Determination of Four Pesticides in Soil by Homogeneous Ionic Liquid-based Microextraction Coupled with High-performance Liquid Chromatography

doi:10.1007/s40242-013-2388-0

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (2): 218-222.doi: 10.1007/s40242-013-2388-0

Determination of Four Pesticides in Soil by Homogeneous Ionic Liquid-based Microextraction Coupled with High-performance Liquid Chromatography

YAN Rui¹, SHAO Ming-yuan¹, LIANG Zhen-fen², ZHANG Han-qi¹, YU Ai-min¹

1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Academy of Quality Inspection and Research in Heilongjiang Province, Harbin 150050, P. R. China

收稿日期:2012-10-11 修回日期:2012-11-10 出版日期:2013-04-01 发布日期:2013-03-20
通讯作者: YU Ai-min E-mail:analchem@mail.jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.51209024).

Determination of Four Pesticides in Soil by Homogeneous Ionic Liquid-based Microextraction Coupled with High-performance Liquid Chromatography

YAN Rui¹, SHAO Ming-yuan¹, LIANG Zhen-fen², ZHANG Han-qi¹, YU Ai-min¹

1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Academy of Quality Inspection and Research in Heilongjiang Province, Harbin 150050, P. R. China

Received:2012-10-11 Revised:2012-11-10 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the National Natural Science Foundation of China(No.51209024).

摘要/Abstract

摘要：

Homogeneous ionic liquid microextraction was developed for the simultaneceus extraction of dimethomorph, mefenacet, isoprothiolane and oxadiazon from soil. 1-Butyl-3-methylimidazolium tetrafluoroborate was used as extraction solvent, and ammonium hexafluorophosphate was used as ion-pairing agent. High-performance liquid chromatography(HPLC) was employed for separation and determination of the analytes. The calibration curves show good linear relationship(r>0.9988). The recoveries are between 74.2% and 97.9% with relative standard deviations(RSDs) lower than 5.97%. The present method is free of volatile organic solvents, and expenditures of sample, extraction time and solvent are lower, compared with ultrasonic and Soxhlet extraction. There was no obvious diffe- rence in the extraction recoveries of pesticides obtained by the three extraction methods.

关键词: Pesticide, Soil, Ionic liquid-based microextraction, High-performance liquid chromatography(HPLC)

Abstract:

Key words: Pesticide, Soil, Ionic liquid-based microextraction, High-performance liquid chromatography(HPLC)

YAN Rui, SHAO Ming-yuan, LIANG Zhen-fen, ZHANG Han-qi, YU Ai-min. Determination of Four Pesticides in Soil by Homogeneous Ionic Liquid-based Microextraction Coupled with High-performance Liquid Chromatography[J]. 高等学校化学研究, 2013, 29(2): 218-222.

参考文献

[1] Holland J., Sinclair P.; Eds. Hamilton D., Crossley S., Pesticides Residues in Food and Drinking Water, Human Exposure and Risks, John Wiley & Sons Ltd., Chichester, 2004, 27

[2] Paul R., Silve S., De Nys N., Dupuy P. H., Le-Bouteiller C. L., Rosenfeld J., Ferrara P., Lefur G., Casellas P., Loison G., J. Pharmacol. Exp. Ther., 1998, 285, 1296

[3] Okamura H., Omori M., Luo R., Aoyama I., Liu D., Science of the Total Environment, 1999, 234(1-3), 223

[4] Okamura H., Piao M. Y., Aoyama I., Sudo M.,Okubo T., Nakamura M., Environmental Pollution, 2002, 117(3), 411

[5] Tomlin C., The Pesticide Manual: A World Compendium, 11th Ed., British Crop Protection Council, Farnham, 1997

[6] Huang B. Y., Pan C. P., Wang Y. R., Cao Z., Zhang W., Li W. M., Jiang S. R., Chem. J. Chinese Universities, 2006, 27(2), 227

[7] Wu X. P., Wang L., Xie Z. H., Yan C., Chen G. N., Chem. Res. Chinese Universities, 2007, 23(1), 109

[8] Tanabe A., Mitobe H., Kawata K., Sakai M.,J. Chromatogr. A,1996, 754(1/2), 159

[9] Riley M. B., Keese R. J., Weed Sci., 1996, 44, 689

[10] Ying G. G., Williams B., Environ J., Sci. Health B: Pest. Food Contam. Agric. Wastes, 1999, 34(3), 397

[11] Mateus N. M. M., Branco L. C., Lourenco N. M. T., Afonso C. A. M., Green Chem., 2003, 5, 347

[12] Yang H. Z., Gu Y. L., Deng Y. Q., ShiF., Chem. Commun., 2002, (3), 274

[13] Murty M. S. R., Rajasekhar K., Harikrishna V., YadavJ. S., Heteroat. Chem.,2008, 19, 104

[14] Bica K., Gaertner P., Org. Lett.,2006, 8(4), 733

[15] Deng F. Z., Guo D. F., Chinese J. Analytical Chemistry, 2006, 34(10), 1451

[16] Qi D., Cui S. Y., Chen X. G.., HuZ. D., J. Chromatogr. A, 2004, 1059(1/2), 191

[17] Belding S. R., Rees N. V., Aldous L., Hardacre C., Compton R. G., J. Phys. Chem. C, 2008, 112, 1650

[18] Huddleston J. G., Rogers R. D., Chem. Commun., 1998, (16), 1765

[19] Wang J. H., Cheng D. H., Chen X. W., Du Z., Fang Z. L.,Anal. Chem., 2007, 79(2), 620

[20] Liu J. F., Jiang G. B., Chi Y. G., Cai Y. Q., Hu J. T., Zhou Q. X., Anal. Chem., 2003, 75(21), 5870

[21] Liu J., Li N., Jiang G., Liu J., Jonsson J. A., Wen M. J., J. Chromatogr. A, 2005, 1066(1/2), 27

[22] Du Z., Yu Y. L., Wang J. H., Chem. Eng. J., 2007, 13(7), 2130

[23] He C. Y., Li S. H., Liu H. W., Li K. A., Liu F., J. Chromatogr. A, 2005, 1082(2), 143

[24] Chen Y., Guo Z. P., Wang X. Y., J. Chromatogr. A, 2008, 1184(1/2), 191

[25] Guo Z. K., Jin Q. H., Fan G.. Q., Duan Y. P., Qin C., Wen M. J., Anal. Chim. Acta, 2001, 436(1), 41

Determination of Four Pesticides in Soil by Homogeneous Ionic Liquid-based Microextraction Coupled with High-performance Liquid Chromatography

Determination of Four Pesticides in Soil by Homogeneous Ionic Liquid-based Microextraction Coupled with High-performance Liquid Chromatography

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