Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

doi:10.1007/s40242-018-7173-7

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (1): 138-144.doi: 10.1007/s40242-018-7173-7

Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

DONG Lei¹, LIU Huan¹, LI Yanjuan², ZHANG Hongtao¹, YU Liangmin¹, JIA Lanni^3,4

1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China;
2. School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou 221116, P. R. China;
3. National Engineering Research Center for Marine Drugs, Ocean University of China, Qingdao 266071, P. R. China;
4. Marine Biomedical Research Institute of Qingdao, Qingdao 266071, P. R. China

收稿日期:2017-05-15 出版日期:2018-02-01 发布日期:2018-01-20
通讯作者: YU Liangmin,E-mail:yuyan@ouc.edu.cn;JIA Lanni,E-mail:jialann@163.com E-mail:yuyan@ouc.edu.cn;jialann@163.com
基金资助:
Supported by the National Natural Science Foundation of China(No.51102219) and the Fundamental Research Funds for the Central Universities of China(Nos.201113024, 41404010204).

Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

DONG Lei¹, LIU Huan¹, LI Yanjuan², ZHANG Hongtao¹, YU Liangmin¹, JIA Lanni^3,4

1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China;
2. School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou 221116, P. R. China;
3. National Engineering Research Center for Marine Drugs, Ocean University of China, Qingdao 266071, P. R. China;
4. Marine Biomedical Research Institute of Qingdao, Qingdao 266071, P. R. China

Received:2017-05-15 Online:2018-02-01 Published:2018-01-20
Contact: YU Liangmin,E-mail:yuyan@ouc.edu.cn;JIA Lanni,E-mail:jialann@163.com E-mail:yuyan@ouc.edu.cn;jialann@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.51102219) and the Fundamental Research Funds for the Central Universities of China(Nos.201113024, 41404010204).

摘要/Abstract

摘要： To determine the template effect of hydrophobically associating copolymers(HACPs) on the morphology of nano/micro structures, six HACPs were synthesized and used as templates to biomimetically synthesize cuprous oxide(Cu₂O), an important semiconductor. This experiment showed a clear relationship between the associating state of the HACP molecules and the morphology of the Cu₂O particles. Cu₂O hollow spheres were preferentially prepared when the HACP molecules were in an intramolecular associating state. Furthermore, a Cu₂O hexapod was easily obtained when the HACP molecules were in an intermolecular associating state. The morphologies of the Cu₂O crystals prepared in the presence of the HACPs also confirmed this result.

关键词: Template, Hydrophobically associating polymer, Cuprous oxide, Morphology

Abstract: To determine the template effect of hydrophobically associating copolymers(HACPs) on the morphology of nano/micro structures, six HACPs were synthesized and used as templates to biomimetically synthesize cuprous oxide(Cu₂O), an important semiconductor. This experiment showed a clear relationship between the associating state of the HACP molecules and the morphology of the Cu₂O particles. Cu₂O hollow spheres were preferentially prepared when the HACP molecules were in an intramolecular associating state. Furthermore, a Cu₂O hexapod was easily obtained when the HACP molecules were in an intermolecular associating state. The morphologies of the Cu₂O crystals prepared in the presence of the HACPs also confirmed this result.

Key words: Template, Hydrophobically associating polymer, Cuprous oxide, Morphology

DONG Lei, LIU Huan, LI Yanjuan, ZHANG Hongtao, YU Liangmin, JIA Lanni. Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure[J]. 高等学校化学研究, 2018, 34(1): 138-144.

