高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (2): 161-168.
Recent Advance in the Electrochemical Detection of Sulphide and Sulphhydryl Species
Nathan S. Lawrence1, Timothy G. J. Jones2, Richard G. Compton1, Li Jiang2
- 1. Physical and Theoretical Chemistry Laboratory, University of Oxford, Oxford, OX1 3QZ, UK;
2. Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB30EL, UK
Recent Advance in the Electrochemical Detection of Sulphide and Sulphhydryl Species
Nathan S. Lawrence1, Timothy G. J. Jones2, Richard G. Compton1, Li Jiang2
- 1. Physical and Theoretical Chemistry Laboratory, University of Oxford, Oxford, OX1 3QZ, UK;
2. Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB30EL, UK
摘要： This article aims at providing a critical review of some most recent developments in the electrochemical detection and measurement of hydrogen sulphide and the related species, which are of great significance to a variety of industries and in environmental moitoring. The molecular recognition processes are initiated by using either an organic precursor or a catalytic complex, leading to extensive ranges of detection. A series of advanced chemical and simulation techniques are used to probe the mechanistic details of the analytical chemistry involved.