[Ce(H2 O)7 Al(OH)6 Mo6O18]·4H2 O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

高等学校化学研究 ›› 2005, Vol. 21 ›› Issue (6): 637-640.

• Articles • 下一篇

[Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

JIN Hua, QI Yan-fei, QIN Chao, WANG Xin-long, WANG En-bo, XU Lin

Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

收稿日期:2005-02-01 出版日期:2005-11-23 发布日期:2011-08-06
基金资助:
Supported by the National Natural Science Foundation of China(No.20371011)

[Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

JIN Hua, QI Yan-fei, QIN Chao, WANG Xin-long, WANG En-bo, XU Lin

Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

Received:2005-02-01 Online:2005-11-23 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20371011)

摘要/Abstract

摘要： A new cerium polyoxomolybdate {[Ce(H₂O)₇Al(OH)₆Mo₆O₁₈]·4H₂O} (compound 1) was synthesized and characterized by X-ray diffraction analysis, elemental analysis, TG analysis and IR spectrometry.Compound 1 exhibits a zigzag chain-like structure, which is constructed from an Anderson type anion and rare earth metal, Ce (Ⅲ).These 1-D chains are further extended into a 3-D network by the aid of multipoint hydrogen-bonding interactions.

关键词: One-pot reaction, Zigzag chain-like polymer, Rare earth metal, Polyoxometalate

Abstract: A new cerium polyoxomolybdate {[Ce(H₂O)₇Al(OH)₆Mo₆O₁₈]·4H₂O} (compound 1) was synthesized and characterized by X-ray diffraction analysis, elemental analysis, TG analysis and IR spectrometry.Compound 1 exhibits a zigzag chain-like structure, which is constructed from an Anderson type anion and rare earth metal, Ce (Ⅲ).These 1-D chains are further extended into a 3-D network by the aid of multipoint hydrogen-bonding interactions.

Key words: One-pot reaction, Zigzag chain-like polymer, Rare earth metal, Polyoxometalate

JIN Hua, QI Yan-fei, QIN Chao, WANG Xin-long, WANG En-bo, XU Lin. [Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions[J]. 高等学校化学研究, 2005, 21(6): 637-640.

[1]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1128-1135.
[2]	DONG Pengfei, LI Na, ZHAO Haiyan, CUI Min, ZHANG Cong, HAN Hongyan, REN Jujie. POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen[J]. 高等学校化学研究, 2019, 35(4): 592-597.
[3]	WANG Shuo, GAO Yu, SU Xiaofang, YAN Likai. Exploration on Charge Transfer and Absorption Spectra of Spiro[fluorene-9,90-xanthene]-based Polyoxometalate Hybrids Toward High Performance Dye-sensitized Solar Cell[J]. 高等学校化学研究, 2018, 34(5): 767-771.
[4]	SONG Jiangfeng, WANG Jun, ZHOU Ruisha, CUI Xiaobing. A New Inorganic 2D Framework Based on Bi-bismuth-capping Keggin Polyoxometalate with Photodegradation and Selective Absorption of Organic Dyes[J]. 高等学校化学研究, 2017, 33(3): 333-338.
[5]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework[J]. 高等学校化学研究, 2017, 33(1): 7-11.
[6]	GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai. Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules[J]. 高等学校化学研究, 2016, 32(4): 527-529.
[7]	WANG Yue, HOU Dalong, LÜ Haoze, ZHANG Baozhen, WANG Ensi. Efficient Synthesis of Beraprost Sodium[J]. 高等学校化学研究, 2016, 32(4): 581-585.
[8]	MEN Yican, ZHANG Jiqian, ZHOU Lishan, LI Junqiu, LIU Jun, LI Juan, QU Hongmei. Zirconium-mediated Selective Synthesis of Quinoline Derivatives[J]. 高等学校化学研究, 2016, 32(4): 621-624.
[9]	WANG Xiuli, LIU Danna, HAN Na, LIN Hongyan, LUAN Jian, TIAN Aixiang. Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits[J]. 高等学校化学研究, 2015, 31(3): 337-341.
[10]	DUAN Weijie, JIAO Shihui, LIU Xu, CHEN Jinlei, CAO Xuan, CHEN Yan, XU Wei, CUI Xiaobing, XU Jiqing, PANG Guangsheng. Two New Supramolecular Hybrids Based on Bi-capped Keggin {PMo₁₂V₂O₄₂} Clusters and Transition Metal Mixed-organic-ligand Complexes[J]. 高等学校化学研究, 2015, 31(2): 179-186.
[11]	LÜ Chengwei, LIU Yanhang, ZHOU Xiaoxia, WANG Jiajing. One-pot Three-component Reaction for Efficient and Facile Synthesis of γ-Nitrocarbonyl Compounds Under Solvent-free Conditions[J]. 高等学校化学研究, 2015, 31(2): 208-211.
[12]	LIU Yabing, DUAN Weijie, CUI Xiaobing, XU Jiqing. Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters[J]. 高等学校化学研究, 2015, 31(1): 4-8.
[13]	ZHOU Yunshan, QU Ningning, WANG Xuan, ZHANG Lijuan, SHI Zonghai, HASSAN ul Sadaf. Third-order Optical Nonlinearities of a Series of Compounds Derived from a Keplerate Type Molybdenum-oxide-based Polyoxometalate[J]. 高等学校化学研究, 2014, 30(5): 715-719.
[14]	KONG Da-liang, WEI Bo, ZHOU Sheng-yan, YANG Hai-shan, JIANG Yang. Volume-related Efficiency of Gadolinium Polyoxometalates as MRI Contrast Agents[J]. 高等学校化学研究, 2013, 29(6): 1055-1058.
[15]	LIU Zhen-ming, WU Lei, SUN Jing, YAN Chao-guo. Efficient One-pot Synthesis of Pyrrolo[2,1-a]isoquinoline and Pyrrolo[1,2-a]quinoline Derivatives[J]. 高等学校化学研究, 2012, 28(6): 990-993.

[Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

[Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价