Thermal and Optoelectronic Properties of Anthracene and Dibenz[a,c]Anthracene

doi:10.1007/s40242-013-2264-y

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (1): 110-115.doi: 10.1007/s40242-013-2264-y

Thermal and Optoelectronic Properties of Anthracene and Dibenz[a,c]Anthracene

MUDDASIR Hanif¹, WANG Zhi-ming², YANG Bing¹, LU Ping¹, MA Yu-guang¹

1. State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P. R. China;
2. School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, P. R. China

收稿日期:2012-07-06 修回日期:2012-08-29 出版日期:2013-02-01 发布日期:2013-01-23
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21107050, 51203091).

Thermal and Optoelectronic Properties of Anthracene andDibenz[a,c]Anthracene

MUDDASIR Hanif¹, WANG Zhi-ming², YANG Bing¹, LU Ping¹, MA Yu-guang¹

1. State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P. R. China;
2. School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, P. R. China

Received:2012-07-06 Revised:2012-08-29 Online:2013-02-01 Published:2013-01-23
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21107050, 51203091).

摘要/Abstract

摘要：

The basic characteristics of anthracene(AN) and dibenz[a,c]anthracene(D[a,c]A) derivatives, important semiconductors, were systematically studied. Differential scanning calorimetry(DSC) shows that D[a,c]A has the reversibility of solid and liquid phases. Thermalgravimetric analysis(TGA) shows that D[a,c]A exhibits higher T_d(decomposition temperature), which indicates D[a,c]A, as active layers, should be more suitable to being made into stable devices. D[a,c]A shows blue-shifted UV-Vis absorption and emission despite increased conjugation compared to anthracene due to different symmetries. Both the compounds are planar and show weak blue fluorescence in the tetrahydrofuran(THF) solution and higher fluorescence in the solid-state, due to different energy levels in solution and solid-state, explained via Jablonski diagram.

关键词: Anthracene, Dibenz[a,c]anthracene, Molecular property, Thermal, Electrochemistry

Abstract:

Key words: Anthracene, Dibenz[a,c]anthracene, Molecular property, Thermal, Electrochemistry

MUDDASIR Hanif, WANG Zhi-ming, YANG Bing, LU Ping, MA Yu-guang. Thermal and Optoelectronic Properties of Anthracene and Dibenz[a,c]Anthracene[J]. 高等学校化学研究, 2013, 29(1): 110-115.

MUDDASIR Hanif, WANG Zhi-ming, YANG Bing, LU Ping, MA Yu-guang. Thermal and Optoelectronic Properties of Anthracene andDibenz[a,c]Anthracene[J]. Chemical Research in Chinese Universities, 2013, 29(1): 110-115.

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Thermal and Optoelectronic Properties of Anthracene and Dibenz[a,c]Anthracene

Thermal and Optoelectronic Properties of Anthracene andDibenz[a,c]Anthracene

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