参考文献

[1] Mnna S., Nature, 1993, 365(7), 499
[2] Weiner S., Addadi L., J. Mater. Chem., 1997, 7(5), 689
[3] Annenkov V. V., Danilovtseva E. N., Pal'shin V. A., RSC Adv., 2017, 7, 20995
[4] Hartgerink J. D., Beniash E., Stupp S. I., Science, 2001, 294(5547), 1684
[5] Zheng Z., Huang B., Ma H., Cryst. Growth Des., 2007, 7(9), 1912
[6] Yan B. Q., Nan Z. D., Liu Y., Chinese J. Chem., 2008, 26(12), 2302
[7] Finnemore A., Cunha P., Shean T., Nat. Com., 2012, 3, 966
[8] Banerjee I. Yu A. L., Matsui H., J. Am. Chem. Soc., 2003, 125(32), 9542
[9] Zhang D., Qi L., Ma J., Cheng H., Chem. Mater., 2001, 13(9), 2753
[10] Qi L., Colfen H., Antonietti M., Nano Lett., 2001, 1(2), 61
[11] Bastakoti B. P., Guragain S., Yokoyama Y., Langmuir, 2011, 27(1), 379
[12] Ng C. H. B., Fan W. Y., J. Phys. Chem. B, 2006, 110(42), 20801
[13] Du S. S., Cheng P. F., Sun P., Wang B., Cai Y. X., Chem. Res. Chinese Universities, 2014, 30(4), 661
[14] Poizot P., Laruelle S., Grugeon S., Dupont L., Taracon J. M., Nature, 2000, 407, 496
[15] Qiu X. Q., Miyauchi M., Sunada K., Minoshima M., ACS Nano, 2012, 6(2), 1609
[16] Chang Y., Teo J. J., Zeng H. C., Langmuir, 2005, 21(3), 1074
[17] Xu J. S., Xue D. F., Acta. Mater., 2007, 55, 2397
[18] Yu L. M., An Z. G., Dong L., Paint Coat. Ind., 2007, 37(7), 70
[19] Jia L. N., Yu L. M., Li R., J. Appl. Polym. Sci., 2013, 130(3), 1794
[20] Feng Y. J., Billon L., Grassl B., Polymer, 2002, 43(7), 2055
[21] Pu H. T., Jiang W. C., Liu L., Chem. J. Chinese Universities, 2005, 26(9), 1743
[22] Gao B. J., Jiang L. D., Liu K. K., Eur. Poly. J., 2007, 43(10), 4530
[23] Dobrynin A. V., Rubinstein M., Macromolecules, 1999, 32(3), 915
[24] Dobrynin A. V., Rubinstein M., Macromolecules, 2000, 33(21), 8097
[25] Zhang L., Eisenberg A., Macromolecules, 1999, 32, 2239
[26] Zhang L., Eisenberg A., Polym. Adv. Technol., 1998, 9, 677
[27] Jiang L. F., Zhong C. R., Xu M., Acta Phys.-Chim. Sin., 2010, 26(3), 535

Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

Template Effect of Hydrophobically Associating Polymers on theConstruction of Cuprous Oxide Micro Structure

