Preparation of Single-handed Helical and C-Shaped 3-Aminophenol-formaldehyde Resin Nanotubes and Single-handed Helical Carbonaceous Nanotubes

doi:10.1007/s40242-016-6069-7

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (5): 862-866.doi: 10.1007/s40242-016-6069-7

Preparation of Single-handed Helical and C-Shaped 3-Aminophenol-formaldehyde Resin Nanotubes and Single-handed Helical Carbonaceous Nanotubes

CAO Yanfang, LIU Dan, LI Baozong, LI Yi, YANG Yonggang

State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

收稿日期:2016-02-29 修回日期:2016-05-24 出版日期:2016-10-01 发布日期:2016-07-18
通讯作者: LI Yi E-mail:liyi@suda.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.51473106, 21574095) and the Science and Technology Plan(Nano Special) of Suzhou, China(No.ZXG201415).

Preparation of Single-handed Helical and C-Shaped 3-Aminophenol-formaldehyde Resin Nanotubes and Single-handed Helical Carbonaceous Nanotubes

CAO Yanfang, LIU Dan, LI Baozong, LI Yi, YANG Yonggang

State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

Received:2016-02-29 Revised:2016-05-24 Online:2016-10-01 Published:2016-07-18
Contact: LI Yi E-mail:liyi@suda.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51473106, 21574095) and the Science and Technology Plan(Nano Special) of Suzhou, China(No.ZXG201415).

摘要/Abstract

摘要：

Single-handed helical and C-shaped 3-aminophenol-formaldehyde resin nanotubes were prepared via a supramolecular templating approach. The chiral templates and 3-aminophenol were initially organized into helical nanoribbons, followed by the adsorption of formaldehyde onto the surfaces of the helical nanoribbons. Subsequent to polymerization and further thermosetting of the resin oligomers, 3-aminophenol-formaldehyde resin nanotubes were obtained after removing the templates. When low amounts of 3-aminophenol were added, straight C-shaped 3-aminophenol-formaldehyde resin nanotubes were obtained. Increasing the amount of added 3-aminophenol led to the formation of single-handed helical nanotubes instead. When the single-handed helical resin nanotubes were carbonized at 900℃ under Ar, single-handed helical carbonaceous nanotubes were obtained. Raman spectrum indicates that this carbon is predominantly amorphous. Circular dichroism spectra illustrate that both the helical resin nanotubes and the carbonaceous nanotubes exhibit optical activity. This work indicates that the added amount and the edge-adsorption mode of the precursors on the templates determine the final morphology and chirality of the products.

关键词: Chirality, Phenolic resin, Carbonaceous nanotube, Templating method

Abstract:

Key words: Chirality, Phenolic resin, Carbonaceous nanotube, Templating method

CAO Yanfang, LIU Dan, LI Baozong, LI Yi, YANG Yonggang. Preparation of Single-handed Helical and C-Shaped 3-Aminophenol-formaldehyde Resin Nanotubes and Single-handed Helical Carbonaceous Nanotubes[J]. 高等学校化学研究, 2016, 32(5): 862-866.

