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高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (2): 239-241 .

• Articles • 上一篇    下一篇

Design, Synthesis and Electrochromic Properties of Anthraquinone Imide-based Donor-acceptor Type of Near Infrared Chromophores

QIAO Wen-qiang   

  1. Key Laboratory of Materials Behaviors and Evaluation Technology in Space Environments, Harbin Institute of Technology, Harbin 150001, P. R. China
  • 收稿日期:2011-05-03 修回日期:2011-05-11 出版日期:2012-03-25 发布日期:2012-03-08
  • 通讯作者: QIAO Wen-qiang E-mail:qwqchina@126.com
  • 基金资助:

    Supported by the Development Program for Outstanding Young Teachers in Harbin Institute of Technology, China(No. HITQNJS.2009.020).

Design, Synthesis and Electrochromic Properties of Anthraquinone Imide-based Donor-acceptor Type of Near Infrared Chromophores

QIAO Wen-qiang   

  1. Key Laboratory of Materials Behaviors and Evaluation Technology in Space Environments, Harbin Institute of Technology, Harbin 150001, P. R. China
  • Received:2011-05-03 Revised:2011-05-11 Online:2012-03-25 Published:2012-03-08
  • Contact: QIAO Wen-qiang E-mail:qwqchina@126.com
  • Supported by:

    Supported by the Development Program for Outstanding Young Teachers in Harbin Institute of Technology, China(No. HITQNJS.2009.020).

摘要: A new series of near infrared(NIR) electrochromic anthraquinone imides containing a triphenylamine moiety as an electron donor was synthesized and their electrochemical and spectroelectrochemical behavior were investigated. The results show that the new anthraquinone imides are redox active which can be reduced electrochemically from the neutral state to the radical anion form that absorbs in a range of 700―1200 nm.

关键词: Anthraquinone imide, Triphenylamine moiety, Near infrared electrochromism

Abstract: A new series of near infrared(NIR) electrochromic anthraquinone imides containing a triphenylamine moiety as an electron donor was synthesized and their electrochemical and spectroelectrochemical behavior were investigated. The results show that the new anthraquinone imides are redox active which can be reduced electrochemically from the neutral state to the radical anion form that absorbs in a range of 700―1200 nm.

Key words: Anthraquinone imide, Triphenylamine moiety, Near infrared electrochromism