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高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (6): 1112-1118.

• Articles • 上一篇    

Separation of Salbutamol by Nano-baskets of Calix[4]arene Bearing Sulfonyl-carboxamides in Partial-cone Conformation

MOKHTARI Bahram, POURABDOLLAH Kobra   

  1. Razi Chemistry Research Center(RCRC), Shahreza Branch, Islamic Azad University, Shahreza, Iran
  • 收稿日期:2011-11-09 修回日期:2012-01-11 出版日期:2012-11-25 发布日期:2012-11-09
  • 通讯作者: POURABDOLLAH Kobra E-mail:pourabdollah@iaush.ac.ir
  • 基金资助:

    Supported by the Project of Islamic Azad University(Shahreza Branch) and the Iran Nanotechnology Initiative Council.

Separation of Salbutamol by Nano-baskets of Calix[4]arene Bearing Sulfonyl-carboxamides in Partial-cone Conformation

MOKHTARI Bahram, POURABDOLLAH Kobra   

  1. Razi Chemistry Research Center(RCRC), Shahreza Branch, Islamic Azad University, Shahreza, Iran
  • Received:2011-11-09 Revised:2012-01-11 Online:2012-11-25 Published:2012-11-09
  • Contact: POURABDOLLAH Kobra E-mail:pourabdollah@iaush.ac.ir
  • Supported by:

    Supported by the Project of Islamic Azad University(Shahreza Branch) and the Iran Nanotechnology Initiative Council.

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被引次数

3

摘要：

Salbutamol, which increases the muscle mass and decreases the adipose tissue, is misused as nutrient repartitioning agent in the livestock. The novelty of this work is the determination of salbutamol in the livestock meat via new bonded-phases bearing eight derivatives of p-tert-calix[4]arene in partial-cone conformation. The new synthesized bonded-phases were characterized and optimized. The bonding interactions of solute and stationary-phases were examined and the main interactions were reported. The salbutamol levels in six samples of livestock meat were analyzed and the results reveal that for the best bonded-phases, the limit of detection(LOD) and limit of quantitation (LOQ) were 0.02 and 0.06 μg/mL, respectively.

关键词: Nano-basket, Bonded-phase, Partial-cone conformation, Calix[4]arene, Salbutamol

Abstract:

Salbutamol, which increases the muscle mass and decreases the adipose tissue, is misused as nutrient repartitioning agent in the livestock. The novelty of this work is the determination of salbutamol in the livestock meat via new bonded-phases bearing eight derivatives of p-tert-calix[4]arene in partial-cone conformation. The new synthesized bonded-phases were characterized and optimized. The bonding interactions of solute and stationary-phases were examined and the main interactions were reported. The salbutamol levels in six samples of livestock meat were analyzed and the results reveal that for the best bonded-phases, the limit of detection(LOD) and limit of quantitation (LOQ) were 0.02 and 0.06 μg/mL, respectively.

Key words: Nano-basket, Bonded-phase, Partial-cone conformation, Calix[4]arene, Salbutamol