Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding

高等学校化学研究 ›› 2003, Vol. 19 ›› Issue (2): 216-218.

Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding

GAO Zhong-min¹, JIN Hong-zheng², LI Xiang-shan², HUA Zhong²

1. State Key Laboratory of Inorgnic Synthesis & Preparative Chemistry;
2. Department of Material Science, Jilin University, Changchun 130023, P. R. China

收稿日期:2002-05-08 出版日期:2003-04-24 发布日期:2011-08-06

Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding

GAO Zhong-min¹, JIN Hong-zheng², LI Xiang-shan², HUA Zhong²

1. State Key Laboratory of Inorgnic Synthesis & Preparative Chemistry;
2. Department of Material Science, Jilin University, Changchun 130023, P. R. China

Received:2002-05-08 Online:2003-04-24 Published:2011-08-06

摘要/Abstract

摘要： The transformation from graphite to turbostratic graphite by means of the treatment with high-energy ball milling was investigated by X-ray powder diffraction method. It is believed that the size effect of nano-crystal leads to this transformation. A possible transformation mechanism is proposed from the change of the eletronic structure of the hexagonal plane of the carbon atoms.

关键词: G-T(Graphite-Turbostratic graphite) phase transition, Nanocrystalline, Size effect, Electronic structure, Mechanical grinding

Abstract: The transformation from graphite to turbostratic graphite by means of the treatment with high-energy ball milling was investigated by X-ray powder diffraction method. It is believed that the size effect of nano-crystal leads to this transformation. A possible transformation mechanism is proposed from the change of the eletronic structure of the hexagonal plane of the carbon atoms.

Key words: G-T(Graphite-Turbostratic graphite) phase transition, Nanocrystalline, Size effect, Electronic structure, Mechanical grinding

GAO Zhong-min, JIN Hong-zheng, LI Xiang-shan, HUA Zhong. Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding[J]. 高等学校化学研究, 2003, 19(2): 216-218.

GAO Zhong-min, JIN Hong-zheng, LI Xiang-shan, HUA Zhong. Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding[J]. Chemical Research in Chinese Universities, 2003, 19(2): 216-218.

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Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding

Phase Transformation Mechanism of Graphite-Turbostratic Graphite in the Course of Mechanical Grinding

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