高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 745-746.doi: 10.1007/s40242-019-1002-5
Geminiarene: A New Macrocyclic Arene with Dual/Gemini Molecular Conformation and Guest Selectivity in the Solid State
XU Jialiang1, BU Xian-He1,2
- 1. School of Materials Science and Engineering, National Institute for Advanced Materials, Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300350, P. R. China;
2. State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China
Geminiarene: A New Macrocyclic Arene with Dual/Gemini Molecular Conformation and Guest Selectivity in the Solid State
XU Jialiang1, BU Xian-He1,2
- 1. School of Materials Science and Engineering, National Institute for Advanced Materials, Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300350, P. R. China;
2. State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China
摘要： Prof. YANG Yingwei and his coworker from Jilin University reported an entirely new kind of macrocyclic arene, namely geminiarene, featuring two different but interconvertible molecular configurations. Taking advantage of the dual/gemini conformational feature and the unique host-guest property of geminiarene, they developed unitary and dual guest selective adsorption/separation systems, in particular toward chlorobenzene and chlorocyclohexane.