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高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (S1): 11-11.

• Articles • 上一篇    下一篇

Synthetic Applications of Chiral Furanboronate

CHAN Kin-Fai, WONG Henry N. C.   

  1. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong
  • 出版日期:2001-12-31 发布日期:2016-03-14

Synthetic Applications of Chiral Furanboronate

CHAN Kin-Fai, WONG Henry N. C.   

  1. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong
  • Online:2001-12-31 Published:2016-03-14

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摘要：

We recently uncovered that consecutive reactions of chiral furfaral-boronate 1 with a lithium alkoxide and a nucleophile led to the formation of alcohols 2 with good diastereoselection in favor of S-configuration at the newly generated chiral carbon.

Abstract:

We recently uncovered that consecutive reactions of chiral furfaral-boronate 1 with a lithium alkoxide and a nucleophile led to the formation of alcohols 2 with good diastereoselection in favor of S-configuration at the newly generated chiral carbon.