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高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (4): 484-487.

• Articles • 上一篇    下一篇

Photoelectrochemical Character of TiO2 Nanocrystalline Electrodes Sensitized by Aluminum Phthalocyanines Modified with Sulfonate Groups

PAN Kai1, LIU Zhao-yue1, WANG Geng2, BAI Yu-bai1, LI Tie-jin1   

  1. 1. College of Chemistry, Jilin University, Changchun 130021, P. R. China;
    2. Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
  • 收稿日期:2005-07-04 出版日期:2006-08-24 发布日期:2011-08-06
  • 基金资助:

    Supported by the National Natural Science Foundation of China(Nos. 60271020 and 20125513).

Photoelectrochemical Character of TiO2 Nanocrystalline Electrodes Sensitized by Aluminum Phthalocyanines Modified with Sulfonate Groups

PAN Kai1, LIU Zhao-yue1, WANG Geng2, BAI Yu-bai1, LI Tie-jin1   

  1. 1. College of Chemistry, Jilin University, Changchun 130021, P. R. China;
    2. Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
  • Received:2005-07-04 Online:2006-08-24 Published:2011-08-06
  • Supported by:

    Supported by the National Natural Science Foundation of China(Nos. 60271020 and 20125513).

PDF (PC)

摘要： Particular kinds of TiO2 nanocrystalline electrodes were sensitized by aluminum phthalocyanines modified with sulfonate groups [Al(OH)PcSn]. It was found that in the red region, the electrodes show obvious photoelectrical responses. The surface photovoltage spectra and photocurrent action spectra indicate that in the red region, the monomers of aluminum phthalocyanines have a greater influence on the determination of the photoelectrical response of TiO2 electrodes than the dimers. The dye-sensitized solar cells were obtained by using the aluminum phthalocyanines-sensitized TiO2 electrodes and Pt electrodes, which have an open circuit photovoltage of 360 mV, a short circuit photocurrent of 39.4 μA/cm2, a fill factor of 0.54 and a maximum power output of 7.65 μW/cm2 under a light intensity of 50 mW/cm2.

关键词: Aluminum phthalocyanines [Al(OH)PcSn], TiO2 nanocrystalline electrode, Photoelectrochemical character

Abstract: Particular kinds of TiO2 nanocrystalline electrodes were sensitized by aluminum phthalocyanines modified with sulfonate groups [Al(OH)PcSn]. It was found that in the red region, the electrodes show obvious photoelectrical responses. The surface photovoltage spectra and photocurrent action spectra indicate that in the red region, the monomers of aluminum phthalocyanines have a greater influence on the determination of the photoelectrical response of TiO2 electrodes than the dimers. The dye-sensitized solar cells were obtained by using the aluminum phthalocyanines-sensitized TiO2 electrodes and Pt electrodes, which have an open circuit photovoltage of 360 mV, a short circuit photocurrent of 39.4 μA/cm2, a fill factor of 0.54 and a maximum power output of 7.65 μW/cm2 under a light intensity of 50 mW/cm2.

Key words: Aluminum phthalocyanines [Al(OH)PcSn], TiO2 nanocrystalline electrode, Photoelectrochemical character