Design, Synthesis and Properties of Novel C60-Crown Dyads by 1,3-Dipolar Cycloaddition

doi:10.1007/s40242-014-3296-7

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (2): 242-244.doi: 10.1007/s40242-014-3296-7

Design, Synthesis and Properties of Novel C₆₀-Crown Dyads by 1,3-Dipolar Cycloaddition

DI Xingdong¹, YE Jinqi¹, YANG Fafu^1,2, GUO Hongyu¹, YAN Xiaoyun³

1. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, P. R. China;
2. Fujian Key Laboratory of Polymer Materials, Fuzhou 350007, P. R. China;
3. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China

收稿日期:2013-07-12 修回日期:2013-08-19 出版日期:2014-04-01 发布日期:2013-09-02
通讯作者: YANG Fafu E-mail:yangfafu@fjnu.edu.cn
基金资助:
Supported by the Program for Innovative Research Team in Science and Technology in Fujian Province University, China, the Fujian Natural Science Foundation of China(No.2011J01031), the Project of Fujian Provincial Department of Education, China(No.JA11044) and the Program for Excellent Young Researchers in University of Fujian Province, China(No.JA10056).

Design, Synthesis and Properties of Novel C₆₀-Crown Dyads by 1,3-Dipolar Cycloaddition

DI Xingdong¹, YE Jinqi¹, YANG Fafu^1,2, GUO Hongyu¹, YAN Xiaoyun³

1. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, P. R. China;
2. Fujian Key Laboratory of Polymer Materials, Fuzhou 350007, P. R. China;
3. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China

Received:2013-07-12 Revised:2013-08-19 Online:2014-04-01 Published:2013-09-02
Contact: YANG Fafu E-mail:yangfafu@fjnu.edu.cn
Supported by:
Supported by the Program for Innovative Research Team in Science and Technology in Fujian Province University, China, the Fujian Natural Science Foundation of China(No.2011J01031), the Project of Fujian Provincial Department of Education, China(No.JA11044) and the Program for Excellent Young Researchers in University of Fujian Province, China(No.JA10056).

摘要/Abstract

摘要：

Based on the 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine attached to C₆₀, two novel benzo-15-crown-5/C₆₀ dyads with a different linking chain in each were designed and synthesized in yields of 30% and 38%, respectively. It was found that their UV-Vis absorption spectra could be regulated hypsochromically by metal ions complexed. The long and soft linking chain was favorable for cooperate interaction of crown ether unit and C₆₀ unit.

关键词: C₆₀, Benzo-15-crown-5, 1,3-Dipolar cycloaddition, Complexation

Abstract:

Key words: C₆₀, Benzo-15-crown-5, 1,3-Dipolar cycloaddition, Complexation

DI Xingdong, YE Jinqi, YANG Fafu, GUO Hongyu, YAN Xiaoyun. Design, Synthesis and Properties of Novel C₆₀-Crown Dyads by 1,3-Dipolar Cycloaddition[J]. 高等学校化学研究, 2014, 30(2): 242-244.

DI Xingdong, YE Jinqi, YANG Fafu, GUO Hongyu, YAN Xiaoyun. Design, Synthesis and Properties of Novel C₆₀-Crown Dyads by 1,3-Dipolar Cycloaddition[J]. Chemical Research in Chinese Universities, 2014, 30(2): 242-244.

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Design, Synthesis and Properties of Novel C₆₀-Crown Dyads by 1,3-Dipolar Cycloaddition

Design, Synthesis and Properties of Novel C₆₀-Crown Dyads by 1,3-Dipolar Cycloaddition

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