高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (S1): 116-116.
Synthesis of Dioxa-cage Compounds as a New Probe for the Stereochemistry of the Bisadducts of p-Benzoquinone with 1,3-Cyclodienes
WU Hsien-Jen, TSAO Ching-Bo, TSAI Ting-Yueh
- Department of Applied Chemistry, Chiao Tung University, Hsinchu, Taiwan, China
Synthesis of Dioxa-cage Compounds as a New Probe for the Stereochemistry of the Bisadducts of p-Benzoquinone with 1,3-Cyclodienes
WU Hsien-Jen, TSAO Ching-Bo, TSAI Ting-Yueh
- Department of Applied Chemistry, Chiao Tung University, Hsinchu, Taiwan, China
摘要：
π-Facial stereoselectivety in Diels-alder reactions and their synthetic applications have attracted considerable attention in recent years.In the Diels-Alder reaction of the cyclopentadiene-quinone cycloadduct 1 with cycloalkadiene,four bisadducts with different stereochemistry could potentially result endo-anti-endo 2,endo-anii-exo 3,endo-syn-exo 4,and endosyn-etido 5.