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	LI Jun, RONG Huazhen, CHEN Cong, LI Ziyi, ZUO Jiayu, WANG Wenjian, LIU Xinjian, GUAN Yixing, YANG Xiong, LIU Yingshu, ZOU Xiaoqin, ZHU Guangshan. Synthesis Optimization of SSZ-13 Zeolite Membranes by Dual Templates for N₂/NO₂ Separation[J]. 高等学校化学研究, 2022, 38(1): 250-256.
[2]	YANG Shaobo, CAO Yuanyuan, WANG Shuqi, LI Yongsheng, SHI Jianlin. Understanding on the Surfactants Engineered Morphology Evolution of Block Copolymer Particles and Their Precise Mesoporous Silica Replicas[J]. 高等学校化学研究, 2022, 38(1): 99-106.
[3]	Andy Shun-Hoi CHEUNG, Sammual Yu-Lut LEUNG, Franky Ka-Wah HAU, Vivian Wing-Wah YAM. Supramolecular Self-assembly of Amphiphilic Alkynyl-platinum(II) 2,6-Bis(N-alkylbenzimidazol-2'-yl) pyridine Complexes[J]. 高等学校化学研究, 2021, 37(5): 1079-1084.
[4]	ZHAO Lei, YANG Ge, GUO Hailing, WANG Chunzheng, WANG Lijuan, Svetlana MINTOVA. Effect of Sodium Concentration on the Synthesis of Faujasite by Two-step Synthesis Procedure[J]. 高等学校化学研究, 2021, 37(5): 1137-1142.
[5]	ZHU Jinjin, SHANG Yingxu, YU Haiyin, LI Na, DING Baoquan. Shape-controllable Synthesis of Functional Nanomaterials on DNA Templates[J]. 高等学校化学研究, 2020, 36(2): 171-176.
[6]	LIN Xinchen, XIE Feng, YU Xiaodan, TANG Xin, GUAN Heda, CHEN Yu, FENG Wei. Ultraviolet Light Assisted Hierarchical Porous Fe₂O₃ Catalyzing Heterogeneous Fenton Degradation of Tetracycline Under Neutral Condition with a Low Requirement of H₂O₂[J]. 高等学校化学研究, 2019, 35(2): 304-310.
[7]	XIA Qi, PAN Shaofeng, ZHANG Yi, AN Qi, ZHANG Qian, ZHANG Yihe. Preparation of Highly Loaded PAA/PAH Layer-by-layer Films by Combining Acid Transformation and Templating Methods[J]. 高等学校化学研究, 2019, 35(2): 353-358.
[8]	MENG Qingling, XIE Chenchen, DING Ran, CAO Liang, MA Ke, LI Li, WENG Zhankun and WANG Zuobin. Bio-template Synthesis of Spirulina/α-Fe₂O₃ Composite with Improved Surface Wettability[J]. 高等学校化学研究, 2018, 34(6): 1058-1062.
[9]	LIU Xiaofang, ZENG Shangjing, WANG Runwei, ZHANG Zongtao, QIU Shilun. Sustainable Synthesis of Hierarchically Porous Silicalite-1 Zeolite by Steam-assisted Crystallization of Solid Raw Materials Without Secondary Templates[J]. 高等学校化学研究, 2018, 34(3): 350-357.
[10]	YU Ke, DIAO Tingting, ZHU Junjiang, ZHAO Zhen. Perovskite Oxides La_0.8Sr_0.2Co_1-xFe_xO₃ for CO Oxidation and CO+NO Reduction: Effect of Redox Property and Surface Morphology[J]. 高等学校化学研究, 2018, 34(1): 119-126.
[11]	LIU Yanfeng, LIU Boliang, ZHOU Qingfeng, ZHANG Tianyong, WU Wubin. Morphology Effect of Metal-organic Framework HKUST-1 as a Catalyst on Benzene Oxidation[J]. 高等学校化学研究, 2017, 33(6): 971-978.
[12]	KONG Chao, HAN Yanxia, HOU Lijie, CHEN Dongping, WU Bowan. Effect of Synthetic Method and Reductant on the Morphology and Photocatalytic Hydrogen Evolution Performance of Ru Nanoparticles[J]. 高等学校化学研究, 2017, 33(5): 816-821.
[13]	ZHANG Chunxia, XU Xu, ZHANG Panpan, DANG Yang, KANG Bonan. Polymer Solar Cells with Improved Power Conversion Efficiency Using Solvent Mixtures[J]. 高等学校化学研究, 2017, 33(3): 466-470.
[14]	JIA Yongchang, WANG Shuyuan, LU Jiqing, LUO Mengfei. Effect of Structural Properties of Mesoporous Co₃O₄ Catalysts on Methane Combustion[J]. 高等学校化学研究, 2016, 32(5): 808-811.
[15]	YU Jingfeng, LI Zhiying, LIU Xiaoli, SONG Sanan, GAO Ge, ZHANG Qing, LIU Fengqi. Molecular Size and Morphology of Single Chains of Poly(sulfobetaine methacrylate)[J]. 高等学校化学研究, 2016, 32(3): 499-504.