Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions

doi:10.1007/s40242-018-7375-z

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (3): 500-505.doi: 10.1007/s40242-018-7375-z

Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions

LIU Li¹, PAN Ge¹, WANG Licheng², REN Xiuyan¹, ZHANG Xinyue¹, WU Guangfeng¹

1. School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2017-11-22 修回日期:2018-02-07 出版日期:2018-06-01 发布日期:2018-03-26
通讯作者: WU Guangfeng E-mail:gfwu@ccut.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.51173020).

Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions

LIU Li¹, PAN Ge¹, WANG Licheng², REN Xiuyan¹, ZHANG Xinyue¹, WU Guangfeng¹

1. School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2017-11-22 Revised:2018-02-07 Online:2018-06-01 Published:2018-03-26
Contact: 10.1007/s40242-018-7375-z E-mail:gfwu@ccut.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.51173020).

摘要/Abstract

摘要： Polystyrene nanoparticles with negative charges(n-PSs) were synthesized using styrene(St) and sodium styrene sulfonate(NaSS) as initial materials by surfactant-free emulsion polymerization. Subsequently, a hybrid hydrogel was prepared using acrylamide(AAm) and methacryloyloxyethyltrimethyl ammonium chloride(DMC) as co-monomers with N,N'-methylenebisacrylamide(MBA) as a chemical crosslinker and n-PSs as a physical electro-static interaction agent. The resulting hybrid hydrogels exhibited excellent tensile strength and elongation at break. The tensile stress of hybrid hydrogels was seven times greater than that of hydrogels without n-PSs. The elongation at break of hydrogels reached 700%, which was much higher compared to those of the hydrogels without n-PSs. Furthermore, swelling measurements of the hydrogels indicate that there is an overshoot in the swelling process and the extent of overshoot decreases with the increasing n-PSs. Therefore, the work presented here provides a method for improving the mechanical properties of hydrogels via the introduction of polymeric nanoparticles.

关键词: Hydrogel, Electrostatic interaction, Mechanical property, Swelling property

Abstract: Polystyrene nanoparticles with negative charges(n-PSs) were synthesized using styrene(St) and sodium styrene sulfonate(NaSS) as initial materials by surfactant-free emulsion polymerization. Subsequently, a hybrid hydrogel was prepared using acrylamide(AAm) and methacryloyloxyethyltrimethyl ammonium chloride(DMC) as co-monomers with N,N'-methylenebisacrylamide(MBA) as a chemical crosslinker and n-PSs as a physical electro-static interaction agent. The resulting hybrid hydrogels exhibited excellent tensile strength and elongation at break. The tensile stress of hybrid hydrogels was seven times greater than that of hydrogels without n-PSs. The elongation at break of hydrogels reached 700%, which was much higher compared to those of the hydrogels without n-PSs. Furthermore, swelling measurements of the hydrogels indicate that there is an overshoot in the swelling process and the extent of overshoot decreases with the increasing n-PSs. Therefore, the work presented here provides a method for improving the mechanical properties of hydrogels via the introduction of polymeric nanoparticles.

Key words: Hydrogel, Electrostatic interaction, Mechanical property, Swelling property

LIU Li, PAN Ge, WANG Licheng, REN Xiuyan, ZHANG Xinyue, WU Guangfeng. Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions[J]. 高等学校化学研究, 2018, 34(3): 500-505.

LIU Li, PAN Ge, WANG Licheng, REN Xiuyan, ZHANG Xinyue, WU Guangfeng. Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions[J]. Chemical Research in Chinese Universities, 2018, 34(3): 500-505.

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Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions

Hybrid Hydrogels Toughened by Chemical Covalent Bonding and Physical Electrostatic Interactions

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