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高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (4): 414-418.

• Articles • 上一篇    下一篇

A New Approach to Inducing Silicon Tethered Ring-closing Metathesis Reactions

YANG Hong-li, VAULTIER Michel   

  1. Synthèse et Electrosynthèse Organiques, UMR CNRS 6510, Université de Rennes 1, Campus de Beaulieu, Avenue du Général Leclerc, 35042 RENNES CEDEX, France
  • 收稿日期:2001-08-13 出版日期:2002-12-24 发布日期:2011-08-04

A New Approach to Inducing Silicon Tethered Ring-closing Metathesis Reactions

YANG Hong-li, VAULTIER Michel   

  1. Synthèse et Electrosynthèse Organiques, UMR CNRS 6510, Université de Rennes 1, Campus de Beaulieu, Avenue du Général Leclerc, 35042 RENNES CEDEX, France
  • Received:2001-08-13 Online:2002-12-24 Published:2011-08-04

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摘要： Ring-closing metathesis reactions involving diallyldiphenylsilane and diallyloxydiphenylsilane were successfully performed by using only 0.01 mol or even less of Grubbs' catalyst 1. The effects of reaction parameters, such as solvents, temperature and concentration of the catalyst are discussed.

关键词: Ring-closing metathesis reaction, Grubbs' catalyst, Diallyldiphenylsilane, Diallyloxydiphenyl-silane

Abstract: Ring-closing metathesis reactions involving diallyldiphenylsilane and diallyloxydiphenylsilane were successfully performed by using only 0.01 mol or even less of Grubbs' catalyst 1. The effects of reaction parameters, such as solvents, temperature and concentration of the catalyst are discussed.

Key words: Ring-closing metathesis reaction, Grubbs' catalyst, Diallyldiphenylsilane, Diallyloxydiphenyl-silane