[an error occurred while processing this directive]

高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (S1): 124-124.

• Articles • 上一篇    下一篇

Immobilization of Homogeneous Catalysis on Phosphinated MCM-41

SHYU Shin-Guang, CHENG Sheau-Wen, TZOU Der-Lii   

  1. Institute of Chemistry, Academia Sinica, Taipei, Taiwan
  • 出版日期:2001-12-31 发布日期:2016-03-14

Immobilization of Homogeneous Catalysis on Phosphinated MCM-41

SHYU Shin-Guang, CHENG Sheau-Wen, TZOU Der-Lii   

  1. Institute of Chemistry, Academia Sinica, Taipei, Taiwan
  • Online:2001-12-31 Published:2016-03-14

PDF (PC)

摘要：

Homogeneous catalysis Rh(PPh3)3Cl immobilized on MCM-41 modified with(OEt)3Si(CH2)3PPh2 results in a stable hydrogenation catalyst with turn over frequency(TOF) three times higher than that of RH(PPh3)3C1 in the hydrogenation of cyclohexene.

Abstract:

Homogeneous catalysis Rh(PPh3)3Cl immobilized on MCM-41 modified with(OEt)3Si(CH2)3PPh2 results in a stable hydrogenation catalyst with turn over frequency(TOF) three times higher than that of RH(PPh3)3C1 in the hydrogenation of cyclohexene.