Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates[Ni(1,2-dap)3] [As2CdSe4],[Zn(1,2-dap)3] [As2CdSe4] and[Ni(en)3] [As2CdSe4]

doi:10.1007/s40242-019-9011-y

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 560-563.doi: 10.1007/s40242-019-9011-y

Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates[Ni(1,2-dap)₃] [As₂CdSe₄],[Zn(1,2-dap)₃] [As₂CdSe₄] and[Ni(en)₃] [As₂CdSe₄]

DU Cuixia, CHEN Juan, BAIYIN Menghe

College of Chemistry & amp;Environmental Science, Inner Mongolia Normal University, Hohhot 010022, P. R. China

收稿日期:2019-01-09 修回日期:2019-04-30 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: BAIYIN Menghe E-mail:baiymh@163.com
基金资助:
Supported by the National Natural Science Foundation of China(No.21461019).

Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates[Ni(1,2-dap)₃] [As₂CdSe₄],[Zn(1,2-dap)₃] [As₂CdSe₄] and[Ni(en)₃] [As₂CdSe₄]

DU Cuixia, CHEN Juan, BAIYIN Menghe

College of Chemistry & amp;Environmental Science, Inner Mongolia Normal University, Hohhot 010022, P. R. China

Received:2019-01-09 Revised:2019-04-30 Online:2019-08-01 Published:2019-08-01
Contact: BAIYIN Menghe E-mail:baiymh@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21461019).

摘要/Abstract

摘要： Three new cadmium selenidoarsenates,[Ni(1,2-dap)₃] [As₂CdSe₄](1)(1,2-dap=1,2-diaminopropane),[Zn(1,2-dap)₃] [As₂CdSe₄](2) and[Ni(en)₃] [As₂CdSe₄](3)(en=ethylenediamine), were synthesized under solvothermal conditions. And they are isostructural and monoclinic crystalls. As seen from their structures,they exhibited one-dimensional(1D) chains composed of[As₂CdSe₄]^2- anions and[TM(amine)₃]²⁺(TM=Ni, Zn; amine=1,2-dap, en) cations. Their absorption edges are 2.32, 1.84 and 2.38 eV, and they show the properties of the semiconductor. These compounds were also characterized by means of single-crystal X-ray diffraction(XRD), powder X-ray diffraction (PXRD), solid-state optical absorption spectrometry, and so on.

关键词: Solvothermal synthesis, Selenidoarsenate, Cadmium

Abstract: Three new cadmium selenidoarsenates,[Ni(1,2-dap)₃] [As₂CdSe₄](1)(1,2-dap=1,2-diaminopropane),[Zn(1,2-dap)₃] [As₂CdSe₄](2) and[Ni(en)₃] [As₂CdSe₄](3)(en=ethylenediamine), were synthesized under solvothermal conditions. And they are isostructural and monoclinic crystalls. As seen from their structures,they exhibited one-dimensional(1D) chains composed of[As₂CdSe₄]^2- anions and[TM(amine)₃]²⁺(TM=Ni, Zn; amine=1,2-dap, en) cations. Their absorption edges are 2.32, 1.84 and 2.38 eV, and they show the properties of the semiconductor. These compounds were also characterized by means of single-crystal X-ray diffraction(XRD), powder X-ray diffraction (PXRD), solid-state optical absorption spectrometry, and so on.

Key words: Solvothermal synthesis, Selenidoarsenate, Cadmium

DU Cuixia, CHEN Juan, BAIYIN Menghe. Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates[Ni(1,2-dap)₃] [As₂CdSe₄],[Zn(1,2-dap)₃] [As₂CdSe₄] and[Ni(en)₃] [As₂CdSe₄][J]. 高等学校化学研究, 2019, 35(4): 560-563.

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Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates[Ni(1,2-dap)₃] [As₂CdSe₄],[Zn(1,2-dap)₃] [As₂CdSe₄] and[Ni(en)₃] [As₂CdSe₄]

Solvothermal Syntheses and Characterization of Three One-dimension Cadmium Selenidoarsenates[Ni(1,2-dap)₃] [As₂CdSe₄],[Zn(1,2-dap)₃] [As₂CdSe₄] and[Ni(en)₃] [As₂CdSe₄]

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