Electrical Conductivity of Alkaline-reduced Graphene Oxide

高等学校化学研究 ›› 2011, Vol. 27 ›› Issue (5): 857-861.

Electrical Conductivity of Alkaline-reduced Graphene Oxide

WANG Huan¹, TIAN Hong-wei¹, WANG Xin-wei¹, QIAO Liang¹, WANG Shu-min¹, WANG Xing-li¹, ZHENG Wei-tao^1* and LIU Yi-chun²

1. Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science, Jilin University, Changchun 130012, P. R. China;
2. Key Laboratory for UV-Emitting Materials and Technology, Ministry of Education, Center for Advanced Optoelectronic Functional Materials Research, Northeast Normal University, Changchun 130024, P. R. China

收稿日期:2011-04-06 修回日期:2011-05-01 出版日期:2011-09-25 发布日期:2011-09-06
通讯作者: ZHENG Wei-tao E-mail:wtzheng@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.50525204, 50832001), the Special PhD Program of Ministry of Education, China(No.200801830025), the Program for Changjiang Scholars and Innovative Research Team in University of China and the “211” and “985” Project of Jilin University, China.

Electrical Conductivity of Alkaline-reduced Graphene Oxide

WANG Huan¹, TIAN Hong-wei¹, WANG Xin-wei¹, QIAO Liang¹, WANG Shu-min¹, WANG Xing-li¹, ZHENG Wei-tao^1* and LIU Yi-chun²

1. Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science, Jilin University, Changchun 130012, P. R. China;
2. Key Laboratory for UV-Emitting Materials and Technology, Ministry of Education, Center for Advanced Optoelectronic Functional Materials Research, Northeast Normal University, Changchun 130024, P. R. China

Received:2011-04-06 Revised:2011-05-01 Online:2011-09-25 Published:2011-09-06
Contact: ZHENG Wei-tao E-mail:wtzheng@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.50525204, 50832001), the Special PhD Program of Ministry of Education, China(No.200801830025), the Program for Changjiang Scholars and Innovative Research Team in University of China and the “211” and “985” Project of Jilin University, China.

摘要/Abstract

摘要： A green route using a very simple and straightforward ultrasonic process under alkaline conditions, rather than a general chemical reduction process using hydrazine, was utilized to obtain the hydrophilic reduced graphene oxide(RGO) sheets, via removing oxygen functional groups from graphene oxide(GO) and repairing the aromatic structure. It is found that the conductivity of the obtained RGO could be tuned by changing pH value in alkaline solution, and the current-voltage(I-V) curves of both GO and RGO are nonlinear and slightly asymmetric. Under the same applied voltage, the current of RGO is much larger than that of GO, indicating a pronounced increase in the electrical conductivity of RGO, compared to that of GO.

关键词: Graphene, Reduction, Conductivity

Abstract: A green route using a very simple and straightforward ultrasonic process under alkaline conditions, rather than a general chemical reduction process using hydrazine, was utilized to obtain the hydrophilic reduced graphene oxide(RGO) sheets, via removing oxygen functional groups from graphene oxide(GO) and repairing the aromatic structure. It is found that the conductivity of the obtained RGO could be tuned by changing pH value in alkaline solution, and the current-voltage(I-V) curves of both GO and RGO are nonlinear and slightly asymmetric. Under the same applied voltage, the current of RGO is much larger than that of GO, indicating a pronounced increase in the electrical conductivity of RGO, compared to that of GO.

Key words: Graphene, Reduction, Conductivity

WANG Huan, TIAN Hong-wei, WANG Xin-wei, QIAO Liang, WANG Shu-min, WANG Xing-li, . Electrical Conductivity of Alkaline-reduced Graphene Oxide[J]. 高等学校化学研究, 2011, 27(5): 857-861.

WANG Huan, TIAN Hong-wei, WANG Xin-wei, QIAO Liang, WANG Shu-min, WANG Xing-li, ZHENG Wei-tao* and LIU Yi-chun. Electrical Conductivity of Alkaline-reduced Graphene Oxide[J]. Chemical Research in Chinese Universities, 2011, 27(5): 857-861.

