Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO2 Hydrogenation to Methanol

doi:10.1007/s40242-016-6130-6

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (6): 1005-1009.doi: 10.1007/s40242-016-6130-6

Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol

BEN Shunge, YUAN Fulong, ZHU Yujun

Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University), Ministry of Education, School of Chemistry and Materials, Heilongjiang University, Harbin 150080, P. R. China

收稿日期:2016-04-05 修回日期:2016-08-25 出版日期:2016-12-01 发布日期:2016-09-19
通讯作者: YUAN Fulong, E-mail:fulongyuan2000@yahoo.com; ZHU Yujun, E-mail:yujunzhu@hlju.edu.cn E-mail:fulongyuan2000@yahoo.com;yujunzhu@hlju.edu.cn
基金资助:
Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China(No.2013-1792) and the Ministry of Human Resources and Social Security, China(No.2013-277).

Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol

BEN Shunge, YUAN Fulong, ZHU Yujun

Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University), Ministry of Education, School of Chemistry and Materials, Heilongjiang University, Harbin 150080, P. R. China

Received:2016-04-05 Revised:2016-08-25 Online:2016-12-01 Published:2016-09-19
Contact: YUAN Fulong, E-mail:fulongyuan2000@yahoo.com; ZHU Yujun, E-mail:yujunzhu@hlju.edu.cn E-mail:fulongyuan2000@yahoo.com;yujunzhu@hlju.edu.cn
Supported by:
Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China(No.2013-1792) and the Ministry of Human Resources and Social Security, China(No.2013-277).

摘要/Abstract

摘要：

A series of 50%CuO-25%ZnO-25%Al(Zr) oxide catalysts was synthesized by a reverse co-precipitation method and characterized by XRD, N₂ adsorption-desorption, H₂-TPR, H₂-TPD and CO₂-TPD, and used as catalyst for CO₂ hydrogenation to methanol under mild conditions(200-260℃ and 1-3 MPa). Consequently, H₂-TPR exhibited that the dispersed CuO species increased with the zirconium content, while the H₂-TPD showed that small amount of zirconia can increase the H₂ desorption amount. As a result, Cat-2 and Cat-3 exhibited an enhanced H₂-spillover effect, the most H₂ desorption amount, which showed an optimum activity of about 7% methanol yield.

关键词: Carbon dioxide, Reverse co-precipitation, Methanol, Catalytic hydrogenation, Copper based catalyst

Abstract:

Key words: Carbon dioxide, Reverse co-precipitation, Methanol, Catalytic hydrogenation, Copper based catalyst

BEN Shunge, YUAN Fulong, ZHU Yujun. Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol[J]. 高等学校化学研究, 2016, 32(6): 1005-1009.

BEN Shunge, YUAN Fulong, ZHU Yujun. Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol[J]. Chemical Research in Chinese Universities, 2016, 32(6): 1005-1009.

