Crystal and Molecular Structure of an Inclusion Complex of p-tert-Butylcalix[6] arene with Toluene

高等学校化学研究 ›› 1999, Vol. 15 ›› Issue (1): 1-4.

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Crystal and Molecular Structure of an Inclusion Complex of p-tert-Butylcalix[6] arene with Toluene

LU Tong-bu¹, LI Xiao-yan¹, JI Liang-nian¹, HAN Bao-hang², LIU-Yu², YU Kai-bei³

1. Department of Chemistry and Center of Measurement, Zhongshan University, Guangzhou, 510275;
2. Department of Chemistry, Nankai University, Tianjin, 300071;
3. Chengdu Centerof Analysis and Measurement, Academia Sinica, Chengdu, 610041

收稿日期:1998-03-02 出版日期:1999-01-24 发布日期:2011-08-17
通讯作者: JI Liang-nian
基金资助:
Supported by the Guangdong Provincial Natural Science Foundation.

Crystal and Molecular Structure of an Inclusion Complex of p-tert-Butylcalix[6] arene with Toluene

LU Tong-bu¹, LI Xiao-yan¹, JI Liang-nian¹, HAN Bao-hang², LIU-Yu², YU Kai-bei³

1. Department of Chemistry and Center of Measurement, Zhongshan University, Guangzhou, 510275;
2. Department of Chemistry, Nankai University, Tianjin, 300071;
3. Chengdu Centerof Analysis and Measurement, Academia Sinica, Chengdu, 610041

Received:1998-03-02 Online:1999-01-24 Published:2011-08-17
Supported by:
Supported by the Guangdong Provincial Natural Science Foundation.

摘要/Abstract

摘要： An inclusion complex between p-tert-butylcalix[6] arene and toluene was prepared. It crystallized in the monoclinic system with space group P2₁/ n, a =1.734 7(2) nm, b =1.903 2(2) nm, c =1.972 9(2) nm, β =94.74(1)°, V =6.491 2(14) nm³, Z =4. The toluene molecule was included in the macrocycle cavity. The calixanene is of a pinched cone conformation.

关键词: p-tert-Butylcalix[6]arene, Toluene, Inclusion complex

Abstract: An inclusion complex between p-tert-butylcalix[6] arene and toluene was prepared. It crystallized in the monoclinic system with space group P2₁/ n, a =1.734 7(2) nm, b =1.903 2(2) nm, c =1.972 9(2) nm, β =94.74(1)°, V =6.491 2(14) nm³, Z =4. The toluene molecule was included in the macrocycle cavity. The calixanene is of a pinched cone conformation.

Key words: p-tert-Butylcalix[6]arene, Toluene, Inclusion complex

LU Tong-bu, LI Xiao-yan, JI Liang-nian, HAN Bao-hang, LIU-Yu, YU Kai-bei . Crystal and Molecular Structure of an Inclusion Complex of p-tert-Butylcalix[6] arene with Toluene[J]. 高等学校化学研究, 1999, 15(1): 1-4.

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Crystal and Molecular Structure of an Inclusion Complex of p-tert-Butylcalix[6] arene with Toluene

Crystal and Molecular Structure of an Inclusion Complex of p-tert-Butylcalix[6] arene with Toluene

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