[1]	XU Guangyuan, LIU Qin, YAN Huan. Recent Advances of Single-atom Catalysts for Electro-catalysis[J]. 高等学校化学研究, 2022, 38(5): 1146-1150.
[2]	BU Ran, LU Yingying, ZHANG Bing. Covalent Organic Frameworks Based Single-site Electrocatalysts for Oxygen Reduction Reaction[J]. 高等学校化学研究, 2022, 38(5): 1151-1162.
[3]	MIAO Tianchang, DI Xin, HAO Feini, ZHENG Gengfeng, HAN Qing. Polymeric Carbon Nitride-based Single Atom Photocatalysts for CO₂ Reduction to C₁ Products[J]. 高等学校化学研究, 2022, 38(5): 1197-1206.
[4]	MA Chunrong, SONG Bingyi, MA Zhentao, WANG Xiaoqian, TIAN Lin, ZHANG Haoran, CHEN Cai, ZHENG Xusheng, YANG Li-ming, WU Yuen. A Supported Palladium on Gallium-based Liquid Metal Catalyst for Enhanced Oxygen Reduction Reaction[J]. 高等学校化学研究, 2022, 38(5): 1219-1225.
[5]	QIAN Shengjie, WANG Yanggang, LI Jun. Single Iron-dimer Catalysts on MoS₂ Nanosheet for Potential Nitrogen Activation[J]. 高等学校化学研究, 2022, 38(5): 1226-1231.
[6]	SHU Chengyong, GAN Zhuofan, ZHOU Jia, WANG Zhen, TANG Wei. Highly Efficient Oxygen Reduction Reaction Fe-N-C Cathode in Long-durable Direct Glycol Fuel Cells[J]. 高等学校化学研究, 2022, 38(5): 1268-1274.
[7]	ZHENG Meng, WANG Jin. Regulating the Oxygen Affinity of Single Atom Catalysts by Dual-atom Design for Enhanced Oxygen Reduction Reaction Activity[J]. 高等学校化学研究, 2022, 38(5): 1275-1281.
[8]	GONG Yu, PAN Jing, ZHANG Lingling, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Metal-Organic Frameworks-derived Indium Clusters/Carbon Nanocomposites for Efficient CO₂ Electroreduction[J]. 高等学校化学研究, 2022, 38(5): 1287-1291.
[9]	ZHU Junlun, CUI Qian, WEN Wei, ZHANG Xiuhua, WANG Shengfu. Cu/CuO-Graphene Foam with Laccase-like Activity for Identification of Phenolic Compounds and Detection of Epinephrine[J]. 高等学校化学研究, 2022, 38(4): 919-927.
[10]	GAO Wei, LI Yufeng, ZHAO Jitao, ZHANG Zhe, TANG Weiwei, WANG Jun, WU Zhenyu, LI Zhenyu. Design and Preparation of Graphene/Fe₂O₃ Nanocomposite as Negative Material for Supercapacitor[J]. 高等学校化学研究, 2022, 38(4): 1097-1104.
[11]	ZHENG Xuelian, LIU Ling, YANG Cuicui, HE Yuanyuan, CHEN Jiu, TIAN Wei Quan. Modulation of the Second Order Nonlinear Optical Properties of Helical Graphene Nanoribbons Through Introducing Azulene Defects or/and BN Units[J]. 高等学校化学研究, 2022, 38(4): 974-984.
[12]	ZHENG Ruonan, ZHAI Zihui, QIU Chenxi, GAO Rui, LV Yang, SONG Yujiang. Highly Active Electrocatalyst Derived from ZIF-8 Decorated with Iron(III) and Cobalt(III) Porphyrin Toward Efficient Oxygen Reduction in Both Alkaline and Acidic Media[J]. 高等学校化学研究, 2022, 38(4): 961-967.
[13]	CHEN Yu, CHEN Yongting, LIAO Yuxiang, CHEN Shengli. A Chemical Dealloying Approach for Pt Surface-enriched Pt₃Co Alloy Nanoparticles as Oxygen Reduction Reaction Electrocatalysts[J]. 高等学校化学研究, 2022, 38(4): 991-998.
[14]	JI Yuancheng, XU Jiayun, SUN Hongcheng, and LIU Junqiu. Artificial Photosynthesis(AP): from Molecular Catalysts to Heterogeneous Materials[J]. 高等学校化学研究, 2022, 38(3): 688-697.
[15]	CHANG Shunkai, LI Cuiyan, LI Hui, ZHU Liangkui, FANG Qianrong. Stable Thiophene-sulfur Covalent Organic Frameworks for Oxygen Reduction Reaction(ORR)[J]. 高等学校化学研究, 2022, 38(2): 396-401.

Electrical Conductivity of Alkaline-reduced Graphene Oxide

Electrical Conductivity of Alkaline-reduced Graphene Oxide

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价