参考文献

[1] Chen Q., Lv M., Tang Z., Wang H., Wei W., Sun Y., J. CO₂ Util., 2016, 14, 1
[2] Wang W., Wang S., Ma X., Gong J., Chem. Soc. Rev., 2011, 40(7), 3703
[3] Li L., Zhao N., Wei W., Sun Y., Fuel, 2013, 108, 112
[4] Munshi P., Main A. D., Linehan J. C., Tai C. C., Jessop P. G., J. Am. Chem. Soc., 2002, 124(27), 7963
[5] Bai H. P., Zheng Y. P., Li P. P., Zhang A. B., Chem. Res. Chinese Universities, 2015, 31(3), 488
[6] Gao P., Li F., Xiao F., Zhao N., Wei W., Zhong L., Sun Y., Catal. Today, 2012, 194(1), 9
[7] Raudaskoski R., Niemelä M. V., Keiski R. L., Top. Catal., 2007, 45(1-4), 57
[8] Gao P., Li F., Zhan H., Zhao N., Xiao F., Wei W., Zhong L., Wang H., Sun Y., J. Catal., 2013, 298, 51
[9] Arena F., Mezzatesta G., Zafarana G., Trunfio G., Frusteri F., Spadaro L., J. Catal., 2013, 300, 141
[10] Grabowski R., S?oczyński J., ?liwa M., Mucha D., Socha R. P., Lachowska M., Skrzypek J., ACS Catal., 2011, 1(4), 266
[11] Kwak J. H., Kovarik L., Szanyi J., ACS Catal., 2013, 3(11), 2449
[12] Zhang R., Liu H., Wang B., Ling L., Appl. Catal. B, 2012, 126, 108
[13] Liang X. L., Dong X., Lin G. D., Zhang H. B., Appl. Catal. B, 2009, 88(3/4), 315
[14] Karelovic A., Bargibant A., Fernández C., Ruiz P., Catal. Today, 2012, 197(1), 109
[15] Ernst K. H., Schlatterbeck D., Christmann K., Phys. Chem. Chem. Phys., 1999, 1(17), 4105
[16] Li Z. X., Na W., Wang H., Gao W. G., Chem. J. Chinese Universities, 2014, 35(12), 2616
[17] Liu R., Zha F., Yang A. M., Chang Y., Chem. J. Chinese Universities, 2016, 37(5), 964
[18] Zhang Y. N., Li J. L., Huang X. R., Chem. J. Chinese Universities, 2016, 37(3), 534
[19] Shishido T., Yamamoto M., Li D., Tian Y., Morioka H., Honda M., Sano T., Takehira K., Appl. Catal. A, 2006, 303(1), 62
[20] Jones S. D., Neal L. M., Hagelin-Weaver H. E., Appl. Catal. B, 2008, 84(3/4), 631
[21] Baltes C., Vukojevic S., Schuth F., J. Catal., 2008, 258(2), 334
[22] Wang D., Tao F., Zhao H., Song H., Chou L., Chinese J. Catal., 2011, 32(9/10), 1452
[23] Ladera R., Pérez-Alonso F. J., González-Carballo J. M., Ojeda M., Rojas S., Fierro J. L. G., Appl. Catal. B, 2013, 142/143, 241
[24] Zhuang H. D., Bai S. F., Liu X. M., Yan Z. F., J. Fuel Chem. Technol., 2010, 38(4), 462
[25] Collins S. E., Chiavassa D. L., Bonivardi A. L., Baltanás M. A., Catal. Lett., 2005, 103(1/2), 83
[26] Guo X., Mao D., Lu G., Wang S., Wu G., Catal. Commun., 2011, 12(12), 1095
[27] Wu D. L., Jiang W., Liu X. Q., Qiu N. X., Xue Y., Chem. Res. Chinese Universities, 2016, 32(1), 118
[28] Zhao Y. F., Yang Y., Mims C., Peden C. H. F., Li J., Mei D., J. Catal., 2011, 281(2), 199
[29] Medford A. J., Sehested J., Rossmeisl J., Chorkendorff I., Studt F., Nørskov J. K., Moses P. G., J. Catal., 2014, 309, 397
[30] Grabow L. C., Mavrikakis M., ACS Catal., 2011, 1(4), 365
[31] Wang D., Zhao J., Song H., Chou L., J. Nat. Gas Chem., 2011, 20(6), 629
[32] Baltes C., Vukojevic S., Schuth F., J. Catal., 2008, 258, 334
[33] Behrens M., Kasatkin I., Kühl S., Weinberg G., Chem. Mater., 2010, 22(2), 386
[34] Arena F., Italiano G., Barbera K., Bordiga S., Bonura G., Spadaro L., Frusteri F., Appl. Catal. A, 2008, 350(1), 16
[35] An X., Li J., Zuo Y., Zhang Q., Wang D., Wang J., Catal. Lett., 2007, 118(3/4), 264
[36] Li C., Yuan X., Fujimoto K., Appl. Catal. A, 2014, 469, 306
[37] Kong L. Z., Wang Q., Xu L., Yan Y. S., Li H. M., Yang X. G., Chem. J. Chinese Universities, 2015, 36(7), 1372
[38] Wambach J., Baiker A., Wokaun A., Phys. Chem. Chem. Phys., 1999, 1(22), 5071
[39] Guo X., Mao D., Wang S., Wu G., Lu G., Catal. Commun., 2009, 10(13), 1661
[40] Arena F., Mezzatesta G., Zafarana G., Trunfio G., Frusteri F., Spadaro L., Catal. Today, 2013, 210, 39
[41] Jia L., Gao J., Fang W., Li Q., J. Rare Earth., 2010, 28(5), 747
[42] Zhan H., Li F., Gao P., Zhao N., Xiao F., Wei W., Zhong L., Sun Y., J. Power Sources, 2014, 251, 113

Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol

Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol

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