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高等学校化学研究 ›› 1997, Vol. 13 ›› Issue (1): 70-76.

• Articles • 上一篇    下一篇

Electron Ionization Mass Spectrometry of Some Ferrocenyl Thia-crown Ethers

SU Jing-zhe1, JU Ying1, WANG Tsong-Hui2, LUO Zhao-fu3, HU ANG Zai-fu4   

  1. 1. Beijing Institute of Chemical Reagents, Beijing 100022;
    2. Instituteof Forensic Science, Beijing 100038;
    3. Editorial Departmentof Wuhan University Journal, Wuhan University, Wuhan 430072;
    4. Departmentof Environmental Science, Wuhan University, Wuhan 430072
  • 收稿日期:1996-05-08 出版日期:1997-01-24 发布日期:2011-08-17

Electron Ionization Mass Spectrometry of Some Ferrocenyl Thia-crown Ethers

SU Jing-zhe1, JU Ying1, WANG Tsong-Hui2, LUO Zhao-fu3, HU ANG Zai-fu4   

  1. 1. Beijing Institute of Chemical Reagents, Beijing 100022;
    2. Instituteof Forensic Science, Beijing 100038;
    3. Editorial Departmentof Wuhan University Journal, Wuhan University, Wuhan 430072;
    4. Departmentof Environmental Science, Wuhan University, Wuhan 430072
  • Received:1996-05-08 Online:1997-01-24 Published:2011-08-17

PDF (PC)

摘要： A new type of ferrocenyl thia crown ethers used as selective ligands to some poisonous metals was synthesized, and the features of their mass spectra in electron ionization mode were summarized as: (1) the strong molecular ion peaks; (2) a characteristic homologous ion series with sequential loss of C2H4S or C2H4O from M C5H5; (3) a new rearrangement reaction of Fe migration; (4) the uncommon loss of alcohol or thiol from the fragments of Fe rearrangement. Some typical fragmentation patterns were discussed in detail with the aid of exact mass measurement and MS/MS technique.

关键词: Ferrocenyl thia crown ether, Poisonous metal, Electron ionization mode

Abstract: A new type of ferrocenyl thia crown ethers used as selective ligands to some poisonous metals was synthesized, and the features of their mass spectra in electron ionization mode were summarized as: (1) the strong molecular ion peaks; (2) a characteristic homologous ion series with sequential loss of C2H4S or C2H4O from M C5H5; (3) a new rearrangement reaction of Fe migration; (4) the uncommon loss of alcohol or thiol from the fragments of Fe rearrangement. Some typical fragmentation patterns were discussed in detail with the aid of exact mass measurement and MS/MS technique.

Key words: Ferrocenyl thia crown ether, Poisonous metal, Electron ionization mode