参考文献

[1] Wang H., Wei J., Nanoscale, 2015, 7(28), 11815
[2] Fernandes C., Stenning G., Taylor J., Nunes C., Vaz P., Adv. Synth. Catal., 2015, 357(14/15), 3127
[3] Chu G., Wang X., Chen T., Gao J., Gai F., Wang Y., Xu Y., ACS Appl. Mater. Interfaces, 2015, 7(22), 11863
[4] Wang H., Zhu W., Li J., Tian T., Lan Y., Gao N., Wang C., Zhang M.,. Faul C., Li G., Chem. Sci., 2015, 6(3), 1910
[5] Jung S., Jeon J., Kim H., Jaworski J., Jung J., J. Am. Chem. Soc., 2014, 136(17), 6446
[6] Han Y., Zhao L., Ying J., Adv. Mater., 2007, 19(18), 2454
[7] Jung J., Ono Y., Hanabusa K., Shinkai S., J. Am. Chem. Soc., 2000, 122(20), 5008
[8] Wu X., Ji S., Li Y., Li B., Zhu X., Hanabusa K., Yang Y., J. Am. Chem. Soc., 2009, 131(16), 5986
[9] Xiao M., Liu X., Hu K., Wu Li., Li Y., Li B., Yang Y., Chem. Res. Chinese Universities, 2012, 28(4), 637
[10] Cornelissen J., Fischer M., Sommerdijk N., Nolte R., Science, 1998, 280(5368), 1427
[11] Paik P., Gedanken A., Mastai Y., J. Mater. Chem., 2010, 20(1/2), 4085
[12] Fan C., Qiu H., Ruan J., Terasaki O., Yan Y., Wei Z., Che S., Adv. Funct. Mater., 2008, 18(18), 2699
[13] Yan Y., Yu Z., Huang Y., Yuan W., Wei Z., Adv. Mater., 2007, 19(20), 3353
[14] Chen H., Li Y., Tang X., Li B., Zhang C., Yang, Y., RSC Advances, 2015, 5(50), 39946
[15] Zhao J., Niu W., Zhang L., Cai H., Han M., Yuan Y., Majeed S., Anjum S., Xu G., Macromolecules, 2013, 46(1), 140
[16] Li W., Lee L.J., Polymer, 2000, 41(2), 685
[17] Liang C., Dai S., J. Am. Chem. Soc., 2006, 128(16), 5316
[18] Zhang X., Chu X., Wang L., Wang H., Liang G., Zhang J., Long J., Yang Z., Angew. Chem. Int. Ed., 2012, 124(18), 4464
[19] Das R., Zouani O., Labrugere C., Oda R., Durrieu M., ACS Nano, 2013, 7(4), 3351
[20] Shi J., Du X., Yuan D., Zhou J., Zhou N., Huang Y., Xu B., Bi-omacromolecules, 2014, 15(10), 3559
[21] Pappas C., Frederix P., Mutasa T., Fleming S., Abul-Haija Y., Kelly S., Gachagan A., Kalafatovic D., Trevino J., Ulijn R., Bai S., Chem. Commun., 2015, 51(40), 8465
[22] Marchesan S., Waddington L., Easton C., Winkler D., Goodall L., Forsythe J., Hartley P., Nanoscale, 2012, 4(21), 6752
[23] Liu S., Duan Y., Feng X., Yang J., Che S., Angew. Chem. Int. Ed., 2013, 52(27), 6858
[24] Shen Z., Wang T., Liu M., Chem. Commun., 2014, 50(17), 2096
[25] Cui H., Cheetham A., Pashuck E. T., Stupp S., J. Am. Chem. Soc., 2014, 136(35), 12461
[26] Fang Y., Lv Y., Gong F., Wu Z., Li X., Zhu H., Zhou L., Yao C., Zhang F., Zhao D., J. Am. Chem. Soc., 2015, 137(8), 2808
[27] Florent M., Xue C., Zhao D., Goldfarb D., Chem. Mater., 2012, 24(2), 383
[28] Zhuang X., Wan Y., Feng C., Shen Y., Zhao D., Chem. Mater., 2009, 21(4), 706
[29] Ma L., Chen H., Guo Y., Li B., Li Y., Chinese Chem. Lett., 2014, 25(10), 1363
[30] Chen X., Yang S., Motojima S., Ichihara M., Mater. Lett., 2005, 59(7), 854
[31] D'Urso A., Randazzo R., Lo Faro L., Purrello R., Angew. Chem. Int. Ed., 2010, 49(1), 108
[32] Wolffs M., George S., Tomovic Z., Merkers S., Schenning A., Meijier E., Angew. Chem. Int. Ed., 2007, 119(43), 8203
[33] Tsuda A., Alam M., Harada T., Yamaguchi T., Ishii N., Aida T., Angew. Chem. Int. Ed., 2007, 46(43), 8198
[34] Motojima S., Hoshiya S., Hishikawa Y., Carbon, 2003, 41(13), 2658
[35] Kong X., Wang Z., Nano Lett., 2003, 3(12), 1625
[36] Zhang X., Yin J., Yoon J., Chem. Rev., 2014, 114(9), 4918

Preparation of Single-handed Helical and C-Shaped 3-Aminophenol-formaldehyde Resin Nanotubes and Single-handed Helical Carbonaceous Nanotubes

Preparation of Single-handed Helical and C-Shaped 3-Aminophenol-formaldehyde Resin Nanotubes and Single-handed Helical Carbonaceous Nanotubes

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 7

编辑推荐

Metrics

本文评价

[1]	HOU Bang, LI Ziping, KANG Xing, JIANG Hong, CUI Yong. Recent Advances of Covalent Organic Frameworks for Chiral Separation[J]. 高等学校化学研究, 2022, 38(2): 350-355.
[2]	LIU Zhenyu, DONG Jinyi, PAN Jiahao, ZHOU Chao, FAN Chunhai, WANG Qiangbin. Catalytic DNA Origami-based Chiral Plasmonic Biosensor[J]. 高等学校化学研究, 2021, 37(4): 914-918.
[3]	ZHANG Lujun, ZHANG Pei, ZHANG Xiudong, SONG Jinliang, YANG Guanying, JIANG Long, HAN Buxing. Chirality Inversion of Assemblies of Bio-based Surfactant Triggered by Metal Ions[J]. 高等学校化学研究, 2018, 34(2): 155-157.
[4]	ZHANG Qing, LI Rui, ZHAI Yong-ai, LIU Feng-qi and GAO Ge*. Synthesis of Octylmethoxycinamate-silica Core-shell Nanoparticles with Self-templating Method[J]. 高等学校化学研究, 2010, 26(3): 339-343.
[5]	XU Wei, LU Yin-xiang, LIU Chun-ming, LAN Bi-jian, ZHOU Hui, WANG Jing-mei. Molecular Chirality and Chiral Superlattice in Crystal of Tetrakis[(pyrrol-1-yl)methyl]methane[J]. 高等学校化学研究, 2004, 20(6): 778-780.
[6]	WANG Zhong, SHI Zuo-qing, SHI Rong-fu, FAN Yun-ge, YAN Yi-Zhong. Studies on Thermodynamic Properties of Adsorption of Theophylline by Phenolic Resin Adsorbents[J]. 高等学校化学研究, 2004, 20(3): 373-376.
[7]	LU Shi-xiang, JIN Guo-xin, HU Ning-hai, JIA Heng-qing. Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η⁵-C₅H₃(t-Bu)₂]₂Fe₂(CO)₃Se₂C₂B₁₀H₁₀[J]. 高等学校化学研究, 2002, 18(4): 405-408.