H. S., Aiyappa H. B., Bhange S. N., Karak S., Halder A., Kurungot S., Banerjee R., Angew. Chem. Int. Ed., 2018, 57, 10894
[28]	Joarder B., Lin J. B., Romero Z., Shimizu G. K. H., J. Am. Chem. Soc., 2017, 139, 7176
[29]	Ramaswamy P., Wong N. E., Gelfand B. S., Shimizu G. K. H., J. Am. Chem. Soc., 2015, 137, 7640
[30]	Wei Y. S., Hu X. P., Han Z., Dong X. Y., Zang S. Q., Mak T. C. W., J. Am. Chem. Soc., 2017, 139, 3505
[31]	Liu M., Chen L. J., Lewis S., Chong S. Y., Little M. A., Hasell T., Aldous I. M., Brown C. M., Smith M. W., Morrison C. A., Hardwick L. J., Cooper A. I., Nat. Commun., 2016, 7, 12750
[32]	Zhang G. Y., Fei H. H., Chem. Commun., 2017, 53, 4156
[33]	Ramaswamy P., Wong N. E., Shimizu G. K. H., Chem. Soc. Rev., 2014, 43, 591

Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

Introduction of H₂SO₄ and H₃PO₄ into Crystalline Porous Organic Salts(CPOS-1) for Outstanding Proton Conductivity

可视化

摘要/Abstract

引用本文

使用本文

参考文献 33

相关文章 7

编辑推荐

Metrics

本文评价

[1]	ZHAO Qi, LIANG Xiaoxiao, YOU Yingxue, WANG Yuliang, DU Xinwei, LIU Baijun, HU Wei. Proton Conductivity Improvement Effect of Cellulose on SPEEKK Based PEM[J]. 高等学校化学研究, 2019, 35(5): 916-923.
[2]	LI Yu-han, WANG Wei-jian, JIN Ri-zhe, GAO Lian-xun. Synthesis and Characterization of Novel Sulfonated Polyimides from 4, 6-Bis(4-aminophenoxy)-naphthalene-2-sulfonic Acid[J]. 高等学校化学研究, 2013, 29(6): 1225-1228.
[3]	QIAO Li-gen, SHI Wen-fang. Preparation and Conducting Behavior of Amphibious Organic/Inorganic Hybrid Proton Exchange Membranes Based on Benzyltetrazole[J]. 高等学校化学研究, 2012, 28(2): 345-352 .
[4]	MA Hai-song, HAO Xiu-feng, LI Xian-feng, ZHAO Cheng-ji, FU Tie-zhu, NA Hui, .... Evolution of Morphology and Properties of Sulfonated Poly(ether ether ketone ketone) Membranes Fabricated via Electrospinning[J]. 高等学校化学研究, 2010, 26(1): 157-160.
[5]	FENG Shou-hua, ZHAO Hui, LI Lian-sheng, Martha Greenblatt . Synthesis, Proton Conductivity and Humidity Sensing Property of γ-Type Zirconium Hydrogen Phosphate, Zr(HPO⁴)²·2H²O[J]. 高等学校化学研究, 1999, 15(1): 5-9.
[6]	WANG Ge, FENG Shou-hua, WANG Bo, Martha Greenblatt. Synthesis,Proton Conductivity and High-Temperature Humidity Sensing Property of Zr(HPO₄)₂·H₂O and Its Aluminium-substituted Compositions[J]. 高等学校化学研究, 1996, 12(4): 313-321.
[7]	WANG En-bo, LI Bai-tao, WANG Zuo-ping, ZHANG Bao-jian. Researches into the Proton Conductivity of Molybdovanadophosphoric Acids with Wells-Dawson Structure[J]. 高等学校化学研究, 1996, 12(4): 322-325.