Impregnated Sulfur in Carbonized Nitrogen-containing Porous Organic Frameworks as Cathode with High Rate Performance and Long Cycle Life for Lithium-sulfur Batteries

doi:10.1007/s40242-019-9038-0

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 654-661.doi: 10.1007/s40242-019-9038-0

Impregnated Sulfur in Carbonized Nitrogen-containing Porous Organic Frameworks as Cathode with High Rate Performance and Long Cycle Life for Lithium-sulfur Batteries

DONG Yan^1,2, BEN Teng¹

1. Department of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Department of Bioengineering, Zunyi Medical University(Zhuhai Campus), Zhuhai 519041, P. R. China

收稿日期:2019-02-10 修回日期:2019-05-05 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: BEN Teng E-mail:tben@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21871103) and the Foundation of Science and Techno-logy Department of Jilin Province, China(No.20180414009GH).

Impregnated Sulfur in Carbonized Nitrogen-containing Porous Organic Frameworks as Cathode with High Rate Performance and Long Cycle Life for Lithium-sulfur Batteries

DONG Yan^1,2, BEN Teng¹

1. Department of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Department of Bioengineering, Zunyi Medical University(Zhuhai Campus), Zhuhai 519041, P. R. China

Received:2019-02-10 Revised:2019-05-05 Online:2019-08-01 Published:2019-08-01
Contact: BEN Teng E-mail:tben@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21871103) and the Foundation of Science and Techno-logy Department of Jilin Province, China(No.20180414009GH).

摘要/Abstract

摘要： The undesirable cycling performance caused by soluble polysulfides shuttling between anode and cathode has been considered as the main challenge that has hindered its practical applications for lithium-sulfur(Li-S) batteries. To solve this issue effectively, a nitrogen-containing porous carbon, namely JUC-Z2-900, developed from a porous organic framework, namely JUC-Z2, bearing a high surface area(805 m²/g), small pore size(0.5 nm) and nitrogen doping(2.15%, mass fraction), has been used as a host material for Li-S batteries. The micropores of JUC-Z2-900 can confine the smaller sulfur molecules S_2-4, which can essentially alleviate the critical problem of polysulfide dissolution. Furthermore, nitrogen-containing JUC-Z2-900 can promote chemical adsorption of sulfur. The above two factors can improve the electrochemical performance of Li-S batteries effectively. To compare the effects of sulfur contents and melt-diffusion strategy in JUC-Z2-900/S composites, a series of JUC-Z2-900/S composites was synthesized and their electrochemical performances were explored, indicating good rate performance and excellent cycling stability of the composites contributed by both appropriate mass percentage of sulfur and its confinement in the micropores.

关键词: Li-S battery, Nitrogen-containing porous carbon, Porous organic framework

Abstract: The undesirable cycling performance caused by soluble polysulfides shuttling between anode and cathode has been considered as the main challenge that has hindered its practical applications for lithium-sulfur(Li-S) batteries. To solve this issue effectively, a nitrogen-containing porous carbon, namely JUC-Z2-900, developed from a porous organic framework, namely JUC-Z2, bearing a high surface area(805 m²/g), small pore size(0.5 nm) and nitrogen doping(2.15%, mass fraction), has been used as a host material for Li-S batteries. The micropores of JUC-Z2-900 can confine the smaller sulfur molecules S_2-4, which can essentially alleviate the critical problem of polysulfide dissolution. Furthermore, nitrogen-containing JUC-Z2-900 can promote chemical adsorption of sulfur. The above two factors can improve the electrochemical performance of Li-S batteries effectively. To compare the effects of sulfur contents and melt-diffusion strategy in JUC-Z2-900/S composites, a series of JUC-Z2-900/S composites was synthesized and their electrochemical performances were explored, indicating good rate performance and excellent cycling stability of the composites contributed by both appropriate mass percentage of sulfur and its confinement in the micropores.

Key words: Li-S battery, Nitrogen-containing porous carbon, Porous organic framework

DONG Yan, BEN Teng. Impregnated Sulfur in Carbonized Nitrogen-containing Porous Organic Frameworks as Cathode with High Rate Performance and Long Cycle Life for Lithium-sulfur Batteries[J]. 高等学校化学研究, 2019, 35(4): 654-661.

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Impregnated Sulfur in Carbonized Nitrogen-containing Porous Organic Frameworks as Cathode with High Rate Performance and Long Cycle Life for Lithium-sulfur Batteries

Impregnated Sulfur in Carbonized Nitrogen-containing Porous Organic Frameworks as Cathode with High Rate Performance and Long Cycle Life for Lithium-sulfur Batteries

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