Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide

高等学校化学研究 ›› 1998, Vol. 14 ›› Issue (2): 138-142.

Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide

LI Ye-zhi, GUO Chun-xiao, ZHANG Li, HUANG Hua-min

Department of Chemistry, National Key Laboratory of Computational Theoretical Chemistry, Jilin University, Changchun 130023

收稿日期:1997-09-23 出版日期:1998-04-24 发布日期:2011-08-17
基金资助:
Supported by the National Natural Science Foundation of China.

Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide

LI Ye-zhi, GUO Chun-xiao, ZHANG Li, HUANG Hua-min

Department of Chemistry, National Key Laboratory of Computational Theoretical Chemistry, Jilin University, Changchun 130023

Received:1997-09-23 Online:1998-04-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China.

摘要/Abstract

摘要： (R)-N-(β-Trichlorogermyl propionyl)thiazolidine-2-thione-4-carboxylic methyl ether(1) and its sesquioxide(2) were synthesized. The crystal structure of 1 was determined by means of X-ray diffraction analysis, which shown that the >C=O and >C=S groups are located in the opposite sides of C(4)—N—C(3) bond with trans configuration. The electronic structures and optimized configurations of compounds 1 and 2 were studied with MNDO method.

关键词: ?-N-(&beta, -Trichlorogermyl propionyl)thiazolidine-2-thione-4-carboxylic methyl ether, (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium sesquioxide, MNDO, Electronic structure, Optimized configuration

Abstract: (R)-N-(β-Trichlorogermyl propionyl)thiazolidine-2-thione-4-carboxylic methyl ether(1) and its sesquioxide(2) were synthesized. The crystal structure of 1 was determined by means of X-ray diffraction analysis, which shown that the >C=O and >C=S groups are located in the opposite sides of C(4)—N—C(3) bond with trans configuration. The electronic structures and optimized configurations of compounds 1 and 2 were studied with MNDO method.

Key words: ?-N-(β-Trichlorogermyl propionyl)thiazolidine-2-thione-4-carboxylic methyl ether, (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium sesquioxide, MNDO, Electronic structure, Optimized configuration

LI Ye-zhi, GUO Chun-xiao, ZHANG Li, HUANG Hua-min . Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide[J]. 高等学校化学研究, 1998, 14(2): 138-142.

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Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide

Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide

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