Mixed-phase Mesoporous TiO2 Film for High Efficiency Perovskite Solar Cells

doi:10.1007/s40242-018-8201-3

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (1): 101-108.doi: 10.1007/s40242-018-8201-3

Mixed-phase Mesoporous TiO₂ Film for High Efficiency Perovskite Solar Cells

XIANG Yan, ZHUANG Jia, MA Zhu, LU Honglin, XIA Haoran, ZHOU Weiya, ZHANG Tao, LI Haimin

School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, P. R. China

收稿日期:2018-06-19 修回日期:2018-09-05 出版日期:2019-02-01 发布日期:2018-09-29
通讯作者: ZHUANG Jia, MA Zhu E-mail:zj-656@163.com;deve198509@163.com
基金资助:
Supported by the Science and Technology Program of Sichuan Province, China(No.2018JY0015), the Young Scholars Development Fund of Southwest Petroleum University, China(No.201699010017) and the Scientific Research Starting Project of Southwest Petroleum University, China(No.2017QHZ021).

Mixed-phase Mesoporous TiO₂ Film for High Efficiency Perovskite Solar Cells

XIANG Yan, ZHUANG Jia, MA Zhu, LU Honglin, XIA Haoran, ZHOU Weiya, ZHANG Tao, LI Haimin

School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, P. R. China

Received:2018-06-19 Revised:2018-09-05 Online:2019-02-01 Published:2018-09-29
Contact: ZHUANG Jia, MA Zhu E-mail:zj-656@163.com;deve198509@163.com
Supported by:
Supported by the Science and Technology Program of Sichuan Province, China(No.2018JY0015), the Young Scholars Development Fund of Southwest Petroleum University, China(No.201699010017) and the Scientific Research Starting Project of Southwest Petroleum University, China(No.2017QHZ021).

摘要/Abstract

摘要： Mesoporous scaffold structures have played great roles in halide perovskite solar cells (PSCs), due to the excellent photovoltaic performance and commercial perspective of mesoporous PSCs. Here, we reported a mixed-phase TiO₂ mesoporous film as an efficient electron transport layer (ETL) for mesoporous perovskite solar cells. Due to the improved crystal phase, film thickness and nanoparticle size of TiO₂ layer, which were controlled by varying the one-step hydrothermal reaction time and annealing time, the PSCs exhibited an outstanding short circuit photocurrent density of 25.27 mA/cm², and a maximum power conversion efficiency (PCE) of 19.87%. It is found that the ultra-high J_sc attributes to the excellent film quality, light capturing and excellent electron transport ability of mixed-phase TiO₂ mesoporous film. The results indicate that mix-phase mesoporous metal oxide films could be a promising candidate for producing effective ETLs and high efficiency PSCs.

关键词: Mesoporous perovskite solar cell, Mixed-phase TiO₂, Hydrothermal method, Nanoparticle, Electron recombination

Abstract: Mesoporous scaffold structures have played great roles in halide perovskite solar cells (PSCs), due to the excellent photovoltaic performance and commercial perspective of mesoporous PSCs. Here, we reported a mixed-phase TiO₂ mesoporous film as an efficient electron transport layer (ETL) for mesoporous perovskite solar cells. Due to the improved crystal phase, film thickness and nanoparticle size of TiO₂ layer, which were controlled by varying the one-step hydrothermal reaction time and annealing time, the PSCs exhibited an outstanding short circuit photocurrent density of 25.27 mA/cm², and a maximum power conversion efficiency (PCE) of 19.87%. It is found that the ultra-high J_sc attributes to the excellent film quality, light capturing and excellent electron transport ability of mixed-phase TiO₂ mesoporous film. The results indicate that mix-phase mesoporous metal oxide films could be a promising candidate for producing effective ETLs and high efficiency PSCs.

Key words: Mesoporous perovskite solar cell, Mixed-phase TiO₂, Hydrothermal method, Nanoparticle, Electron recombination

XIANG Yan, ZHUANG Jia, MA Zhu, LU Honglin, XIA Haoran, ZHOU Weiya, ZHANG Tao, LI Haimin. Mixed-phase Mesoporous TiO₂ Film for High Efficiency Perovskite Solar Cells[J]. 高等学校化学研究, 2019, 35(1): 101-108.

XIANG Yan, ZHUANG Jia, MA Zhu, LU Honglin, XIA Haoran, ZHOU Weiya, ZHANG Tao, LI Haimin. Mixed-phase Mesoporous TiO₂ Film for High Efficiency Perovskite Solar Cells[J]. Chemical Research in Chinese Universities, 2019, 35(1): 101-108.

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Mixed-phase Mesoporous TiO₂ Film for High Efficiency Perovskite Solar Cells

Mixed-phase Mesoporous TiO₂ Film for High Efficiency Perovskite Solar Cells

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