Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules

doi:10.1007/s40242-016-6058-x

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (4): 527-529.doi: 10.1007/s40242-016-6058-x

Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules

GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai

School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China

收稿日期:2016-02-19 修回日期:2016-03-28 出版日期:2016-08-01 发布日期:2016-04-20
通讯作者: FU Hai E-mail:mr.fuhai@163.com
基金资助:
Supported by the National Natural Science Foundation of China(No.21301019), the Youth Foundation of Science and Technology Department of Jilin Province, China(No.20130522129JH), the National Science Foundation for Post-doctoral Scientists of China(No.2013M530135) and the Project of the Technology Department of Jilin Province, China(No.ZDZH2011003).

Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules

GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai

School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China

Received:2016-02-19 Revised:2016-03-28 Online:2016-08-01 Published:2016-04-20
Contact: FU Hai E-mail:mr.fuhai@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21301019), the Youth Foundation of Science and Technology Department of Jilin Province, China(No.20130522129JH), the National Science Foundation for Post-doctoral Scientists of China(No.2013M530135) and the Project of the Technology Department of Jilin Province, China(No.ZDZH2011003).

摘要/Abstract

摘要：

Two novel 3D supramolecular architectures with hexamolybdate and phosphotungstate anions were synthesized under ionothermal conditions. The structures were named as[Cu^I(L1)₂]₂L2[Mo₆O₁₉](1) and[Cu^I(L3)₂]_2.5· H_0.5[PW₁₂O₄₀]·H₂O(2)(L1=2,2'-bipyridine, L2=4,4'-bipyridine, L3=2,2'-biimidazole) and characterized via Fourier transform infrared spectroscopy(FTIR) and FT-Raman spectroscopy analyses. Single-crystal X-ray diffraction analysis revealed that the two compounds crystallized in the space group P and were constructed through hydrogen bonding.

关键词: Ionothermal, Polyoxometalate, Supramolecule

Abstract:

Key words: Ionothermal, Polyoxometalate, Supramolecule

GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai. Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules[J]. 高等学校化学研究, 2016, 32(4): 527-529.

GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai. Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules[J]. Chemical Research in Chinese Universities, 2016, 32(4): 527-529.

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Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules

Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules

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