Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

doi:10.1007/s40242-016-5331-3

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (2): 272-277.doi: 10.1007/s40242-016-5331-3

Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan

Department of Pharmaceutical and Biological Engineering, Hunan Chemical Vocational Technology College, Zhuzhou 412004, P. R. China

收稿日期:2015-08-17 修回日期:2015-11-18 出版日期:2016-04-01 发布日期:2015-12-14
通讯作者: LIU Jun E-mail:151283329@qq.com
基金资助:
Supported by the Programs Foundation of Scientific Research of Education Department of Hunan Province, China (Nos.14C0381, 15C0464).

Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan

Department of Pharmaceutical and Biological Engineering, Hunan Chemical Vocational Technology College, Zhuzhou 412004, P. R. China

Received:2015-08-17 Revised:2015-11-18 Online:2016-04-01 Published:2015-12-14
Contact: LIU Jun E-mail:151283329@qq.com
Supported by:
Supported by the Programs Foundation of Scientific Research of Education Department of Hunan Province, China (Nos.14C0381, 15C0464).

摘要/Abstract

摘要：

Agglomerated Pd catalysts with the nano-porous structure were simply prepared by one-step reduction reaction without using any stabilizer. The Pd catalysts show a high catalytic activity for the decomposition of formic acid at room temperature. Among all the Pd catalysts tested, the Pd_Mg catalyst exhibits the highest catalytic activity. Moreover, the breakthrough of the advanced catalysts is that the above agglomerated Pd catalysts can be easily separated from the liquid system to control the catalytic reaction at any time, which may further promote the practical application of formic acid as a H₂ storage material.

关键词: Hydrogen energy, Heterogeneous catalyst, Formic acid decomposition, Pd catalyst, Nano-porous structure

Abstract:

Key words: Hydrogen energy, Heterogeneous catalyst, Formic acid decomposition, Pd catalyst, Nano-porous structure

LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan. Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature[J]. 高等学校化学研究, 2016, 32(2): 272-277.

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Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

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